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EP0933377A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Anti-smudge agent, method of forming an anti-smudge layer, anti-reflection optical member and display device

Assignee: Daikin Industries Ltd
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Filing: 1999-01-29
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Granted: —
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Expires: 2019-01-29
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Abstract

Abstract An anti-smudge agent characterized by containing an organosilicon compound represented by the following general formula (1): R f2 -(OC 3 F 6 ) n2 -O-(CF 2 ) m2 -(CH 2 ) 12 -Z-(CH 2 ) s2 -Si-(R 2 ) 3 wherein R f2 is a linear or branched perfluoroalkyl group having 1 to 16 carbon atoms; R 2 is a hydrolytic group; Z is -OOCNH- or -O-; n2 is an integer of 1 to 50; m2 is an integer of 0 to 3; 12 is an integer of 0 to 3; and s2 is an integer of 1 to 6, with a proviso that these m2 and 12 meet the condition of 6≧m2+12>0.

Inventors

  • 👤 Koichi Ohata
  • 👤 Niro Watanabe
  • 👤 Toru Okubo
  • 👤 Atsushi Miida

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 21:36
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/10; G02B1/18; C; C09; C09D; C09D4/00; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/24; G02B1/11; H; H01; H01J; H01J29/00; H01J29/86; H01J29/89; H01J29/896

