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US3887631A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxidative dehydrogenation of hydrocarbons

Assignee: Texaco Inc
•
Filing: 1973-05-14
•
Granted: 1975-06-03
•
Expires: 1993-05-14
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Abstract

Abstract Hydrocarbons such as butene may be oxidatively dehydrogenated to eg butadiene by use of a catalyst consisting essentially of oxides of molybdenum, cobalt, and boron.

Inventors

  • 👤 Roberta Yaffe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 02:52
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J23/882; C; C07; C07C; C07C5/00; C07C5/42; C07C5/48

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 71 words
The method of preparing butadiene from butene which comprises contacting said butene in vapor phase in the presence of oxygen with a catalyst consisting essentially of a CoO. b MoO3 . c B2O3 wherein a is 0.75-1.25, b is 0.75-1.25, and c is 0.8-2; maintaining said butene in contact with said catalyst for 0.5-7 seconds at 440*C-510*C thereby forming effluent gas containing butadiene; and recovering said effluent gas containing said butadiene.
Claim 2
Independent Claim 71 words
The method of preparing butadiene from butene which comprises contacting said butene in vapor phase in the presence of oxygen with a catalyst consisting essentially of a CoO. b MoO3 . c B2O3 wherein a is 0.75-1.25, b is 0.75-1.25, and c is 0.8-2; maintaining said butene in contact with said catalyst for 0.5-7 seconds at 440*C-510*C thereby forming effluent gas containing butadiene; and recovering said effluent gas containing said butadiene.
Claim 3
Independent Claim 25 words
THE METHOD OF PREPARING BUTADIENE FROM BUTENE WHICH COMPRISES CONTACTING SAID BUTENE IN VAPOR PHASE IN THE PRESENCE OF OXYGEN WITH CATALYST CONSISTING ESSENTIALLY OF
Claim 4
Independent Claim 25 words
THE METHOD OF PREPARING BUTADIENE FROM BUTENE WHICH COMPRISES CONTACTING SAID BUTENE IN VAPOR PHASE IN THE PRESENCE OF OXYGEN WITH CATALYST CONSISTING ESSENTIALLY OF
Claim 5
Dependent Claim 19 words
The method of preparing butadiene as claimed in claim 1 wherein said catalyst is CoO. MoO3 . 0.8-2 B2O3.
Claim 6
Dependent Claim 30 words
The method of preparing butadiene from butene as claimed in claim 1 wherein said charge butene is admitted to the catalyst at a volume hourly space velocity VHSV of 500-8000.
Claim 7
Dependent Claim 26 words
The method of preparing butadiene from butene as claimed in claim 1 wherein said charge butene is admitted to the catalyst at a VHSV of 1000-4000.
Claim 8
Dependent Claim 24 words
The method of preparing butadiene from butene as claimed in claim 1 wherein said charge butene is contacted with said catalyst for 1.1-2.8 seconds.

References Cited (Backward Citations)

US3380931A Cited
US3159688A Cited
US3320330A Cited
US3414631A Cited
US3577477A Cited
US3607966A Cited
US3778386A Cited
US3764632A Cited
US3759840A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-02 1978-12-02 1979-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-02 1982-12-02 1983-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-02 1986-12-02 1987-06-03 $7700.00 Window Closed / Lapsed

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