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US3668099A Expired / Lapsed US ⏱️ 0.0 years remaining

Apparatus for measuring oxygen content of a fluid

Assignee: United States Steel Corp
•
Filing: 1971-02-16
•
Granted: 1972-06-06
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Expires: 1991-02-16
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Abstract

Abstract Apparatus for measuring oxygen content of fluids at elevated temperatures includes a sensor or probe which comprises a Cr2O3 tube and a solid electrolyte button sealing that end of the tube that contacts the fluid. A solid oxygen reference material in the tube made of chromium or a chromium alloy contacts the button and the other end of the tube is sealed with a molybdenum cap. A thermocouple and a lead wire pass through the cap into the tube. A quartz tube surrounds the Cr2O3 tube and button with its outer end in sealing engagement with the button. An electronic conductor has one end extending into the fluid. In one embodiment the conductor is a tube surrounding the quartz tube and in another it is a separate rod or tube. In both embodiments the conductor is preferably a mixture of Al2O3 and molybdenum. The lead wire and the other end of the conductor are connected to a voltage measuring means.

Inventors

  • 👤 Robert S Rittiger
  • 👤 Charles K Russell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:48
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/411

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 49 words
Apparatus according to claim 1 in which said first tube is made of Cr2O3, said button is made of ZrO2 containing 3 to 10% CaO, said reference material is of the class consisting of chromium and chromium alloys, and said electronic conductor is a mixture of Al2O3 and molybdenum.
Claim 2
Dependent Claim 19 words
Apparatus according to claim 2 in which said second electronic conductor is a third tube surrounding said second tube.
Claim 3
Dependent Claim 25 words
Apparatus according to claim 3 including a molybdenum cap sealing the upper end of said first tube with said lead wire and thermocouple passing therethrough.
Claim 4
Dependent Claim 78 words
Apparatus according to claim 4 including a flange extending radially outward from the inner end oF said second tube, a flange extending radially outward from the inner end of said third tube and abutting the flange on said second tube, an internally threaded sleeve surrounding said flanges and having a flange engaging the flange on said third tube, a male threaded cap threaded into said sleeve, and a lead extending between said cap and said voltage measuring means.
Claim 5
Dependent Claim 18 words
Apparatus according to claim 5 in which said internally threaded sleeve and male threaded cap are stainless steel.
Claim 6
Dependent Claim 28 words
Apparatus according to claim 6 including a protective sleeve surrounding a portion of said third tube with one end bearing against the flange of said stainless steel sleeve.
Claim 7
Dependent Claim 19 words
Apparatus according to claim 1 in which said second electronic conductor is a third tube surrounding said second tube.
Claim 8
Dependent Claim 21 words
Apparatus according to claim 8 including a protective sleeve surrounding said third tube on the inner side of said first tube.
Claim 9
Dependent Claim 78 words
Apparatus according to claim 8 including a flange extending radially outward from the inner end of said second tube, a flange extending radially outward from the inner end of said third tube and abutting the flange on said second tube, an internally threaded sleeve surrounding said flanges and having a flange engaging the flange on said third tube, a male threaded cap threaded into said sleeve, and a lead extending between said cap and said voltage measuring means.
Claim 10
Dependent Claim 20 words
Apparatus according to claim 1 in which said second electronic conductor is an elongated member spaced from said second tube.
Claim 11
Dependent Claim 24 words
Apparatus according to claim 1 including a cap sealing the upper end of said first tube with said lead wire and thermocouple passing therethrough.

References Cited (Backward Citations)

GB1094180A Cited
GB1191222A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-06-06 1975-12-06 1976-06-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-06-06 1979-12-06 1980-06-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-06-06 1983-12-06 1984-06-06 $7700.00 Window Closed / Lapsed

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