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EP0230024A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Optical recording medium having a stabilized recording layer

Assignee: Panasonic Holdings Corp
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Filing: 1986-12-19
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Granted: —
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Expires: 2006-12-19
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Abstract

Abstract An optical recording medium comprising an optically transparent substrate and a recording layer formed on the substrate and comprising a mixture of a photochromic spiropyran and an amphiphatic aliphatic acid or its salt. The aliphatic acid or its salt can stabilize photomerocyanine which is a colored isomer of a photochromic spiropyran. The mixture may further comprise a resin binder.

Inventors

  • 👤 Jinsei Miyazaki
  • 👤 Eiji Ando

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 09:04
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/685; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/246; G11B7/247; G11B7/2475; G11B7/252; G11B7/253; G11B7/2531

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 54 words
An optical recording medium which comprises an optically transparent substrate and a recording layer formed on said substrate, said recording layer comprising a mixture of a photochromic spiropyran having a hydrophobic long-chain alkyl group in the molecule and an amphiphatic compound selected from the group consisting of aliphatic acids and salts of the acids.
Claim 2
Dependent Claim 54 words
An optical recording medium which comprises an optically transparent substrate and a recording layer formed on said substrate, said recording layer comprising a mixture of a photochromic spiropyran having a hydrophobic long-chain alkyl group in the molecule and an amphiphatic compound selected from the group consisting of aliphatic acids and salts of the acids.
Claim 3
Dependent Claim 26 words
An optical recording medium according to Claim 1, wherein said photochromic spiropyran and said amphiphatic compound are mixed in a molar ratio of 1:0.1 to 10.
Claim 4
Dependent Claim 22 words
An optical recording medium according to Claim 1, wherein said recording layer consists of a plurality of Langmuir-Blodgett films of said mixture.
Claim 5
Dependent Claim 99 words
An optical recording medium according to Claim 1, wherein said spiropyran has the general formula in which R₁ and R₂ are independently a lower alkyl group, R₃ represents an alkyl group having at least 10 carbon atoms, X is a single bond or a group of one of the following formulae, -C n H 2n OCO-, -C n H 2n COO-, -­C n H 2n NHCO-, -C n H 2n CONH- or -C n H 2n O- wherein n≧ 0, R₄ represents an alkyl group having at least one carbon atom, and Y represents an oxygen or sulfur atom.
Claim 6
Dependent Claim 27 words
An optical recording medium according to Claim 4, wherein R₃ is an alkyl group having from 14 to 24 carbon atoms and X is -CH₂OCO- or -O-.
Claim 7
Dependent Claim 23 words
An optical recording medium according to Claim 1, wherein said amphiphatic compound is an aliphatic acid having from 2 to 30 carbon atoms.
Claim 8
Dependent Claim 19 words
An optical recording medium according to Claim 6, wherein said aliphatic acid has from 14 to 24 carbon atoms.
Claim 9
Dependent Claim 15 words
An optical recording medium according to Claim 6, wherein said aliphatic acid is stearic acid.
Claim 10
Dependent Claim 20 words
An optical recording medium according to Claim 1, wherein said amphiphatic compound is a metal salt of an aliphatic acid.
Claim 11
Dependent Claim 17 words
10 An optical recording medium according to Claim 1, wherein said mixture further comprises a resin binder.
Claim 12
Dependent Claim 15 words
An optical recording medium according to Claim 1, wherein said spiropyran is 6-nitro-1ʹ-octadecyl-8-­docosanoyloxy-3ʹ,3ʹ-dimethylspiro[2H-1-benzopyran-2,2ʹ-­indoline] or 6-nitro-1ʹ-octadecyl-8-methoxy-3ʹ,3ʹ-­dimethylspiro[2H-1-benzopyran-2,2ʹ-indoline].

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