US3937956A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Isotope separation process
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1973-10-23
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Granted: 1976-02-10
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Expires: 1993-10-23
Abstract
Abstract The instant invention relates to a process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in said material. In one embodiment, the invention relates to a method for the isotopically selective excitation of gas phase molecules by multiple infrared photon absorption followed by selective dissociation of said excited molecules by the absorption of a single photon of visible or ultraviolet light. This invention is useful for, but not limited to, the separation of the principal isotopes of uranium.
Inventors
- 👤 Richard K. Lyon
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:16
CPC Classifications
B; B01; B01D; B01D59/00; B01D59/34; B01J; B01J19/00; B01J19/08; B01J19/12; B01J19/121
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
179 words
A method of separating the isotopes of an element, said method being applied to a gaseous compound of said element, said method comprising subjecting the molecules of said compound to IR radiation at a predetermined frequency by means of an IR laser, said gaseous compound being irradiated by said IR laser at a power density of at least 10 4 watts per cm 2 per torr pressure of said gaseous compound for a time of between 10 - 10 and 5×10 - 5 seconds and wherein a second gas is present along with said gaseous compound, said second gas partial pressure being at least 5 times the partial pressure of said gaseous compound, whereby the molecules containing the lighter isotope or isotopes are preferentially excited and absorb more than one quanta of IR radiation, subjecting said gaseous mixture to radiation at the second predetermined frequency within the visible or ultraviolet spectrum, said second predetermined frequency being selected to convert said excited molecules to a form whereby they may be separated from the nonexcited molecules, and separating said converted molecules.
Claim 2
Independent Claim
179 words
A method of separating the isotopes of an element, said method being applied to a gaseous compound of said element, said method comprising subjecting the molecules of said compound to IR radiation at a predetermined frequency by means of an IR laser, said gaseous compound being irradiated by said IR laser at a power density of at least 10 4 watts per cm 2 per torr pressure of said gaseous compound for a time of between 10 - 10 and 5×10 - 5 seconds and wherein a second gas is present along with said gaseous compound, said second gas partial pressure being at least 5 times the partial pressure of said gaseous compound, whereby the molecules containing the lighter isotope or isotopes are preferentially excited and absorb more than one quanta of IR radiation, subjecting said gaseous mixture to radiation at the second predetermined frequency within the visible or ultraviolet spectrum, said second predetermined frequency being selected to convert said excited molecules to a form whereby they may be separated from the nonexcited molecules, and separating said converted molecules.
Claim 3
Dependent Claim
18 words
The method of claim 1 wherein said visible or ultraviolet radiation source is a visible or ultraviolet laser.
Claim 4
Dependent Claim
17 words
The method of claim 1 wherein the excited molecules are photodissociated by said visible or ultraviolet laser.
Claim 5
Dependent Claim
25 words
The method of claim 1 wherein said second gas is selected from the group consisting of hydrogen, nitrogen, oxygen, helium, neon, argon, krypton and xenon.
Claim 6
Dependent Claim
35 words
The method of claim 4 wherein said gaseous compound is subjected to IR light at an energy density of between 10 - 3 joules per cm 2 and 10 3 joules per cm 2 .
Claim 7
Dependent Claim
28 words
The method of claim 5 wherein said gaseous compound is subjected to radiation from said visible or ultraviolet laser for less than 5 × 10 - 5 seconds.
Claim 8
Dependent Claim
28 words
The method of claim 6 wherein said IR laser operates at a wave length corresponding to an R branch of a vibrational absorption band of said gaseous compound.
Claim 9
Dependent Claim
13 words
The method of claim 6 wherein said gaseous compound is UF 6 .
Claim 10
Dependent Claim
18 words
The method of claim 8 wherein said IR frequency ranges from 620 to 645 cm - 1 .
Claim 11
Dependent Claim
18 words
The method of claim 8 wherein said IR frequency ranges from 189 to 204 cm - 1 .
Claim 12
Dependent Claim
15 words
The method of claim 8 wherein said second predetermined frequency ranges from 2400 to 4600°A.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-09 | 1979-08-11 | 1980-02-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-09 | 1983-08-11 | 1984-02-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-09 | 1987-08-11 | 1988-02-10 | $7700.00 | Window Closed / Lapsed |