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US3963618A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel polymer membranes for reverse osmosis

Assignee: Babcock International Ltd
•
Filing: 1974-07-25
•
Granted: 1976-06-15
•
Expires: 1994-07-25
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Abstract

Abstract This case is directed to the preparation of polyvinyl acetal resins as semi-permeable membranes for use in the treatment of feed solutions by reverse osmosis, ultafiltration or related techinques.

Inventors

  • 👤 William McClements Muir

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 16:53
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/38; B01D71/383; C; C08; C08F; C08F8/00; C08F8/48; C08J; C08J5/00; C08J5/18; C08F2810/00; C08F2810/30

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 179 words
A semi-permeable membrane for use in the treatment of feed solutions by reverse osmosis, ultrafiltration or related techniques consisting essentially of a polyvinyl coacetal resin having a backbone chain of the general formula -X.sup.1 -X.sup.2 -X.sup.3 -X.sup.4 -X.sup.5 . . . . X.sup.n - wherein each X of X 1 , X 2 . . . X n is selected from the group consisting of hydroxy-bis-methylene --CH 2 --CH(OH)--, acetoxy-bis-methylene --CH 2 --CH(OCO.CH 3 )--, a first acetal group --CH.sub.2 --CH--CH.sub.2 --CH-- || OO ∠ ∠ R.sup.1 H and a second acetal group --CH.sub.2 --CH--CH.sub.2 --CH-- || OO ∠ C ∠ R.sup.2 H provided that said first and second acetal groups are both present and together comprise 25 to 100% of the chain, said groups R 1 and R 2 being different and each being selected from the group consisting of a hydrogen atom, straight or branched alkyl or alkenyl groups containing up to 6 carbon atoms and phenylalkyl or phenylalkenyl groups wherein the alkyl or alkenyl group is straight or branched and contains up to 6 carbon atoms.
Claim 2
Dependent Claim 179 words
A semi-permeable membrane for use in the treatment of feed solutions by reverse osmosis, ultrafiltration or related techniques consisting essentially of a polyvinyl coacetal resin having a backbone chain of the general formula -X.sup.1 -X.sup.2 -X.sup.3 -X.sup.4 -X.sup.5 . . . . X.sup.n - wherein each X of X 1 , X 2 . . . X n is selected from the group consisting of hydroxy-bis-methylene --CH 2 --CH(OH)--, acetoxy-bis-methylene --CH 2 --CH(OCO.CH 3 )--, a first acetal group --CH.sub.2 --CH--CH.sub.2 --CH-- || OO ∠ ∠ R.sup.1 H and a second acetal group --CH.sub.2 --CH--CH.sub.2 --CH-- || OO ∠ C ∠ R.sup.2 H provided that said first and second acetal groups are both present and together comprise 25 to 100% of the chain, said groups R 1 and R 2 being different and each being selected from the group consisting of a hydrogen atom, straight or branched alkyl or alkenyl groups containing up to 6 carbon atoms and phenylalkyl or phenylalkenyl groups wherein the alkyl or alkenyl group is straight or branched and contains up to 6 carbon atoms.
Claim 3
Dependent Claim 11 words
The semi-permeable membrane of claim 1 which is of tubular form.
Claim 4
Dependent Claim 11 words
The semi-permeable membrane of claim 1 which is of flat form.
Claim 5
Dependent Claim 19 words
A semi-permeable membrane according to claim 1, wherein the two acetal groups comprise 85 to 100% of the chain.
Claim 6
Dependent Claim 29 words
A semi-permeable membrane according to claim 1, wherein the amount of acetoxy-bis-methylene groups in the chain is substantially zero or at the most up to 2% of the chain.
Claim 7
Dependent Claim 31 words
A semi-permeable membrane according to claim 1, wherein R 1 and R 2 are different and are selected from a hydrogen atom, and methyl, ethyl, propyl, iso-propyl, prop-1-enyl and phenylethenyl groups.
Claim 8
Dependent Claim 32 words
A semi-permeable membrane according to claim 6, wherein the polyvinyl co-acetal resin is selected from polyvinyl propional - cinnamal, polyvinyl acetal - cinnamal, polyvinyl acetal - butyral, and polyvinyl propional - isobutyral.

References Cited (Backward Citations)

US2326048A Cited
US2387833A Cited
US2915504A Cited
US2981718A Cited
US3170869A Cited
US3907675A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-15 1979-12-15 1980-06-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-15 1983-12-15 1984-06-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-15 1987-12-15 1988-06-15 $7700.00 Window Closed / Lapsed

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