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US3962405A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the removal of sulfur oxides from waste gases

Assignee: Chevron USA Inc
•
Filing: 1973-04-16
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Granted: 1976-06-08
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Expires: 1993-04-16
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Abstract

Abstract The effectiveness of gas scrubbing process for the removal of sulfur dioxide from a sulfur-dioxide-containing gas is improved by employing an integrated scrubbing process.

Inventors

  • 👤 Richard J. Annesser
  • 👤 Robert J. Klett

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 00:44
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501; C; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C01B17/60

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 261 words
In a process for removing sulfur dioxide from a gaseous sulfur dioxide-containing feed by means of a lean aqueous sulfite-containing solution in a gas scrubbing zone, said lean solution comprising regenerated sulfite-containing solution and makeup solution by: a. introducing the lean solution into the scrubbing zone; b. introducing the feed into the scrubbing zone and into contact with the lean solution to form a fat solution and a resulting gas having a sulfur dioxide content which is less than the sulfur dioxide content of the feed gas; c. withdrawing the resulting gas from the gas scrubbing zone; d. withdrawing the fat solution from the gas scrubbing zone; e. passing the withdrawn fat solution into a stripping zone and forming gaseous sulfur dioxide and said regenerated solution by stripping said fat solution; f. withdrawing said sulfur dioxide gas from the stripping zone; and g. withdrawing the regenerated solution from the stripping zone and forming said lean solution by adding makeup solution, said makeup solution being aqueous alkaline caustic selected from the group consisting of alkali metal hydroxide, carbonate and mixtures thereof; the improvement which comprises scrubbing said resulting gas with at least a portion of said makeup solution prior to said addition, said scrubbing being effected by employing at least sufficient of said makeup solution to maintain the process in balance and to provide a degree of gas scrubbing corresponding to at least a single tray in a tray-type gas scrubbing tower, thereby reducing the sulfur dioxide content of the resulting effluent gas stream to a value less than about 75 ppm.
Claim 2
Dependent Claim 261 words
In a process for removing sulfur dioxide from a gaseous sulfur dioxide-containing feed by means of a lean aqueous sulfite-containing solution in a gas scrubbing zone, said lean solution comprising regenerated sulfite-containing solution and makeup solution by: a. introducing the lean solution into the scrubbing zone; b. introducing the feed into the scrubbing zone and into contact with the lean solution to form a fat solution and a resulting gas having a sulfur dioxide content which is less than the sulfur dioxide content of the feed gas; c. withdrawing the resulting gas from the gas scrubbing zone; d. withdrawing the fat solution from the gas scrubbing zone; e. passing the withdrawn fat solution into a stripping zone and forming gaseous sulfur dioxide and said regenerated solution by stripping said fat solution; f. withdrawing said sulfur dioxide gas from the stripping zone; and g. withdrawing the regenerated solution from the stripping zone and forming said lean solution by adding makeup solution, said makeup solution being aqueous alkaline caustic selected from the group consisting of alkali metal hydroxide, carbonate and mixtures thereof; the improvement which comprises scrubbing said resulting gas with at least a portion of said makeup solution prior to said addition, said scrubbing being effected by employing at least sufficient of said makeup solution to maintain the process in balance and to provide a degree of gas scrubbing corresponding to at least a single tray in a tray-type gas scrubbing tower, thereby reducing the sulfur dioxide content of the resulting effluent gas stream to a value less than about 75 ppm.
Claim 3
Dependent Claim 15 words
The process as in claim 1, wherein said process is a countercurrent gas scrubbing process.
Claim 4
Dependent Claim 27 words
The process as in claim 1, wherein the remainder of the gas comprises one or more gases of the group carbon dioxide, carbon monoxide, nitrogen, and hydrogen.
Claim 5
Dependent Claim 180 words
In a process wherein sulfur dioxide is scrubbed from a sulfur dioxide-containing gas stream in countercurrent contact in a gas scrubbing zone with a lean aqueous sulfite-containing solution comprising regenerated sulfite-containing solution and makeup solution, said makeup being aqueous caustic solution selected from the group consisting of alkali metal hydroxide, carbonate and mixtures thereof, wherein a scrubbed gas product of reduced sulfur dioxide content and used scrubbing solution are withdrawn from said zone, wherein sulfur dioxide is removed from said used solution to produce said regenerated solution, and wherein said regenerated solution is returned to said zone, the improvement which comprises countercurrently contacting said gas stream with said regenerated solution and then contacting said gas stream with said makeup solution, said scrubbing being effected by employing at least sufficient of said makeup solution to maintain the process in balance and to provide a degree of gas scrubbing corresponding to at least a single tray in a tray-type gas scrubbing tower, thereby reducing the sulfur dioxide content of the resulting effluent gas stream to a value less than about 75 ppm.
Claim 6
Dependent Claim 180 words
In a process wherein sulfur dioxide is scrubbed from a sulfur dioxide-containing gas stream in countercurrent contact in a gas scrubbing zone with a lean aqueous sulfite-containing solution comprising regenerated sulfite-containing solution and makeup solution, said makeup being aqueous caustic solution selected from the group consisting of alkali metal hydroxide, carbonate and mixtures thereof, wherein a scrubbed gas product of reduced sulfur dioxide content and used scrubbing solution are withdrawn from said zone, wherein sulfur dioxide is removed from said used solution to produce said regenerated solution, and wherein said regenerated solution is returned to said zone, the improvement which comprises countercurrently contacting said gas stream with said regenerated solution and then contacting said gas stream with said makeup solution, said scrubbing being effected by employing at least sufficient of said makeup solution to maintain the process in balance and to provide a degree of gas scrubbing corresponding to at least a single tray in a tray-type gas scrubbing tower, thereby reducing the sulfur dioxide content of the resulting effluent gas stream to a value less than about 75 ppm.

References Cited (Backward Citations)

US2615787A Cited
US3285711A Cited
US3428424A Cited
US3428420A Cited
US3653812A Cited
US3832444A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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