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EP0427316A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Individualized, polycarboxylic acid crosslinked fibers

Assignee: Weyerhaeuser Co
•
Filing: 1990-10-29
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Granted: —
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Expires: 2010-10-29
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Abstract

Abstract Disclosed are individualized, crosslinked fibers, and process for making such fibers. The individualized, crosslinked fibers have a C₂ - C₉ polycarboxylic acid crosslinking agent reached with the fibers in the form of intrafiber crosslink bonds. Preferably, the crosslinking agent is citric acid, and preferably, between about 0.5 mole % and about 10.0 mole % of the crosslinking agent reacts to form the intrafiber crosslink bonds. The individualized, crosslinked fibers are useful in a variety of absorbent structure application.

Inventors

  • 👤 Carlisle Mitchell Herron
  • 👤 David James Cooper

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 16:01
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/10; D06M13/184; D06M13/192; D21; D21C; D21C9/00; D21C9/001; D21C9/002; D21C9/005; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2918; Y10T428/292; Y10T428/31504; Y10T428/31725; Y10T428/31736

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 133 words
Individualized, crosslinked cellulosic fibers, said fibers characterized in that it comprises cellulosic fibers in substantially individual form having an effective amount of a C₂ - C₉ polycarboxylic acid crosslinking agent reacted with said fibers in intrafiber crosslink bond form, wherein said C₂ - C₉ polycarboxylic acid crosslinking agent is selected from: (a) aliphatic and alicyclic C₂ - C₉ polycarboxylic acids either olefinically saturated or unsaturated and having at least three carboxyl groups per molecule; and (b) aliphatic and alicyclic C₂ - C₉ polycarboxylic acids having two carboxyl groups per molecule and having a carbon-carbon double bond located alpha, beta to one or both of the carboxylgroups, wherein one carboxyl group in said C₂ - C₉ polycarboxylic acid crosslinking agent is separated from a second carboxyl group by either two or three carbon atoms.
Claim 2
Dependent Claim 133 words
Individualized, crosslinked cellulosic fibers, said fibers characterized in that it comprises cellulosic fibers in substantially individual form having an effective amount of a C₂ - C₉ polycarboxylic acid crosslinking agent reacted with said fibers in intrafiber crosslink bond form, wherein said C₂ - C₉ polycarboxylic acid crosslinking agent is selected from: (a) aliphatic and alicyclic C₂ - C₉ polycarboxylic acids either olefinically saturated or unsaturated and having at least three carboxyl groups per molecule; and (b) aliphatic and alicyclic C₂ - C₉ polycarboxylic acids having two carboxyl groups per molecule and having a carbon-carbon double bond located alpha, beta to one or both of the carboxylgroups, wherein one carboxyl group in said C₂ - C₉ polycarboxylic acid crosslinking agent is separated from a second carboxyl group by either two or three carbon atoms.
Claim 3
Dependent Claim 45 words
The individualized, crosslinked fibers of Claim 1 wherein said fibers have between 0.5 mole % and 10.0 mole preferably between 1.5 mole % and 6.0 mole % crosslinking agent, calculated on a cellulose anhydroglucose molar basis, reacted therewith in the form of intrafiber crosslink bonds.
Claim 4
Dependent Claim 40 words
The individualized fibers of Claim 2 wherein said crosslinking agent is sufficiently reacted with said fibers in intrafiber bond form to cause said fibers to have a water retention value of from 28 to 60, preferably from 30 to 45.
Claim 5
Dependent Claim 30 words
The individualized, crosslinked fibers of any of Claims 1-3 wherein said crosslinking agent is selected from citric acid, 1,2,3,4 butane tetracarboxylic acid, and 1,2,3 propane tricarboxylic acid, preferably citric acid.
Claim 6
Dependent Claim 34 words
The individualized, crosslinked fibers of any of Claim 1-3 wherein said crosslinking agent is selected from oxydisuccinic acid, tartrate monosuccinic acid having the formula and tartrate disuccinic acid having the formula preferably oxydisuccinic acid.

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