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US3959173A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel liquid membrane formulations and uses thereof

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1974-07-29
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Granted: 1976-05-25
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Expires: 1994-07-29
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Abstract

Abstract The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.

Inventors

  • 👤 Norman N. Li
  • 👤 Gopal H. Singhal
  • 👤 Richard M. Minday
  • 👤 Martin L. Gorbaty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:06
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/09; B; B01; B01D; B01D61/00; B01D61/38; B01D61/40

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 78 words
A water-in-oil emulsion comprising (a) an ethylene vinyl alkanoate copolymer, wherein the alkanoate group has from 1 to 20 carbons, comprising at least 25% by weight ethylene and (b) a solvent for said copolymer as the oil phase of the emulsion, the solvent having a boiling point of greater than 85° C and selected from the group consisting of petroleum distillates and paraffinic solvents including paraffinic solvents bearing substituents selected from the group consisting of halogen and aromatics.
Claim 2
Dependent Claim 78 words
A water-in-oil emulsion comprising (a) an ethylene vinyl alkanoate copolymer, wherein the alkanoate group has from 1 to 20 carbons, comprising at least 25% by weight ethylene and (b) a solvent for said copolymer as the oil phase of the emulsion, the solvent having a boiling point of greater than 85° C and selected from the group consisting of petroleum distillates and paraffinic solvents including paraffinic solvents bearing substituents selected from the group consisting of halogen and aromatics.
Claim 3
Dependent Claim 17 words
The composition of claim 1, wherein ethylene comprises from 25 to 75% by weight of said copolymer.
Claim 4
Dependent Claim 14 words
The composition of claim 2, wherein said copolymer is an ethylene vinyl acetate copolymer.
Claim 5
Dependent Claim 17 words
The composition of claim 2, wherein the molecular weight of said copolymer is from 500 to 10,000.
Claim 6
Dependent Claim 20 words
The composition of claim 2, wherein the aqueous interior phase comprises from 20 to 60 volume % of said emulsion.
Claim 7
Dependent Claim 19 words
The composition of claim 2, wherein said copolymer comprises from 2 to 30 weight percent of said oil phase.
Claim 8
Dependent Claim 11 words
The composition of claim 2, wherein said solvent is a hydrocarbon.
Claim 9
Dependent Claim 15 words
The composition of claim 2, wherein said aqueous phase comprises H 2 SO 4 .
Claim 10
Dependent Claim 17 words
The composition of claim 7, wherein said hydrocarbon solvent boils at a temperature of at least 85°C.
Claim 11
Dependent Claim 11 words
The composition of claim 9, wherein said hydrocarbon is an isoparaffin.

References Cited (Backward Citations)

US3410794A Cited
US3408290A Cited
US3794584A Cited
US3617546A Cited
US3779907A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-25 1979-11-24 1980-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-25 1983-11-24 1984-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-25 1987-11-24 1988-05-25 $7700.00 Window Closed / Lapsed

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