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US3926773A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal anode for electrochemical processes and method of making same

Assignee: De Nora Deutschland GmbH
•
Filing: 1973-09-27
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Granted: 1975-12-16
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Expires: 1993-09-27
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Abstract

Abstract A valve metal anode, for electrolytical processes, having an electron-active covering layer, comprises electron-activating substances, counteracting passivation of the anode, anchored in a sintered porous carrier layer of valve metal. The carrier layer which is sintered onto the cleaned valve metal base may consist of a powder of the same metal or of the crystallographically similar metal. The infusion of the active substances into the carrier layer can be accomplished by impregnating and drying or baking the active substances, by precipitating them from the vapor phase, galvanically, or from the gaseous phase. The active substances may also be ingredients of the sinter mixture.

Inventors

  • 👤 Konrad Koziol
  • 👤 Hans-Carl Rathjen
  • 👤 Karl-Heinz Sieberer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:47
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; C25B11/051; C25B11/073

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 104 words
IN AN ANODE, FOR ELECTROLYTICAL PROCESSES, PARTICULARLY FOR CHLORINE-ALAKLI ELECTROLYSIS, HAVING A SOLID CORE OF VALVE METALS SELECTED FROM THE GROUP CONSISTING OF TITANIUM, TANTALUM, NIOBIUM, ZIRCONIUM, HAFNIUM, TUNGSTEN, MOLYBDENUM, AND ALLOYS THEREOF, AND HAVING A COVERING LAYER CONTAINING ACTIVATING SUBSTANCES COUNTERACTING PASSIVATION OF THE ANODE, SELECTED FROM THE GROUP CONSISTING OF METALS AND OXIDES OF THE PLATINUM METAL GROUP, MIXED OXIDES OF NOBLE AND IGNOBLE METALS, AND OXIDES OF IGNOBLE METALS ALONE: THE IMPROVEMENT IN WHICH THE ACTIVATING SUBSTANCES ARE ANCHORED IN A POROUS COVERING LAYER CONSISTING OF POWDERED VALVE METAL WHICH IS SINTERED TO THE SOLID VALVE METAL CORE OF THE ANODE.
Claim 2
Dependent Claim 104 words
IN AN ANODE, FOR ELECTROLYTICAL PROCESSES, PARTICULARLY FOR CHLORINE-ALAKLI ELECTROLYSIS, HAVING A SOLID CORE OF VALVE METALS SELECTED FROM THE GROUP CONSISTING OF TITANIUM, TANTALUM, NIOBIUM, ZIRCONIUM, HAFNIUM, TUNGSTEN, MOLYBDENUM, AND ALLOYS THEREOF, AND HAVING A COVERING LAYER CONTAINING ACTIVATING SUBSTANCES COUNTERACTING PASSIVATION OF THE ANODE, SELECTED FROM THE GROUP CONSISTING OF METALS AND OXIDES OF THE PLATINUM METAL GROUP, MIXED OXIDES OF NOBLE AND IGNOBLE METALS, AND OXIDES OF IGNOBLE METALS ALONE: THE IMPROVEMENT IN WHICH THE ACTIVATING SUBSTANCES ARE ANCHORED IN A POROUS COVERING LAYER CONSISTING OF POWDERED VALVE METAL WHICH IS SINTERED TO THE SOLID VALVE METAL CORE OF THE ANODE.
Claim 3
Dependent Claim 27 words
An anode, as claimed in claim 1, in which the active substances, in combination with the sintered covering layer form a compound material of valve metal/noble metal.
Claim 4
Dependent Claim 27 words
An anode, as claimed in claim 1, in which the active substances, in combination with the covering layer form a cermet-like compound material of valve metal ceramic.
Claim 5
Dependent Claim 21 words
An anode, as claimed in claim 3, in which the ceramic portion of the compound is composed of noble metal oxides.
Claim 6
Dependent Claim 25 words
An anode, as claimed in claim 3, in which the ceramic portion of the compound is composed of oxide mixtures of noble and ignoble metals.
Claim 7
Dependent Claim 23 words
An anode, as claimed in claim 3, in which the ceramic portion of the compound is composed solely of oxides of ignoble metals.
Claim 8
Dependent Claim 15 words
An anode, as claimed in claim 1, in which said porous covering layer comprises titanium.
Claim 9
Dependent Claim 15 words
An anode, as claimed in claim 1, in which said porous covering layer comprises tantalum.
Claim 10
Dependent Claim 18 words
An anode, as claimed in claim 1, in which said porous covering layer comprises a valve metal alloy.
Claim 11
Dependent Claim 20 words
An anode, as claimed in claim 1, in which said porous covering layer comprises a mixture of different valve metals.

References Cited (Backward Citations)

US2631115A Cited
US3458423A Cited
US3632498A Cited
US3663280A Cited
US3562008A Cited
US3672973A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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