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EP1086997A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Ink, ink-set, and image recording process for improving density of ink-jet recorded image

Assignee: Canon Inc
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Filing: 2000-09-14
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Granted: —
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Expires: 2020-09-14
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Abstract

Abstract An ink is provided which suppresses the influence of the kinds of recording media on the image quality, is excellent in image quality, effectively inhibits the occurrence of bleed upon the formation of color images, is excellent in long-term shelf stability and stably forms high quality images. The ink contains at least one salt selected from the group consisting of (M 1 ) 2 SO 4 , CH 3 COO(M 1 ), Ph-COO(M 1 ), (M 1 )NO 3 , (M 1 )Cl, (M 1 )Br, (M 1 )I, (M 1 ) 2 SO 3 and (M 1 ) 2 CO 3 , wherein M 1 represents an alkali metal, ammonium or organic ammonium, and Ph represents a phenyl group, and a self-dispersing anionic carbon black having a functional-group density of at least 1.8 (µmol/m 2 ) on its surface.

Inventors

  • 👤 Koichi Osumi
  • 👤 Shinya Mishina
  • 👤 Tomonari Watanabe

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 12:05
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09D11/324; B; B41; B41J; B41J2/00; B41J2/005; B41J2/01; B41J2/135; B41J2/14; B41J2/14016; B41J2/1433; C09D11/40; B41J2002/14169; B41J2002/14387; B41J2002/14475

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 92 words
An ink comprising at least one salt selected from the group consisting of (M 1 ) 2 SO 4 , CH 3 COO(M 1 ), Ph-COO(M 1 ), (M 1 )NO 3 , (M 1 )Cl, (M 2 )Br, (M 1 )I, (M 1 ) 2 SO 3 and (M 1 ) 2 CO 3 , wherein M 1 represents an alkali metal, ammonium or organic ammonium, and Ph represents a phenyl group, and self-dispersing anionic carbon black having a functional-group density of at least 1.8 (µmol/m 2 ) on its surface.
Claim 2
Dependent Claim 29 words
The ink according to Claim 1, wherein the salt is contained in a proportion of 0.05 to 10 % by weight based on the total weight of the ink.
Claim 3
Dependent Claim 29 words
The ink according to Claim 2, wherein the salt is contained in a proportion of 0.1 to 5 % by weight based on the total weight of the ink.
Claim 4
Dependent Claim 34 words
The ink according to any one of Claims 1 to 3, wherein the self-dispersing anionic carbon black has at least one hydrophilic group bonded directly or through another atomic group to the surface thereof.
Claim 5
Dependent Claim 54 words
The ink according to Claim 4, wherein the hydrophilic group is selected from the group consisting of -COO(M 2 ), -SO 3 (M 2 ) 2 , -PO 3 H(M 2 ) and -PO 3 (M 2 ) 2 , wherein M 2 is a hydrogen atom, an alkali metal, ammonium or organic ammonium.
Claim 6
Dependent Claim 36 words
The ink according to Claim 4 or 5, wherein said another atomic group is an alkylene group having 1 to 12 carbon atoms, a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group.
Claim 7
Dependent Claim 62 words
The ink according to Claim 4, wherein the hydrophilic group is selected from the group consisting of -COO(M 2 ), -SO 3 (M 2 ) 2 and -PO 3 (M 2 ) 2 , and M 2 in the above formulae is identical with M 1 in the formulae representing the salt in any one of Claims 1 to 4 and 6.
Claim 8
Dependent Claim 112 words
An ink comprising at least one salt selected from the group consisting of (M 1 ) 2 SO 4 , CH 3 COO(M 1 ), Ph-COO(M 1 ), (M 1 )NO 3 , (M 1 )Cl, (M 1 )Br, (M 1 )I, (M 1 ) 2 SO 3 and (M 1 ) 2 CO 3 , wherein M 1 represents an alkali metal, ammonium or organic ammonium, and Ph represents a phenyl group, and a self-dispersing anionic carbon black having a functional-group density of at least 0.45 (mmol/g) on its surface, the ink undergoing no substantial change in viscosity even when it is stored for one month in an environment of 60°C.
Claim 9
Dependent Claim 27 words
The ink according to any one of Claims 1 to 8, wherein the self-dispersing anionic carbon black has an average particle diameter of at least 90 nm.
Claim 10
Dependent Claim 19 words
The ink according to any one of Claims 1 to 9, wherein the ink is an ink for ink-jet.
Claim 11
Dependent Claim 42 words
An ink set comprising in combination the black ink according to any one of Claims 1 to 9, and a water-based color ink comprising at least one coloring material selected from among coloring materials for cyan, magenta, yellow, red, green and blue.
Claim 12
Dependent Claim 23 words
The ink set according to Claim 11, wherein the coloring material for the color ink is an acid dye or a direct dye.
Claim 13
Dependent Claim 18 words
The ink set according to Claim 11, wherein the coloring material for the color ink is a pigment.
Claim 14
Dependent Claim 17 words
The ink set according to any one of Claims 11 to 13, which is used for ink-jet.
Claim 15
Dependent Claim 20 words
An ink cartridge comprising an ink tank which contains the ink according to any one of Claims 1 to 10.
Claim 16
Dependent Claim 23 words
A recording unit comprising an ink container portion containing the ink according to Claim 10, and a head portion for ejecting the ink.
Claim 17
Dependent Claim 24 words
An image recording apparatus comprising an ink container portion containing the ink according to Claim 10, and a recording head for ejecting the ink.
Claim 18
Dependent Claim 60 words
A color-image recording apparatus comprising an ink container portion containing the ink according to Claim 10, another ink container portion containing a water-based color ink comprising at least one coloring material selected from among coloring materials for cyan, magenta, yellow, red, green and blue, and recording head portions for respectively ejecting the inks contained in the respective ink container portions.
Claim 19
Dependent Claim 34 words
An image recording process comprising the step of ejecting the ink according to Claim 10 toward the surface of a recording medium to apply the ink to the surface thereof, thereby recording an image.
Claim 20
Dependent Claim 18 words
The image recording process according to Claim 19, wherein the energy for ejecting the ink is thermal energy.
Claim 21
Dependent Claim 18 words
The image recording process according to Claim 19, wherein the energy for ejecting the ink is mechanical energy.
Claim 22
Dependent Claim 78 words
A process for forming a color image comprising the steps of ejecting a first water-based ink comprising at least one coloring material selected from among coloring materials for cyan, magenta, yellow, red, green and blue toward the surface of a recording medium to apply the ink to the surface thereof; and ejecting the ink according to Claim 10 as a second ink toward the surface of the recording medium to apply the second ink to the surface thereof.
Claim 23
Dependent Claim 47 words
A water-based ink-jet ink comprising a self-dispersing carbon black having an average particle diameter of at least 90 nm and stably dispersed in an aqueous medium, and a salt, wherein the density of an image obtained by the ink is lowered if the salt is not contained.
Claim 24
Independent Claim 69 words
A method for improving the image density of an ink-jet recorded image formed with an ink comprising a self-dispersing carbon black having an average particle diameter of at least 90 nm and being stably dispersed in an aqueous medium, the method comprising causing a salt to be contained as an agent for inhibiting penetration of the self-dispersing carbon black into the interior of a recording medium in the ink.

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