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US3923626A Expired / Lapsed US ⏱️ 0.0 years remaining

Miniature probe containing multifunctional electrochemical sensing electrodes

Assignee: DS MEDICAL PRODUCTS Co A CORP
•
Filing: 1974-11-01
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Granted: 1975-12-02
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Expires: 1994-11-01
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Abstract

Abstract A miniature probe contains multifunctional electrochemical electrodes which measure oxygen content or the hydrogen ion activity or pH of samples. One of these electrodes is contained within an oxygen sensor, one of these electrodes is contained within a carbon dioxide sensor while the other electrode can be coupled with a separate reference electrode or the reference electrode can surround the probe thereby providing a hydrogen ion activity or pH sensor. In this manner, the miniature probe contains an oxygen sensor, a carbon dioxide sensor and a pH electrode, or an oxygen sensor, a carbon dioxide sensor and a pH sensor.

Inventors

  • 👤 Leonard W Niedrach
  • 👤 Jr William H Stoddard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 23:53
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/404; G01N33/00; G01N33/0004; G01N33/0009; G01N33/0027; G01N33/0031

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 349 words
A MINIATURE PROBE CONTAINING AN OXYGEN SENSOR, A CARBON DIOXIDE SENSOR AND A PH ELECTRODE WHICH COMPRISES A FLEXIBLE, ELONGATED ELECTRODE LEAD, THE ELECTRODE WHICH COMPRISES A BASE MEMBER, AND AN EXTERIOR SURFACE OF PALLADIUM ON THE BASE MEMBER, THREE SEPARATE AND SPACED APART ELECTROCHEMICALLY ACTIVE REGIONS OF HYDRIDED PALLADIUM WITH A SURFACE OF PLATINUM BLACK, PALLADIUM OXIDE AND PALLADIUM OXIDE, RESPECTIVELY, ADHERING TIGHTLY TO AN IN ELECTRICAL LEAD AND INSULTED SURFACED BASE MEMBER OF THE ELCTRODE LEAD AND INSULATED ELECTRICALLY FROM EACH OTHER THEREBY FORMING AN OXYGEN ELECTRPDE, A HYDROGEN ELECTRODE AND A HYDROGEN ELECTRODE, SURTIVELY, A REFERENCE ELECTRODE FOR THE OXYGEN ELECTRODE SURRESPECROUNDING AT LEAST PARTIALLY AND SPACED FROM THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD, THE REFERENCE ELECTRODE CONTAINING A METAL LEAD AND AN ELECTROCHEMICALLY ACTIVE REGION OF SILVER, A LAYER OF ELECTRICAL INSULATION DISPOSED BETWEEN THE METAL SURFACED BASE MEMBER FOR THE ELECTRODE LEAD AND THE METAL LEAD OF THE REFERENCE ELECTROD, AND ELECTROLYTE CONTACTING BOTH THE ELECTROCHEMICALLY ACTIVE REGIONS OF HYDRIDED PALLADIUM WITH A SURFACE OF PLATINUM BLACK, AND SILVER, AND AN OUTER SHEATH OF OXYGEN PERMEABLE, ION-IMPERMEABLE DIFFUSION BARRIER MATERIAL ENCAPSULTING AT LEAST THE ELECTROCHEMICALLY ACTIVE REGIONS AND THE ELECTROLYTE THEREBY PROVIDING AN OXYGEN SENSOR; A REFERENCE ELECTRODE FOR THE FIRST HYDROGEN ELECTRODE SURROUNDING AT LEAST PARTIALLY AND SPACED FROM THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD; TRODE CONTAINING AN ELECTROCHEMICALLY ACTIVE REGION OF SILVER AND A SILVER HALIDE, A LAYER OF ELECTRICAL INSULATION DISPOSED BETWEEN THE METAL SURFACE BASE MEMBER OF THE ELECTRODE LEAD AND THE REFERENCE ELECTRODE., AND ELECTRODE, AND CONTACTING BOTH THE ELECTROCHEMICALLY ACTIVE REGIONS OF PALLADIUM OXIDE AND A PH ELECTRODE COMPRISING A SEPARATE PORTION OF THE METAL PERMEABLE, ION-IMPERMEABLE DIFFUSION BARRIER MATERIAL ENCAPSULATING AT LEAST THE ELECTROCHEMICALLY ACTIVE REGIONS AND THE ELECTROLYTE THEREBY PROVIDING A CARBON DIOXIDE SENSOR; AND A PH ELECTRODE COMPRISING A SEPARATE PORTION OF THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD AND AN ELECTROCHEMICALLY ACTIVE REGION OF PALLADIUM OXIDE ADHERING TIGHTLY TO AND IN ELECTRICAL CONTACT WITH THE METAL SURFACED BASED MEMBER AND EXPOSED EXTERIORLY OF THE OUTER SHEATHS.
Claim 2
Dependent Claim 349 words
