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US3871981A Expired / Lapsed US ⏱️ 0.0 years remaining

In-situ oxygen detector

Assignee: Elsag International BV
•
Filing: 1973-07-02
•
Granted: 1975-03-18
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Expires: 1993-07-02
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Abstract

Abstract A measuring apparatus having a self-contained reference atmosphere and utilizing thick film thermocouples to measure the operating temperature of the detector cell. An embodiment of the detector is provided with heating means and enclosed so as to be capable of operation in a high velocity varying temperature atmosphere. In another embodiment, the operating temperature of the detector cell is measured by one thick-film thermocouple inside and another outside the closed end of the electrolyte tube of the detector. The outputs of the two thermocouples are electrically parallel connected to provide an average of the two thermocouple readings.

Inventors

  • 👤 Louis R Flais
  • 👤 Ralph G Gentle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 00:06
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/4067

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 190 words
AN IN-SITU OXYGEN DETECTOR COMPRISING AN ELECTROLYTE TUBE OF ZIRCONIUM - OXIDE FORMED SO AS TO HAVE ONE END OPEN AND ONE END CLOSED; A FIRST POROUS PLATINUM ELECTRODE STRIP BONDED TO THE OUTSIDE OF SAID TUBE, EXTENDING PARTIALLY ACROSS THE CLOSED END AND CONTINUING ALONG THE SIDE OF SAID TUBE TO A FIRST CONTACT TERMINAL ON THE OUTSIDE OF SAID TUBE; A SECOND POROUS PLATINUM ELECTRODE STRIP BONDED TO THE INSIDE OF SAID TUBE, EXTENDING PARTIALLY ACROSS THE CLOSED END OF SAID TUBE SO AS TO OVERLAP SAID FIRST ELECTRODE AND CONTINUING ALONG THE INSIDE, OVER THE OPEN END AND PARTIALLY ON THE OUTSIDE OF SAID TUBE TO A SECOND CONTACT TERMINAL ON THE OUTSIDE OF SAID TUBE; MEANS SEALING THE OPEN END OF SAID TUBE INCLUDING A ZIRCONIA CAP; A SELF-CONTAINED REFERENCE ATMOSPHERE SEALED INSIDE SAID TUBE BY SAID SEALING MEANS; A FIRST THERMOCOUPLE LOCATED ON THE OUTSIDE CLOSED END OF SAID ELECTROLYTE TUBE SO AS TO DETECT THE TEMPERATURE OF SAID FIRST ELECTRODE; AND A SECOND THERMOCOUPLE LOCATED ON THE INSIDE CLOSED END OF SAID ELECTROLYTE TUBE SO AS TO DETECT THE TEMPERATURE OF SAID SECOND ELECTRODE.
Claim 2
Dependent Claim 190 words
AN IN-SITU OXYGEN DETECTOR COMPRISING AN ELECTROLYTE TUBE OF ZIRCONIUM - OXIDE FORMED SO AS TO HAVE ONE END OPEN AND ONE END CLOSED; A FIRST POROUS PLATINUM ELECTRODE STRIP BONDED TO THE OUTSIDE OF SAID TUBE, EXTENDING PARTIALLY ACROSS THE CLOSED END AND CONTINUING ALONG THE SIDE OF SAID TUBE TO A FIRST CONTACT TERMINAL ON THE OUTSIDE OF SAID TUBE; A SECOND POROUS PLATINUM ELECTRODE STRIP BONDED TO THE INSIDE OF SAID TUBE, EXTENDING PARTIALLY ACROSS THE CLOSED END OF SAID TUBE SO AS TO OVERLAP SAID FIRST ELECTRODE AND CONTINUING ALONG THE INSIDE, OVER THE OPEN END AND PARTIALLY ON THE OUTSIDE OF SAID TUBE TO A SECOND CONTACT TERMINAL ON THE OUTSIDE OF SAID TUBE; MEANS SEALING THE OPEN END OF SAID TUBE INCLUDING A ZIRCONIA CAP; A SELF-CONTAINED REFERENCE ATMOSPHERE SEALED INSIDE SAID TUBE BY SAID SEALING MEANS; A FIRST THERMOCOUPLE LOCATED ON THE OUTSIDE CLOSED END OF SAID ELECTROLYTE TUBE SO AS TO DETECT THE TEMPERATURE OF SAID FIRST ELECTRODE; AND A SECOND THERMOCOUPLE LOCATED ON THE INSIDE CLOSED END OF SAID ELECTROLYTE TUBE SO AS TO DETECT THE TEMPERATURE OF SAID SECOND ELECTRODE.
Claim 3
Dependent Claim 49 words
An in-situ oxygen detector as set forth in claim 1 wherein said first and second electrode strips overlap in the central portion of the closed end of said tube so as to form an electrode pair for ion conduction on the center of the closed end of said tube.
Claim 4
Dependent Claim 46 words
An in-situ oxygen detector as set forth in claim 2 wherein said self-contained reference atmosphere includes a metal-metal oxide powder, said metal reacting with any oxygen migrating through said zirconium-oxide tube to form the metal oxide and thereby maintaining said reference atmosphere''s oxygen partial pressure constant.
Claim 5
Dependent Claim 39 words
An in-situ oxygen detector as set forth in claim 3 wherein said sealing means includes the brazing of said zirconia cap to said electrolyte tube with a braze alloy capable of maintaining said brazed seal at 1500*F ambient temperature.
Claim 6
Dependent Claim 25 words
An in-situ oxygen detector as set forth in claim 1 wherein said first and second thermocouples are thickfilm thermocouples from 0.1 to 1.0 mils thick
Claim 7
Dependent Claim 127 words
An in-situ oxygen detector as set forth in claim 1 including: means for enclosing said electrolyte tube so as to leave the closed end of said tube exposed to an atmosphere of unknown oxygen content; a first means for heating a portion of the enclosed length of said electrolyte tube near the closed end of said tube, said first heating means being located along the length of said tube and internal to said enclosing means; a second means for heating the unknown atmosphere and the closed end of said tube located opposite the closed end of said tube; and means for controlling said first and second heating means so that the temperature sensed by said first and second thermocouples is maintained at a substantIally indentical temperature level.

References Cited (Backward Citations)

US3598711A Cited
US3576730A Cited
US3597345A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-17 1978-09-16 1979-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-17 1982-09-16 1983-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-17 1986-09-16 1987-03-18 $7700.00 Window Closed / Lapsed

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