EP0124979A2
Expired / Lapsed
EP
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Polyacetylene production
Assignee: BP PLC
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Filing: 1984-03-15
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Granted: —
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Expires: 2004-03-15
Abstract
Abstract This invention relates to a process for producing an oriented, crystalline poly(acetylene) (III) in film orfibrillarform by solvent casting a film from a solution of a polymer of the general formula (V) derived from a precursor monomer (IV), and transforming the pre-cast film of polymer (V) under tension or in a stress field into the poly(acetylene) (III). The transformation is carried out at a temperature between 20 and 200°C under reduced pressure over a duration of between 1 and 100 hours in an atmosphere inert to the precursor polymer (V) film and to the poly(acetylene) (III). Poly(acetylenes) are conducting polymers and find use in solid state batteries, field effect transistors and the like.
Inventors
- 👤 David Charles Bott
- 👤 Donald White
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-24 15:20
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; D; D01; D01F; D01F6/00; D01F6/02; C08J2349/00; Y; Y10; Y10S; Y10S264/00; Y10S264/47
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
210 words
A process for producing an oriented, crystalline poly(acetylene) (III) in film or fibrillar form comprising solvent casting a film from a solution of a polymer of the general formula (V) derived from a precursor monomer (IV), and transforming under tension or in a stress field the pre-cast film of polymer (V) into an oriented, crystalline film or fibrillar form of the poly(acetylene) (III) and a by-product (VI) at a temperature between 20 and 200°C under reduced pressure over a duration of between 1 and 100 hours in an atmosphere inert to the precursor polymer (V) film and to the poly (acetylene) (III), wherein in the general formulae IV, V and VI each of the groups R 1 and R 2 either (a) represent a radical selected from H, CX 3 , C m H 2m+1 and COOR 5 wherein X is a halogen atom, m has a value betweeen 1 and 4 and R 5 is an alkyl group with 1-4 carbon atoms, or (b) form together with the respective carbon atoms to which they are attached a benzene nucleus, and each of R 3 and R 4 either (c) represent H atoms, or (d) form together with the respective carbon atoms to which they are attached a benzene nucleus.
Claim 2
Dependent Claim
210 words
A process for producing an oriented, crystalline poly(acetylene) (III) in film or fibrillar form comprising solvent casting a film from a solution of a polymer of the general formula (V) derived from a precursor monomer (IV), and transforming under tension or in a stress field the pre-cast film of polymer (V) into an oriented, crystalline film or fibrillar form of the poly(acetylene) (III) and a by-product (VI) at a temperature between 20 and 200°C under reduced pressure over a duration of between 1 and 100 hours in an atmosphere inert to the precursor polymer (V) film and to the poly (acetylene) (III), wherein in the general formulae IV, V and VI each of the groups R 1 and R 2 either (a) represent a radical selected from H, CX 3 , C m H 2m+1 and COOR 5 wherein X is a halogen atom, m has a value betweeen 1 and 4 and R 5 is an alkyl group with 1-4 carbon atoms, or (b) form together with the respective carbon atoms to which they are attached a benzene nucleus, and each of R 3 and R 4 either (c) represent H atoms, or (d) form together with the respective carbon atoms to which they are attached a benzene nucleus.
Claim 3
Dependent Claim
29 words
A process for producing poly(acetylene) according to claim 1 wherein the groups R 1 and R 2 are a trifluoromethyl group, an alkyl group or an alkyl carboxylate group.
Claim 4
Dependent Claim
42 words
A process for producing poly(acetylene) according to claims 1 or 2 wherein the precursor monomer (IV) is a compound in which R 1 and R 2 are each a trifluoromethyl group, and R 3 and R 4 are each a hydrogen atom.
Claim 5
Dependent Claim
48 words
A process according to any one of the preceding claims wherein the polymerisation of the precursor monomer (IV) is carried out in the presence of a tungsten hexachloride/tetralkyl or aryl tin (1:2 w/w) or titanium tetrachloride/ trialkyl or dihaloalkyl aluminium (1:2 w/w) catalyst at ambient temperatures and pressures.
Claim 6
Dependent Claim
39 words
A process according to any one of the preceding claims wherein for the precursor polymer (V) which is to be solvent cast into a film is dissolved in an organic solvent to a concentration of up to 100 g/1.
Claim 7
Dependent Claim
24 words
A process for producing poly(acetylene) according to claim 5 wherein the organic solvent is selected from acetone, chloroform, ethyl acetate, tetrahydrofuran, toluene and xylene.
Claim 8
Dependent Claim
42 words
A process according to any one of the preceding claims wherein the solvent casting process is carried out in the substantial absence of moisture and/or oxygen in the system in order to produce a coherent film having the desirable properties of conductance.
Claim 9
Dependent Claim
32 words
A process according to any one of the preceding claims wherein the precursor polymer film is transformed into poly(acetylene) under a tension or stress in the region of 5 to 1000 MPa.
Claim 10
Dependent Claim
38 words
A process according to any one of the preceding claims wherein the film of the precursor polymer (V) is heated at a temperature between 20 and 200°C for between 1 and 100 hours to produce the poly(acetylene) film.
Claim 11
Dependent Claim
39 words
A process according to any one of the preceding claims wherein the film of the precursor polymer (V) is transformed into poly(acetylene) under conditions of temperature and duration specified in Table 1 of the specification for the respective substituents.
References Cited (Backward Citations)
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