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EP0318964A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Transparent gas-barrier multilayer structure

Assignee: Mitsubishi Gas Chemical Co Inc
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Filing: 1988-11-30
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Granted: —
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Expires: 2008-11-30
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Abstract

Abstract A transparent gas-barrier multilayer structure comprising (A) at least one layer of a polyamide composi­tion comprising (a) 30 to 80 parts by weight of a first copolyamide composed of an aromatic dicarboxylic acid as a main acid component and an aliphatic diamine as a main diamine component and (b) 70 to 20 parts by weight of a second copolyamide composed of an aliphatic dicarboxylic acid as a main acid component and m-xylylenediamine as a main diamine component, the total amount of the first copolyamide and the second copolyamide being 100 parts by weight, and (B) at least one layer of a thermoplastic resin other than the polyamide composition, said at least one layer (A) being bonded to said at least one layer (B).

Inventors

  • 👤 Masahiro Harada
  • 👤 Toru Kino
  • 👤 Akira Iwamoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 03:55
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/34; B32B27/06; B32B27/08; B32B7/00; B32B7/04; B32B7/12; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265; B32B2307/00; B32B2307/40; B32B2307/412; B32B2307/70; B32B2307/724; B32B2307/7242; B32B2377/00; B32B2439/00; B32B2439/70; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31725; Y10T428/31728; Y10T428/31736; Y10T428/3175; Y10T428/31786; Y10T428/31855; Y10T428/31935; Y10T428/31938

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 123 words
A transparent gas-barrier multilayer structure comprising (A) at least one layer of a polyamide composi­tion comprising (a) 30 to 80 parts by weight of a first copolyamide composed of an aromatic dicarboxylic acid as a main acid component and an aliphatic diamine as a main diamine component and (b) 70 to 20 parts by weight of a second copolyamide composed of an aliphatic dicarboxylic acid as a main acid component and m-xylylenediamine as a main diamine component, the total amount of the first copolyamide and the second copolyamide being 100 parts by weight, and (B) at least one layer of a thermoplastic resin other than the polyamide composition, said at least one layer (A) being bonded to said at least one layer (B).
Claim 2
Dependent Claim 123 words
A transparent gas-barrier multilayer structure comprising (A) at least one layer of a polyamide composi­tion comprising (a) 30 to 80 parts by weight of a first copolyamide composed of an aromatic dicarboxylic acid as a main acid component and an aliphatic diamine as a main diamine component and (b) 70 to 20 parts by weight of a second copolyamide composed of an aliphatic dicarboxylic acid as a main acid component and m-xylylenediamine as a main diamine component, the total amount of the first copolyamide and the second copolyamide being 100 parts by weight, and (B) at least one layer of a thermoplastic resin other than the polyamide composition, said at least one layer (A) being bonded to said at least one layer (B).
Claim 3
Dependent Claim 40 words
The multilayer structure of claim 1 in which the acid component of the first copolyamide (a) is com­posed of 100 to 70 mole % of the aromatic dicarboxylic acid and 0 to 30 mole % of an aliphatic dicarboxylic acid.
Claim 4
Dependent Claim 19 words
The multilayer structure of claim 2 in which the aromatic dicarboxylic acid is isophthalic acid, terephthalic acid, or both.
Claim 5
Dependent Claim 24 words
The multilayer structure of claim 2 in which the aliphatic dicarboxylic acid is a linear aliphatic dicarboxylic acid having 4 to 12 carbon atoms.
Claim 6
Dependent Claim 45 words
The multilayer structure of claim 1 in which the diamine component of the first copolyamide (a) is composed of 100 to 95 mole % of an aliphatic diamine having two aminomethyl groups in the molecule and 0 to 5 mole % of an alicyclic diamine.
Claim 7
Dependent Claim 25 words
The multilayer structure of claim 5 in which the aliphatic diamine having two aminomethyl groups in the molecule is selected from hexamethylenediamine, tetramethylenediamine and 1,3-bisaminomethylcyclohexane.
Claim 8
Dependent Claim 15 words
The multilayer structure of claim 5 in which the alicyclic diamine is 1,3-bisaminomethylcyclohexane or bis(4-aminocyclohexylmethane).
Claim 9
Dependent Claim 28 words
The multilayer structure of claim 1 in which the acid component of the second copolyamide (b) is a linear aliphatic dicarboxylic acid having 4 to 12 carbon atoms.
Claim 10
Dependent Claim 47 words
The multilayer structure of claim 1 ln which the acid component of the second copolyamide (b) is composed of at least 90 mole % of a linear aliphatic dicarboxylic acid having 4 to 12 carbon atoms and up to 10 mole % of an aromatic dicarboxylic acid.
Claim 11
Dependent Claim 49 words
The multilayer structure of claim 1 in which the diamine component of the second copolyamide (b) is composed of m-xylylenediamine and 0 to 5 mole % of a subsidiary diamine component selected from aliphatic diamines having 4 to 12 carbon atoms, diamines having an alicyclic group, and aromatic diamines.
Claim 12
Dependent Claim 33 words
The multilayer structure of claim 1 in which the polyamide composition comprises 35 to 60 parts by weight of the first copolyamide and 65 to 40 parts by weight of the second copolyamide.
Claim 13
Dependent Claim 22 words
The multilayer structure of claim 1 in which the other thermoplastic resin (B) is selected from poly­olefins, polystyrene, polyesters, polycarbonates and polyamides.

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