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EP0358652B1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Aqueous silicone emulsions ranging from fine particle emulsions up to optically clear silicone emulsions

Assignee: PFERSEE CHEMIE GMBH TE LANGWEID AM LECH, BONDSREPU
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Filing: 1988-04-07
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Granted: 1991-10-16
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Expires: 2008-04-07
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Abstract

Abstract Aqueous, fine particle to optically clear, thermally and mechanically stable silicone emulsions contain, in relation to the total emulsions, 3 to 25 % by weight of a water-soluble emulsifier (a), 0.1 to 84 % by weight of an aminoalkyl-substituted polysiloxane (b) (amine number at least 0.1), which may be present at least partially in salt form and which may be replaced by up to 70 % by weight of other polysiloxanes (emulsifier/silicone ratio at least 1,2 to 10), up to 3 % by weight of a low molecular weight weak acid (c) and at least 5 % by weight of water (d), whereby the sum of (a), (b), (c) and (d) is equal to 100 % by weight. Also described are a process for manufacturing these emulsions and the use thereof. The silicone emulsions according to the invention possess outstanding thermal stability.

Inventors

  • 👤 Harald Chrobaczek
  • 👤 Günther Tschida

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 12:32
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/6436; C08J2383/00; C08J2383/04; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T442/00; Y10T442/20; Y10T442/2352

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 226 words
Process for manufacturing finely-divided to optically clear thermally and mechanically stable silicone emulsions containing a) emulsifiers, b) aminoalkyl-substituted polysiloxanes, c) acids and d) water, characterised in that a silicone emulsion is produced which consists of a mixture of 3 to 25, preferably 8 to 12, parts by weight of an emulsifier soluble in water yielding a clear to transparent aqueous solution (constituent a), 0.1 to 84 ports by weight of at least one aminoalkyl-substituted polysiloxane with an amine number of at least 0.1, and preferably 0.3 (constituent b), 0.05 to 3.05, especially 0.10 to 1.1, and preferably 0.3 to 0.7, ports by weight of an acid, preferably a low molecular weight organic acid (based on 100% strength acid) (constituent c), and 5 to 96.85 parts by weight of water (constituent d), whereby the sum of the amounts of constituents a), b) and d) and of the amount of constituent c) used for pH-value adjustment, totals 100 parts by weight, whereby the ratio of emulsifier to siloxane is at least 1.2 to 10, wherein a mixture containing at least the constituents a) and d), is heated to a temperature of at least 50°C with stirring, until a homogeneous phase has been formed and is then cooled if need be, and wherein a pH-value of 3.0 to 7.0 is established by adding constituent c) before or after heating.
Claim 2
Dependent Claim 226 words
Process for manufacturing finely-divided to optically clear thermally and mechanically stable silicone emulsions containing a) emulsifiers, b) aminoalkyl-substituted polysiloxanes, c) acids and d) water, characterised in that a silicone emulsion is produced which consists of a mixture of 3 to 25, preferably 8 to 12, parts by weight of an emulsifier soluble in water yielding a clear to transparent aqueous solution (constituent a), 0.1 to 84 ports by weight of at least one aminoalkyl-substituted polysiloxane with an amine number of at least 0.1, and preferably 0.3 (constituent b), 0.05 to 3.05, especially 0.10 to 1.1, and preferably 0.3 to 0.7, ports by weight of an acid, preferably a low molecular weight organic acid (based on 100% strength acid) (constituent c), and 5 to 96.85 parts by weight of water (constituent d), whereby the sum of the amounts of constituents a), b) and d) and of the amount of constituent c) used for pH-value adjustment, totals 100 parts by weight, whereby the ratio of emulsifier to siloxane is at least 1.2 to 10, wherein a mixture containing at least the constituents a) and d), is heated to a temperature of at least 50°C with stirring, until a homogeneous phase has been formed and is then cooled if need be, and wherein a pH-value of 3.0 to 7.0 is established by adding constituent c) before or after heating.
Claim 3
Dependent Claim 34 words
Process according to Claim 1, characterised in that the mixture consisting of the constituents a), b) and d) is heated to a temperature of at least 50°C, and only then is constituent c) added.
Claim 4
Dependent Claim 30 words
Process according to Claim 1, characterised in that the mixture of constituents a) and d) is heated to at least 50°C, and only then are constituents b) and c) added.
Claim 5
Dependent Claim 32 words
Process according to at least one of Claims 1 to 3, characterised in that constituent b) is used in an amount of 5 to 70, preferably 12 to 18, ports by weight.
Claim 6
Dependent Claim 50 words
Process according to at least one of Claims 1 to 4, characterised in that as constituent b) straight-chain or branched-chain aminoalkyl-substituted polysiloxanes with an amine number of at least 0.1, preferably 0.3 to 1.0, in which the NH₂ groups are in the α, ω or in side-chain position, are used.
Claim 7
Dependent Claim 34 words
Process according to at least one of Claims 1 to 5, characterised in that as constituent a) primary and/or secondary, linear or branched C₈ to C₁₆ alkylpolyglycolethers and/or C₆ to C₁₂ alkylphenolethoxylates are used.
Claim 8
Dependent Claim 30 words
Process according to at least one of claims 1 to 6, characterised in that up to 70% of the weight of constituent b) is replaced by amino-group-free polysiloxanes (constituent e).
Claim 9
Dependent Claim 34 words
Process according to at least one of Claims 1 to 7, characterised in that the process is carried out at a temperature of 50 to 120°C and, if need be, under slightly elevated pressure.
Claim 10
Dependent Claim 26 words
Process according to at least one of Claims 1 to 8, characterised in that the process is carried out at a temperature of 60 to 95°C.
Claim 11
Dependent Claim 33 words
Process according to at least one of Claims 1 to 9, characterised in that the amount of constituent c) is chosen such that the prepared emulsion has a pH-value of 5.0 to 7.0.
Claim 12
Dependent Claim 15 words
The silicon dispersions produced according to any one or more of Claims 1 to 10.
Claim 13
Dependent Claim 28 words
The use of the silicone emulsions according to Claim 11 as such, or after the addition of other well-known textile aids, for treating textiles in the usual way.

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