US3896024A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing light fuel oil
Assignee: Mobil Oil AS
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Filing: 1974-04-02
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Granted: 1975-07-22
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Expires: 1994-04-02
Abstract
Abstract The production of light fuel oil by catalytic cracking is accomplished in a single riser conversion zone by cracking a recycle oil product of cracking initially in the riser with freshly regenerated catalyst under restricted severity conditions and a fresh gas oil feed is cracked with coke deactivated zeolite cracking catalyst in an upper portion of the riser under restricted severity conditions.
Inventors
- 👤 Donald M Nace
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 13:55
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/14; C10G11/18
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
195 words
A METHOD FOR PRODUCING LIGHT FUEL OIL AND LOWER BOILING HYDROCARBONS WHICH COMPRISES: COMBINING A HEAVY CYCLE OIL PRODUCT OF CATALYTIC CRACKING WITH FRESHLY REGENERATED CATALYST PARTICLES TO FORM A SUSPENSION AT A TEMPERATURE IN THE RANGE OF 900*F. TO 1000*F., PASSING THE SUSPENSION UPWARDLY THROUGH A RISER CONVERSION ZONE UNER LIMITED CONVERSION CONDITIONS DESIGNED TO PRODUCE LIGHT FUEL OIL PRODUCT AND DEPOSIT FROM ABOUT 0.5 TO ABOUT 1.2 WEIGHT PERCENT CARBON ON THE SUSPENDED CATALYST PARTICLES, COMBINING A FRESH GAS OIL FEED WITH SAID SUSPENSION OF CARBOND CONTAINING CATALYST AND CYCLE OIL CONVESION PRODUCTS IN AN AMOUNT TO FORM A SECOND SUSPENSION OF REDUCED TEMPERATURE WITHIN THE RANGE OF ABOUT 80/*F. TO ABOUT 900*F., PASSING THE SECOND SUSPENSION THROUGH A RISER CONVERSION ZONE UNDER CONVERSION CONDITIONS SELECTED TO PARTICULARLY PRODUCE LIGHT FUEL OIL PRODUCT, SEPRATING THE HYDROCARBON PRODUCT OF SAID CYCLE OIL AND SAID GAS OIL CONVERSION FROM CATALYST PARTICLES AND THEN INTO HYDROCARBON FRACTIONS COMPRISING GASOLINE AND LOWER BOILING COMPNENTS, A LIGHT FUEL OIL PRODUCT FRACTION, A HEAVY CYCLE OIL PRODUCT FRACTION AND A HIGH BOILING RESIDUAL MATEIAL, AND RECRACKING THE SEPARATED HEAVY CYCLE OIL FRACTION WITH FRESHLY REGENERATED CATALYST AS ABOVE DEFINED.
Claim 2
Independent Claim
195 words
A METHOD FOR PRODUCING LIGHT FUEL OIL AND LOWER BOILING HYDROCARBONS WHICH COMPRISES: COMBINING A HEAVY CYCLE OIL PRODUCT OF CATALYTIC CRACKING WITH FRESHLY REGENERATED CATALYST PARTICLES TO FORM A SUSPENSION AT A TEMPERATURE IN THE RANGE OF 900*F. TO 1000*F., PASSING THE SUSPENSION UPWARDLY THROUGH A RISER CONVERSION ZONE UNER LIMITED CONVERSION CONDITIONS DESIGNED TO PRODUCE LIGHT FUEL OIL PRODUCT AND DEPOSIT FROM ABOUT 0.5 TO ABOUT 1.2 WEIGHT PERCENT CARBON ON THE SUSPENDED CATALYST PARTICLES, COMBINING A FRESH GAS OIL FEED WITH SAID SUSPENSION OF CARBOND CONTAINING CATALYST AND CYCLE OIL CONVESION PRODUCTS IN AN AMOUNT TO FORM A SECOND SUSPENSION OF REDUCED TEMPERATURE WITHIN THE RANGE OF ABOUT 80/*F. TO ABOUT 900*F., PASSING THE SECOND SUSPENSION THROUGH A RISER CONVERSION ZONE UNDER CONVERSION CONDITIONS SELECTED TO PARTICULARLY PRODUCE LIGHT FUEL OIL PRODUCT, SEPRATING THE HYDROCARBON PRODUCT OF SAID CYCLE OIL AND SAID GAS OIL CONVERSION FROM CATALYST PARTICLES AND THEN INTO HYDROCARBON FRACTIONS COMPRISING GASOLINE AND LOWER BOILING COMPNENTS, A LIGHT FUEL OIL PRODUCT FRACTION, A HEAVY CYCLE OIL PRODUCT FRACTION AND A HIGH BOILING RESIDUAL MATEIAL, AND RECRACKING THE SEPARATED HEAVY CYCLE OIL FRACTION WITH FRESHLY REGENERATED CATALYST AS ABOVE DEFINED.
