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EP0196388A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method of making electrodes

Assignee: Westinghouse Electric Corp
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Filing: 1985-11-28
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Granted: —
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Expires: 2005-11-28
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Abstract

Abstract Method of making an electrode by coating a solid oxygen conductive oxide layer. A coating of particles of an electronic conductor is formed on one surface of the oxide layer and a source of oxygen is applied to the opposite surface of the oxide layer. A metal halide vapor is applied over the electronic conductor and the oxide layer is heated to a temperature sufficient to induce oxygen to diffuse through the oxide layer and react with the metal halide vapor. This results in the growing of a metal oxide coating on the particles of electronic conductor, thereby binding them to the oxide layer.

Inventors

  • 👤 Arnold Otto Isenberg

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 21:57
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/10; H01M8/12; H01M8/1213; H01M4/00; H01M4/86; H01M4/90; H01M4/9016; H01M4/9025; H01M4/9033; H01M4/9041; H01M4/905; H01M4/9066; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/49115

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 101 words
A method of making an electrode by bonding an electronically conductive layer on a solid, oxygen-transporting oxide layer characterized by forming a coating of particles of an electronic conductor on a first surface of said oxide layer; applying a source of oxygen to a second surface of said oxide layer; applying a metal halide vapor to said first surface of said oxide layer; and heating said oxide layer to a temperature sufficient to induce oxygen to diffuse through said oxide layer and react with said metal halide vapor, whereby a metal oxide coating grows on said particles of said electronic conductor.
Claim 2
Independent Claim 101 words
A method of making an electrode by bonding an electronically conductive layer on a solid, oxygen-transporting oxide layer characterized by forming a coating of particles of an electronic conductor on a first surface of said oxide layer; applying a source of oxygen to a second surface of said oxide layer; applying a metal halide vapor to said first surface of said oxide layer; and heating said oxide layer to a temperature sufficient to induce oxygen to diffuse through said oxide layer and react with said metal halide vapor, whereby a metal oxide coating grows on said particles of said electronic conductor.
Claim 3
Dependent Claim 19 words
A method according to claim 1, characterized in that the oxide layer is a tube, sealed at one end.
Claim 4
Dependent Claim 18 words
A method according to claim 1 or 2, characterized in that the oxide layer consists of stabilized zirconia.
Claim 5
Dependent Claim 16 words
A method according to claim 3, characterized in that the stabilized zirconia is yttria stabilized zirconia.
Claim 6
Dependent Claim 24 words
A method according to claim 4, characterized in that the yttria stabilized zirconia is (ZrO 2 ) 0.90 (Y 2 O 3 ) 0.10
Claim 7
Independent Claim 23 words
A method according to any of claims 1 to 5, characterized in that the particles are from 1 to 100 microns in size.
Claim 8
Independent Claim 28 words
A method according to any of claims 1 to 6, characterized in that the at least one of platinum, gold, copper, nickel, cobalt, iron, and an alloy thereof.
Claim 9
Dependent Claim 24 words
S. A method according to claim 7, characterized in that the electronic conductor is at least one of cobalt, nickel and an alloy thereof.
Claim 10
Independent Claim 27 words
A method according to any of claims 1 to 8, characterized in that the source of oxygen is at least one of oxygen, water and carbon dioxide.
Claim 11
Independent Claim 22 words
A method according to any of claims 1 to 9, characterized in that the metal halide vapor is a metal chloride vapor.
Claim 12
Independent Claim 43 words
A method according to any of claims 1 to 9, characterized in that the metal halide vapor is a mixture of zirconium chloride and a chloride of a metal, the oxide of which stabilizes zirconia, in a proportion suitable to produce stabilized zirconia.
Claim 13
Independent Claim 27 words
A method according to any of claims 1 to 11, characterized in that the temperature is from 1000 to 1400°C for from 1 to about 30 minutes.
Claim 14
Independent Claim 30 words
A method according to any of claims 1 to 12, characterized in that the electronically conducting layer is at least one of a simple oxide and a mixed mixed oxide.
Claim 15
Independent Claim 25 words
A method according to any of claims 1 to 13, characterized in that the oxide layer is:doped lanthanum chromite, doped lanthanum manganite, or chromic oxide.

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