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EP0301532A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Solvent free acrylic acid type thickening agents and a method of making same

Assignee: Goodrich Corp
•
Filing: 1988-07-29
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Granted: —
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Expires: 2008-07-29
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Abstract

Abstract A copolymer having no (zero) organic solvent is suitable for use as a thickening agent comprising an acrylic acid polymer crosslinked with from about 0.1 to about 6% by weight, based upon the weight of the acrylic acid polymer, of a copolymer, the copolymer having at least two terminal allyl groups. The copolymer at a 0.2 weight percent level dispersed in distilled water has a mucilage viscosity of at least 1000 cps. A method for making a solvent-free copolymer suitable as a thickening agent is also disclosed which comprises the steps of: a) charging into a reactor acrylic acid monomer, a comonomer, carbon dioxide, and a chemical initiator; b) polymerizing the acrylic acid monomer with the comonomer at a preselected temperature and pressure to produce a fine, fluffy acrylic acid copolymer; and c) separating totally and completely the acrylic acid copolymer from the carbon dioxide thus producing an organic solvent-free acrylic acid polymer. The amount of chemical initiator employed in the method ranges from about 0.25% to about 4% by weight based upon the weight of the acrylic acid.

Inventors

  • 👤 Mark Wayne Herbert
  • 👤 Gary Stephen Huvard

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 13:40
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/04; C08F20/06; C08F220/00; C08F220/02; C08F220/04; C08F220/06

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 25 words
An improved acrylic acid type copolymer suitable for use as a thickening agent, the improvement comprising: said acrylic acid type polymer being organic solvent free.
Claim 2
Dependent Claim 25 words
An improved acrylic acid type copolymer suitable for use as a thickening agent, the improvement comprising: said acrylic acid type polymer being organic solvent free.
Claim 3
Independent Claim 81 words
A method for making a solvent free acrylic acid type polymer suitable for use as a thickening agent, comprising the steps of: charging into a reactor acrylic acid monomer, a comonomer, carbon dioxide, and a chemical initiator; polymerizing said acrylic acid monomer with said comonomer at a preselected temperature and pressure to produce a fine, fluffy acrylic acid copolymer; and separating totally and completely said acrylic acid copolymer from said carbon dioxide thus producing an organic solvent free acrylic acid polymer.
Claim 4
Independent Claim 81 words
A method for making a solvent free acrylic acid type polymer suitable for use as a thickening agent, comprising the steps of: charging into a reactor acrylic acid monomer, a comonomer, carbon dioxide, and a chemical initiator; polymerizing said acrylic acid monomer with said comonomer at a preselected temperature and pressure to produce a fine, fluffy acrylic acid copolymer; and separating totally and completely said acrylic acid copolymer from said carbon dioxide thus producing an organic solvent free acrylic acid polymer.
Claim 5
Dependent Claim 13 words
The method of claim 3, wherein said charging step is a batch process.
Claim 6
Dependent Claim 13 words
The method of claim 3, wherein said charging step is a continuous process.
Claim 7
Dependent Claim 19 words
The method of claim 4, wherein said comonomer is incrementally charged into said reactor over a period of time.
Claim 8
Dependent Claim 16 words
The method of claim 2, wherein said carbon dioxide is at least 99% by volume pure.
Claim 9
Dependent Claim 22 words
The method of claim 2, wherein said comonomer has at least two terminal allyl groups having the formula H₂C = C .
Claim 10
Dependent Claim 14 words
The method of claim 7, wherein said comonomer is one or more polyunsaturated hydrocarbons.
Claim 11
Dependent Claim 24 words
The method of claim 2, wherein from about 1 to about 20 parts of oxygen is charged into the reactor with said carbon dioxide.
Claim 12
Dependent Claim 29 words
The method of claim 2, wherein the amount of said chemical initiator ranges from about 0.25% to about 4% by weight based on the weight of said acrylic acid.
Claim 13
Dependent Claim 53 words
An acrylic acid copolymer suitable for use as a thickening agent comprising: an acrylic acid polymer crosslinked with from 0.1 to about 6% by weight based upon the weight of said acrylic acid polymer of a copolymer, said copolymer having at least two terminal allyl groups having the formula H₂C = C .
Claim 14
Dependent Claim 53 words
An acrylic acid copolymer suitable for use as a thickening agent comprising: an acrylic acid polymer crosslinked with from 0.1 to about 6% by weight based upon the weight of said acrylic acid polymer of a copolymer, said copolymer having at least two terminal allyl groups having the formula H₂C = C .
Claim 15
Dependent Claim 26 words
The copolymer of claim 11, wherein said copolymer, at a 0.2 weight percent dispersed in distilled water, has a mucilage viscosity of at least 1000 cps.

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