Claim 3
Independent Claim
161 words
A method for cracking gas oils and higher boiling material which comprises: initially catalytically cracking a heavy cycle oil product of cracking in a riser conversion zone at a temperature above 900*F. under conversion conditions restricted to limit conversion of the cycle oil charge and deposit from about 0.8 to about 1.2 weight percent carbon on the catalyst, combining a fresh gas oil feed with the cycle oil conversion product containing catalyst with said deposited carbon to form a suspension at a temperature below 900*F. maintained at a contact time within the range of 2 to 4 seconds to restrict conversion of the fresh gas oil feed, separating the suspEnsion into a hydrocarbon phase and a catalyst phase, regenerating the catalyst phase, separating the hydrocarbon phase into desired product fractions comprising a heavy cycle oil and recycling said heavy cycle oil product of cracking as charge for contact with freshly regenerated catalyst in the initial portion of the riser conversion zone.
Claim 4
Independent Claim
161 words
A method for cracking gas oils and higher boiling material which comprises: initially catalytically cracking a heavy cycle oil product of cracking in a riser conversion zone at a temperature above 900*F. under conversion conditions restricted to limit conversion of the cycle oil charge and deposit from about 0.8 to about 1.2 weight percent carbon on the catalyst, combining a fresh gas oil feed with the cycle oil conversion product containing catalyst with said deposited carbon to form a suspension at a temperature below 900*F. maintained at a contact time within the range of 2 to 4 seconds to restrict conversion of the fresh gas oil feed, separating the suspEnsion into a hydrocarbon phase and a catalyst phase, regenerating the catalyst phase, separating the hydrocarbon phase into desired product fractions comprising a heavy cycle oil and recycling said heavy cycle oil product of cracking as charge for contact with freshly regenerated catalyst in the initial portion of the riser conversion zone.
Claim 5
Independent Claim
148 words
A method for converting hydrocarbons to gasoline and fuel oil products which comprises: passing a cracking catalyst suspended in a hydrocarbon phase upwardly through a riser conversion zone under decreasing temperature and catalyst activity conditions, the hydrocarbon phase in the lower portion of the riser conversion zone initially limited to a heavy cycle oil product of the conversion operation, the hydrocarbon phase in an upper portion of the riser conversion zone comprising fresh gas oil feed material, restricting conversion of the gas oil feed in the upper portion of the riser conversion zone by limiting the conversion condition to a temperature within the range of 800* to 900*F., separating the product of said riser conversion operation to recover light fuel oil and lower boiling products from higher boiling material comprising heavy cycle oil, and recycling the heavy cycle oil to the lower portion of said riser conversion zone.
Claim 6
Independent Claim
148 words
A method for converting hydrocarbons to gasoline and fuel oil products which comprises: passing a cracking catalyst suspended in a hydrocarbon phase upwardly through a riser conversion zone under decreasing temperature and catalyst activity conditions, the hydrocarbon phase in the lower portion of the riser conversion zone initially limited to a heavy cycle oil product of the conversion operation, the hydrocarbon phase in an upper portion of the riser conversion zone comprising fresh gas oil feed material, restricting conversion of the gas oil feed in the upper portion of the riser conversion zone by limiting the conversion condition to a temperature within the range of 800* to 900*F., separating the product of said riser conversion operation to recover light fuel oil and lower boiling products from higher boiling material comprising heavy cycle oil, and recycling the heavy cycle oil to the lower portion of said riser conversion zone.
Claim 7
Dependent Claim
31 words
The method of claim 3 wherein the heavy cycle oil is mixed with freshly regenerated catalyst to form a suspension at a temperature in the range of 900*F. to about 1000*F.
Claim 8
Dependent Claim
33 words
The method of claim 4 wherein conversion of the heavy cycle oil deposits carbon on the catalyst thereby reducing the activity of the catalyst to within the range of 20 to 40 FAI.
Claim 9
Dependent Claim
49 words
The method of claim 5 wherein the fresh gas oil feed is brought in contact with the carbon deactivated catalyst after the catalyst has attained a 20 to 40 fluid activity index level to form a mixture at a conversion temperature within the range of 800*F. to about 900*F.
Claim 10
Dependent Claim
28 words
The method of claim 6 wherein each of said cycle oil feed and said fresh gas oil feed are preheated before contact with catalyst in said conversion zone.
Claim 11
Dependent Claim
46 words
The method of claim 7 wherein the residence time of the fresh gas oil feed in the riser is restricted to within the range of 2 to 4 seconds and the heavy cycle oil feed conversion is restricted to provide increased yields of light fuel oil.
Claim 12
Dependent Claim
14 words
The method of claim 8 wherein the catalyst comprises a crystalline zeolite cracking component.
Claim 13
Dependent Claim
18 words
The method of claim 9 wherein the crystalline zeolite is a rare earth exchanged Y faujasite crystalline zeolite.
References Cited (Backward Citations)
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US2908680A
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US3182011A
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US3186805A
Cited
US3689402A
Cited
US3801493A
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US3847793A
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US3856659A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-07-21 | 1979-01-20 | 1979-07-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-07-21 | 1983-01-20 | 1983-07-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-07-21 | 1987-01-20 | 1987-07-22 | $7700.00 | Window Closed / Lapsed |