A MINIATURE PROBE CONTAINING AN OXYGEN SENSOR, A CARBON DIOXIDE SENSOR AND A PH ELECTRODE WHICH COMPRISES A FLEXIBLE, ELONGATED ELECTRODE LEAD, THE ELECTRODE WHICH COMPRISES A BASE MEMBER, AND AN EXTERIOR SURFACE OF PALLADIUM ON THE BASE MEMBER, THREE SEPARATE AND SPACED APART ELECTROCHEMICALLY ACTIVE REGIONS OF HYDRIDED PALLADIUM WITH A SURFACE OF PLATINUM BLACK, PALLADIUM OXIDE AND PALLADIUM OXIDE, RESPECTIVELY, ADHERING TIGHTLY TO AN IN ELECTRICAL LEAD AND INSULTED SURFACED BASE MEMBER OF THE ELCTRODE LEAD AND INSULATED ELECTRICALLY FROM EACH OTHER THEREBY FORMING AN OXYGEN ELECTRPDE, A HYDROGEN ELECTRODE AND A HYDROGEN ELECTRODE, SURTIVELY, A REFERENCE ELECTRODE FOR THE OXYGEN ELECTRODE SURRESPECROUNDING AT LEAST PARTIALLY AND SPACED FROM THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD, THE REFERENCE ELECTRODE CONTAINING A METAL LEAD AND AN ELECTROCHEMICALLY ACTIVE REGION OF SILVER, A LAYER OF ELECTRICAL INSULATION DISPOSED BETWEEN THE METAL SURFACED BASE MEMBER FOR THE ELECTRODE LEAD AND THE METAL LEAD OF THE REFERENCE ELECTROD, AND ELECTROLYTE CONTACTING BOTH THE ELECTROCHEMICALLY ACTIVE REGIONS OF HYDRIDED PALLADIUM WITH A SURFACE OF PLATINUM BLACK, AND SILVER, AND AN OUTER SHEATH OF OXYGEN PERMEABLE, ION-IMPERMEABLE DIFFUSION BARRIER MATERIAL ENCAPSULTING AT LEAST THE ELECTROCHEMICALLY ACTIVE REGIONS AND THE ELECTROLYTE THEREBY PROVIDING AN OXYGEN SENSOR; A REFERENCE ELECTRODE FOR THE FIRST HYDROGEN ELECTRODE SURROUNDING AT LEAST PARTIALLY AND SPACED FROM THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD; TRODE CONTAINING AN ELECTROCHEMICALLY ACTIVE REGION OF SILVER AND A SILVER HALIDE, A LAYER OF ELECTRICAL INSULATION DISPOSED BETWEEN THE METAL SURFACE BASE MEMBER OF THE ELECTRODE LEAD AND THE REFERENCE ELECTRODE., AND ELECTRODE, AND CONTACTING BOTH THE ELECTROCHEMICALLY ACTIVE REGIONS OF PALLADIUM OXIDE AND A PH ELECTRODE COMPRISING A SEPARATE PORTION OF THE METAL PERMEABLE, ION-IMPERMEABLE DIFFUSION BARRIER MATERIAL ENCAPSULATING AT LEAST THE ELECTROCHEMICALLY ACTIVE REGIONS AND THE ELECTROLYTE THEREBY PROVIDING A CARBON DIOXIDE SENSOR; AND A PH ELECTRODE COMPRISING A SEPARATE PORTION OF THE METAL SURFACED BASE MEMBER OF THE ELECTRODE LEAD AND AN ELECTROCHEMICALLY ACTIVE REGION OF PALLADIUM OXIDE ADHERING TIGHTLY TO AND IN ELECTRICAL CONTACT WITH THE METAL SURFACED BASED MEMBER AND EXPOSED EXTERIORLY OF THE OUTER SHEATHS.
Claim 3
Dependent Claim 26 words
In a miniature probe as in claim 1, in which there is a continuous outer sheath of oxygen and carbon dioxide permeable, ion-impermeable diffusion barier material.
Claim 4
Dependent Claim 16 words
In a miniature probe as in claim 1, in which both electrolytes are immobilized aqueous solutions.
Claim 5
Dependent Claim 31 words
In a miniature probe as in claim 1, in which both electrolytes are anion exchange resin material of quaternized polystyrene partially in its bicarbonate form and partially in its chloride form.
Claim 6
Dependent Claim 24 words
AN ANALYTICAL APPARATUS COMPRISING THE MINATURE PROBE OF CLAIM 1 AND A SEPARATE REFERENCE ELECTRODE CONNECTED ELETRICALLY TO THE PH ELECTRODE OF THE PROBE.
Claim 7
Dependent Claim 21 words
An analytical apparatus as in claim 5 in which the separate reference electrode surrounds and is insulated electrically from the probe.
Claim 8
Dependent Claim 22 words
An analytical apparatus as in claim 5 in which the separate reference electrode is spaced from the other elements of the probe.

References Cited (Backward Citations)

US3714015A Cited
US3709810A Cited
US3719575A Cited
US3705088A Cited
US3709812A Cited
US3730868A Cited
US3719576A Cited
US3671414A Cited
US3839178A Cited
US3794575A Cited
US3835013A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-01 1979-06-02 1979-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-01 1983-06-02 1983-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-01 1987-06-02 1987-12-02 $7700.00 Window Closed / Lapsed

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