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US3599715A Expired / Lapsed US ⏱️ 0.0 years remaining

Use of surfactant foam for recovery of petroleum

Assignee: Marathon Oil Co
•
Filing: 1970-02-18
•
Granted: 1971-08-17
•
Expires: 1990-02-18
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Abstract

Abstract Water-external micellar dispersions containing hydrocarbon, surfactant, and 50-95 percent by volume water are contacted with a gas (e.g. air or nitrogen) to form a stable foam which is then injected into and displaced through an oil-bearing reservoir to recover crude oil. The foam may be generated in situ as well as on the surface.

Inventors

  • 👤 Wayne O Roszelle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:39
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/594

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 26 words
The process of claim 1 wherein the foam is produced in the subterranean formation by contacting the micellar dispersion with the foam producing gas in situ.
Claim 2
Dependent Claim 23 words
The process of claim 1 wherein the foam is produced at the surface and injected into the subterranean formation through said injection means.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein the micellar dispersion is comprised of hydrocarbon, water, and surfactant.
Claim 4
Dependent Claim 35 words
The process of claim 4 wherein the water-external micellar dispersion comprises from about 4 to 45 volume percent hydrocarbon, about 50 to 95 volume percent water, and from about 4 to 20 volume percent surfactant.
Claim 5
Dependent Claim 19 words
The process of claim 5 wherein the micellar dispersion contains from about 0.01 to 20 volume percent of cosurfactant.
Claim 6
Dependent Claim 17 words
The process of claim 5 wherein the micellar dispersion contains about 0.001 to about 5 percent electrolyte.
Claim 7
Dependent Claim 19 words
The process of claim 1 wherein the foam is displaced by injecting a fluid drive material into the formation.
Claim 8
Dependent Claim 12 words
The process of claim 8 wherein the drive material is a gas.
Claim 9
Dependent Claim 13 words
The process of claim 8 wherein the drive material is an aqueous medium.
Claim 10
Dependent Claim 32 words
The process of claim 8 wherein about 5 to 80 pore volume of a mobility buffer is injected after the foam, having a mobility about equal to or greater than said foam.
Claim 11
Dependent Claim 27 words
The process of claim 11 wherein the mobility buffer has a mobility about equal to or less than about that of the back portion of the foam.
Claim 12
Dependent Claim 146 words
A process for recovery of hydrocarbon from a hydrocarbon containing subterranean formation having at least one injection means in fluid communication with at least one producing means, the process comprising: a. injectig into the formation a water-external micellar dispersion comprising about 4 to about 45 percent hydrocarbon, about 50 to about 95 percent water, and at least about 4 percent surfactant, the percents based on volume, and, b. injecting a gas compatible with the micellar dispersion into the formation simultaneously with or subsequent to injection of said micellar dispersion so that when the gas and micellar dispersion come into intimate contact a foam is generated, thereafter, c. injecting into the formation about 5 to 80 percent pore volume of a mobility buffer, and d. injecting a drive material to displace the foam and mobility buffer toward the producing means and recovering hydrocarbon through said producing means.
Claim 13
Dependent Claim 16 words
The process of claim 13 wherein the mobility buffer comprises water and a mobility reducing agent.
Claim 14
Dependent Claim 11 words
The process of claim 13 wherein the drive material is water.
Claim 15
Dependent Claim 32 words
The process of claim 13 wherein the mobility of the front portion of the mobility buffer is about equal to or less than the mobility of the back portion of the foam.

References Cited (Backward Citations)

US2866507A Cited
US3196944A Cited
US3177939A Cited
US3330344A Cited
US3318379A Cited
US3323588A Cited
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US3373809A Cited
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US3506070A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-08-16 1975-02-15 1975-08-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-08-16 1979-02-15 1979-08-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-08-16 1983-02-15 1983-08-17 $7700.00 Window Closed / Lapsed

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