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US3781650A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for reducing interference in a spin resonance spectrometer by subtracting interferograms having 180 grad phase separation

Assignee: Spectrospin AG
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Filing: 1972-05-09
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Granted: 1973-12-25
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Expires: 1992-05-09
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Abstract

Abstract A method and apparatus are described for reducing interference in the receiver of a spin resonance spectrometer. The apparatus generates a first set of RF excitation pulses of one phase angle and a second set of RF pulses having a phase angle that is 180* different. The interferograms formed by one set of these pulses are then subtracted from those formed by the other in a signal averager.

Inventors

  • 👤 T Keller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:57
CPC Classifications
G; G01; G01R; G01R33/00; G01R33/20; G01R33/44; G01R33/46; G01R33/4625

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 97 words
A method for recording spin resonance spectra, comprising: exciting a spin system of a sample with a first set of RF pulses having a first phase angle and a second set of RF pulses having a second phase angle that is 180* different from the first phase angle; receiving interferograms containing the resonance frequencies of the spin system excited by the first and second sets of pulses; and subtracting an interferogram formed by one of the first and second sets of RF pulses from an interferogram formed by the oTher set to obtain a mean value thereof.
Claim 2
Independent Claim 97 words
A method for recording spin resonance spectra, comprising: exciting a spin system of a sample with a first set of RF pulses having a first phase angle and a second set of RF pulses having a second phase angle that is 180* different from the first phase angle; receiving interferograms containing the resonance frequencies of the spin system excited by the first and second sets of pulses; and subtracting an interferogram formed by one of the first and second sets of RF pulses from an interferogram formed by the oTher set to obtain a mean value thereof.
Claim 3
Dependent Claim 21 words
The method of claim 1 wherein the pulses of the first and second sets of RF pulses alternate with each other.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein the phase of each pulse is determined stochastically.
Claim 5
Dependent Claim 20 words
The method of claim 3 wherein the first and second sets of RF pulses have approximately equal numbers of pulses.
Claim 6
Dependent Claim 27 words
The method of claim 1 including the step of generating the first and second RF pulses by modulating an RF signal with modulation pulses of alternating polarity.
Claim 7
Dependent Claim 23 words
The method of claim 1 further comprising the step of Fourier analyzing the mean value interferogram to determine the component resonance frequencies thereof.
Claim 8
Dependent Claim 96 words
Apparatus for recording spin resonance spectra comprising: a spin resonance spectrometer including an RF oscillator, a pulse generator, an RF modulator for pulse modulating the output of the RF oscillator, and a signal averager for averaging interferograms produced in response to each excitation pulse to obtain the mean value thereof; means in said pulse generator for forming pulses of opposite polarity; means for applying said pulses of opposite polarity to the RF modulator; and means for applying corresponding pulses of opposite polarity to the signal averager for controlling the sign of the addition operation performed thereby.
Claim 9
Dependent Claim 96 words
Apparatus for recording spin resonance spectra comprising: a spin resonance spectrometer including an RF oscillator, a pulse generator, an RF modulator for pulse modulating the output of the RF oscillator, and a signal averager for averaging interferograms produced in response to each excitation pulse to obtain the mean value thereof; means in said pulse generator for forming pulses of opposite polarity; means for applying said pulses of opposite polarity to the RF modulator; and means for applying corresponding pulses of opposite polarity to the signal averager for controlling the sign of the addition operation performed thereby.
Claim 10
Dependent Claim 18 words
The apparatus of claim 7 including means for forming pulses of opposite polarity that alternate with each other.
Claim 11
Dependent Claim 15 words
The apparatus of claim 7 including means for forming pulses having stochastically determined phase angles.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-12-24 1977-06-25 1977-12-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-12-24 1981-06-25 1981-12-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-12-24 1985-06-25 1985-12-25 $7700.00 Window Closed / Lapsed

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