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EP0156464A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Random copolymer

Assignee: Mitsui Chemicals Inc
•
Filing: 1985-02-01
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Granted: —
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Expires: 2005-02-01
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Abstract

Abstract A random copolymer composed of ethylene, a 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene and optionally an alpha-olefin having at least three carbon atoms or cycloolefin. The mole ratio of polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units from ethylene is from 3:97 to 95:5 and the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units without ring-opening. The copolymer is prepared by copolymerizing ethylene, optionally the alpha-olefin of at least 3 carbon atoms or cycloolefin, with the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene in a hydrocarbon medium in the presence of a catalyst formed from a vanadium compound and an organoaluminum compound which are soluble in the hydrocarbon medium. The copolymer has excellent transparency and a well balanced-combination of heat resistance, heat aging resistance, chemical and solvent resistance, dielectric properties and mechanical properties such as rigidity.

Inventors

  • 👤 Hirokazu Kajiura
  • 👤 Hidekuni Oda
  • 👤 Syuji Minami

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 14:19
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08; C08F; C08F210/00; C08F210/02; C08L; C08L65/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 145 words
A novel random copolymer, characterized in that (A) it is composed of ethylene and a 1,4,5,8-di- methano-1,2,3,4,4a,5,8,8a-octahydronaphthalene represented by the following formula (1) wherein R 1 and R 2 are identical and different and each represents a hydrogen atom, a halogen atom or an alkyl group, or R 1 and R 2 may be bonded to each other to form a trimethylene group or a group represented by the following formula in which R 3 and R 4 are identical or different and each represents a hydrogen atom, a halogen atom or an alkyl group, (B) the mole ratio of polymerized units derived from 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units derived from ethylene is from 3:97 to 95:5, and (C) the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units represented by the following formula (2) wherein R 1 and R 2 are as defined above.
Claim 2
Dependent Claim 145 words
A novel random copolymer, characterized in that (A) it is composed of ethylene and a 1,4,5,8-di- methano-1,2,3,4,4a,5,8,8a-octahydronaphthalene represented by the following formula (1) wherein R 1 and R 2 are identical and different and each represents a hydrogen atom, a halogen atom or an alkyl group, or R 1 and R 2 may be bonded to each other to form a trimethylene group or a group represented by the following formula in which R 3 and R 4 are identical or different and each represents a hydrogen atom, a halogen atom or an alkyl group, (B) the mole ratio of polymerized units derived from 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units derived from ethylene is from 3:97 to 95:5, and (C) the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units represented by the following formula (2) wherein R 1 and R 2 are as defined above.
Claim 3
Dependent Claim 22 words
A random copolymer according to claim 1 which has an intrinsic viscosity, measured in decalin at 135°C, of 0.005 to 20 dl/g.
Claim 4
Dependent Claim 26 words
A random copolymer according to claim 1 or 2 wherein in formula (1), at least one of R 1 and R 2 is an alkyl group.
Claim 5
Dependent Claim 106 words
A random copolymer, characterized in that (A) it is composed of at least one 1,4,5,8-di- methano - l,2,3,4,4a,5,8,8a-octahydronaphthalene as defined in claim 1, ethylene and at least one alpha-olefin of at least 3 carbon atoms or cycloolefin, (B) the mole ratio of polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units from ethylene is from 3:97 to 95:5, (B') the mole ratio of polymerized units from the at least one alpha-olefin or cycloolefin to the polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is from 95:5 to 20:80, and (C) the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units represented by formula (2) as defined in claim 1.
Claim 6
Dependent Claim 22 words
A random copolymer according to claim 4 which has an intrinsic viscosity, measured in decalin at 135°C, of 0.005 to 20 dl/g.
Claim 7
Dependent Claim 23 words
A random copolymer according to claim 4 or 5 wherein at least one of R 1 and R 2 is an alkyl group.
Claim 8
Dependent Claim 63 words
A process for producing a random copolymer as claimed in any one of the preceding claims which comprises copolymerizing ethylene and optionally at least one alpha-olefin of at least 3 carbon atoms or cycloolefin with said 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene in a hydrocarbon medium in the presence of a catalyst formed from a vanadium compound and an organoaluminum compound which are soluble in the hydrocarbon medium.
Claim 9
Dependent Claim 16 words
Shaped articles of a random copolymer as claimed in any one of claims 1 to 6.

References Cited (Backward Citations)

US3494897A Cited
FR1535460A Cited
FR2276320A1 Cited
US4178424A Cited

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