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US3888786A Expired / Lapsed US ⏱️ 0.0 years remaining

Chlorinated bis(phenylethynyl)anthracenes as fluorescers in chemiluminescent systems

Assignee: Wyeth Holdings LLC
•
Filing: 1973-11-23
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Granted: 1975-06-10
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Expires: 1993-11-23
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Abstract

Abstract This invention relates to a chemiluminescent system to obtain chemiluminescent light by reacting an oxalic-type compound of the group consisting of an oxalic-type ester with a hydroperoxide compound in the presence of a solvent and chloro, fluoro, or lower alkyl bis phenylethynyl-substituted aromatic compound as a fluorescer.

Inventors

  • 👤 Donald Roy Maulding

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 14:01
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/06; C09K11/07; C07; C07C; C07C2603/00; C07C2603/02; C07C2603/04; C07C2603/22; C07C2603/24

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 21 words
A CHEMILUMINESCENT COMPOSITION FOR REACTION WITH A HYDROPEROXIDE TO OBTAIN CHEMILUMINESCENT LIGHT, SAID COMPOSITION COMPRISING (1) AN ESTER OF THE FORMULA:
Claim 2
Dependent Claim 21 words
A CHEMILUMINESCENT COMPOSITION FOR REACTION WITH A HYDROPEROXIDE TO OBTAIN CHEMILUMINESCENT LIGHT, SAID COMPOSITION COMPRISING (1) AN ESTER OF THE FORMULA:
Claim 3
Dependent Claim 17 words
A composition according to claim 1, in which said chemiluminescent compound is a bis-ester of oxalic acid.
Claim 4
Dependent Claim 35 words
A composition according to claim 2 in which said ester comprises an ester formed from oxalic acid and a phenol, said phenol characterized by an ionization constant in water greater than 1.3 X 10 10.
Claim 5
Dependent Claim 12 words
A composition according to claim 3 in which said bis(substituted-phenyl)oxalate comprises bis(2,4,5-trichloro-6-carbopentoxyphenyl)oxalate.
Claim 6
Dependent Claim 15 words
A composition according to claim 2 wherein said bis-phenyl ester is substituted with carbalkoxy groups.
Claim 7
Dependent Claim 18 words
A composition according to claim 2 wherein said fluorescer is a monochloro or a dichloro derivative of 9,10-bis-(phenylethynyl)anthracene.
Claim 8
Dependent Claim 20 words
A composition according to claim 6 wherein said fluorescer is selected from the group consisting of 1,5-dichloro-9,10-bis(phenylethynyl)anthracene; 1,8-dichloro-9,10-bis(phenylethynyl)anthracene; and 2,3-dichloro-9,10-bis(phenylethynyl)anthracene.
Claim 9
Dependent Claim 11 words
A composition according to claIm 2 wherein said fluorescer is 2-methyl-9,10-bis(phenylethynyl)anthracene.
Claim 10
Dependent Claim 11 words
A composition according to claim 3 wherein said fluorescer is 1-chloro-9,10-bis(phenylethynyl)anthracene.
Claim 11
Dependent Claim 11 words
A composition according to claim 3 wherein said fluorescer is 2-chloro-9,10-bis(phenylethynyl)anthracene.

References Cited (Backward Citations)

US3399137A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-09 1978-12-09 1979-06-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-09 1982-12-09 1983-06-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-09 1986-12-09 1987-06-10 $7700.00 Window Closed / Lapsed

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