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 113 words
An anti-smudge agent characterized by containing an organosilicon compound represented by the following general formula (1): R f2 -(OC 3 F 6 ) n2 -O-(CF 2 ) m2 -(CH 2 ) 12 -Z-(CH 2 ) s2 -Si-(R 2 ) 3 wherein R f2 is a linear or branched perfluoroalkyl group having 1 to 16 carbon atoms; R 2 is a hydrolytic group; Z is -OOCNH- or -O-; n2 is an integer of 1 to 50; m2 is an integer of 0 to 3; 12 is an integer of 0 to 3; and s2 is an integer of 1 to 6, with a proviso that these m2 and 12 meet the condition of 6≧m2+12>0.
Claim 2
Dependent Claim 27 words
The anti-smudge agent according to claim 1, characterized in that said R 2 in said general formula (1) is alkoxy group having 1 to 10 carbon atoms.
Claim 3
Dependent Claim 128 words
An anti-smudge agent characterized by containing an organosilicon compound represented by the following general formula (3): wherein R f2 is a linear or branched perfluoroalkyl group having 1 to 16 carbon atoms; R 3 is an alkyl group having 1 to 10 carbon atoms; X is a halogen atom; n2 is an integer of 1 to 50; m2 is an integer of 0 to 3; 12 is an integer of 0 to 3; and s2 is an integer of 1 to 6; a is an integer of 0 to 3; b is an integer of 0 to 3; c is 0 or 1; d is 0 or 1; with a proviso that these m2, 12, a, b, c and d meet the conditions of 6≧m2+12>0, a+b=3, and c+d=1.
Claim 4
Dependent Claim 65 words
The anti-smudge agent according to claim 3, characterized in that said organosilicon compound is formed of a first organosilicon compound represented by said general formula (3) and a second organosilicon compound represented by said general formula (3), and said first organosilicon compound and said second organosilicon compound are different from each other in the components "a", "b", "c" and "d" in said general formula (3).
Claim 5
Dependent Claim 31 words
A method of forming an anti-smudge layer characterized by comprising a step of depositing the anti-smudge agent of claim 1 on a treating substrate by means of a wet coating method.
Claim 6
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 5, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 7
Dependent Claim 31 words
A method of forming an anti-smudge layer characterized by comprising a step of depositing the anti-smudge agent of claim 3 on a treating substrate by means of a wet coating method.
Claim 8
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 7, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 9
Dependent Claim 31 words
A method of forming an anti-smudge layer characterized by comprising a step of depositing the anti-smudge agent of claim 1 on a treating substrate by means of a dry coating method.
Claim 10
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 9, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 11
Dependent Claim 31 words
A method of forming an anti-smudge layer characterized by comprising a step of depositing the anti-smudge agent of claim 3 on a treating substrate by means of a dry coating method.
Claim 12
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 11, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 13
Dependent Claim 54 words
A method of forming an anti-smudge layer characterized by comprising the steps of; impregnating a porous molded body with the anti-smudge agent of claim 1; and heating said porous molded body impregnated with said anti-smudge agent in vacuum thereby to evaporate said anti-smudge agent and to form an anti-smudge layer on a treating substrate.
Claim 14
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 13, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 15
Dependent Claim 58 words
The method of forming an anti-smudge layer according to claim 13, characterized in that said porous molded body is constituted by at least one kind of materials selected from the group consisting of SiO 2 , TiO 2 , ZrO 2 , MgO, Al 2 O 3 , CaSO 4 , Cu, Fe, Al, stainless steel and carbon.
Claim 16
Dependent Claim 57 words
The method of forming an anti-smudge layer according to claim 13, characterized in that the heating method for evaporating said anti-smudge agent impregnated in said porous molded body is at least one method selected from a resistance heating method, an electron beam heating method, ion beam heating method, high frequency heating method and a light heating method.
Claim 17
Dependent Claim 54 words
A method of forming an anti-smudge layer characterized by comprising the steps of; impregnating a porous molded body with the anti-smudge agent of claim 3; and heating said porous molded body impregnated with said anti-smudge agent in vacuum thereby to evaporate said anti-smudge agent and to form an anti-smudge layer on a treating substrate.
Claim 18
Dependent Claim 47 words
The method of forming an anti-smudge layer according to claim 17, characterized in that further comprising a step of subjecting said anti-smudge layer that has been formed on the treating substrate by making use of said anti-smudge agent to heating, humidification, light irradiation, or electron beam irradiation.
Claim 19
Dependent Claim 58 words
The method of forming an anti-smudge layer according to claim 17, characterized in that said porous molded body is constituted by at least one kind of materials selected from the group consisting of SiO 2 , TiO 2 , ZrO 2 , MgO, Al 2 O 3 , CaSO 4 , Cu, Fe, Al, stainless steel and carbon.
Claim 20
Dependent Claim 57 words
The method of forming an anti-smudge layer according to claim 17, characterized in that the heating method for evaporating said anti-smudge agent impregnated in said porous molded body is at least one method selected from a resistance heating method, an electron beam heating method, ion beam heating method, high frequency heating method and a light heating method.
Claim 21
Dependent Claim 45 words
A reflection preventive optical member comprising a transparent substrate; a reflection preventive film formed on at least one surface of said transparent substrate; and an anti-smudge layer formed on an outermost surface; characterized in that said anti-smudge layer contains the anti-smudge agent of claim 1.
Claim 22
Dependent Claim 33 words
The reflection preventive optical member according to claim 21, characterized in that said transparent substrate is an organic substrate formed of a transparent substrate or an inorganic substrate formed of a glass substrate.
Claim 23
Dependent Claim 45 words
A reflection preventive optical member comprising a transparent substrate; a reflection preventive film formed on at least one surface of said transparent substrate; and an anti-smudge layer formed on an outermost surface; characterized in that said anti-smudge layer contains the anti-smudge agent of claim 3.
Claim 24
Dependent Claim 33 words
The reflection preventive optical member according to claim 23, characterized in that said transparent substrate is an organic substrate formed of a transparent substrate or an inorganic substrate formed of a glass substrate.
Claim 25
Dependent Claim 27 words
An optical functional member characterized by comprising the reflection preventive optical member of claim 21; and a functional optical member adhered to said reflection preventive optical member.
Claim 26
Dependent Claim 19 words
The optical functional member according to claim 25, characterized in that said functional optical member is a polarizing plate.
Claim 27
Dependent Claim 27 words
An optical functional member characterized by comprising the reflection preventive optical member of claim 23; and a functional optical member adhered to said reflection preventive optical member.
Claim 28
Dependent Claim 19 words
The optical functional member according to claim 27, characterized in that said functional optical member is a polarizing plate.
Claim 29
Dependent Claim 37 words
A display device comprising a display screen having front face, on the surface of which a coat member is adhered via an adhesive, characterized in that said coat member is the optical functional member of claim 25.
Claim 30
Dependent Claim 37 words
A display device comprising a display screen having front face, on the surface of which a coat member is adhered via an adhesive, characterized in that said coat member is the optical functional member of claim 26.
Claim 31
Dependent Claim 37 words
A display device comprising a display screen having front face, on the surface of which a coat member is adhered via an adhesive, characterized in that said coat member is the optical functional member of claim 27.
Claim 32
Dependent Claim 37 words
A display device comprising a display screen having front face, on the surface of which a coat member is adhered via an adhesive, characterized in that said coat member is the optical functional member of claim 28.
Claim 33
Dependent Claim 30 words
The display device according to claim 29, characterized in that said display is a liquid crystal display, a CRT display, a projection television, a plasma display, or an EL display.
Claim 34
Dependent Claim 30 words
The display device according to claim 30, characterized in that said display is a liquid crystal display, a CRT display, a projection television, a plasma display, or an EL display.
Claim 35
Dependent Claim 30 words
The display device according to claim 31, characterized in that said display is a liquid crystal display, a CRT display, a projection television, a plasma display, or an EL display.
Claim 36
Dependent Claim 30 words
The display device according to claim 32, characterized in that said display is a liquid crystal display, a CRT display, a projection television, a plasma display, or an EL display.

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