US3964256A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of non-toxic gas by combustion of solid propellant
Assignee: Societe Nationale des Poudres et Explosifs
•
Filing: 1973-10-10
•
Granted: 1976-06-22
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Expires: 1993-10-10
Abstract
Abstract A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, comprises:
Inventors
- 👤 Bernard E. Plantif
- 👤 Bernard J. Doin
- 👤 Jean S. Beaumont
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 13:18
CPC Classifications
C; C06; C06D; C06D5/00; C06D5/06
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
210 words
A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, which comprises the steps of: a. effecting combustion of a pyrotechnic charge consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent said inorganic oxidant being selected from the group consisting of alkali metal and alkaline earth metal perchlorates and a low content of a carbonaceous, oxygen-containing, binder not exceeding 17 percent, said binder being selected from the group consisting of cellulose triacetate and silicone resins, the remaining ingredients being free of nitrogenous compounds; in a combustion chamber to produce a substantial volume of combustion gases at an elevated temperature, b. passing the hot combustion gases through a first cooling phase in which the hot combustion gases are diluted with oxygen obtained by the thermal decomposition of an oxygen-containing inorganic compound which has a low thermal stability and liberates, in gaseous form, only oxygen, whereby the combustion gases are cooled to a temperature of from 225° to 700°C, and c. passing the gaseous mixture from step (b) to a second cooling phase in which the gas mixture from the first cooling phase is cooled by contact with cooling means to the temperature of utilization.
Claim 2
Dependent Claim
210 words
A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, which comprises the steps of: a. effecting combustion of a pyrotechnic charge consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent said inorganic oxidant being selected from the group consisting of alkali metal and alkaline earth metal perchlorates and a low content of a carbonaceous, oxygen-containing, binder not exceeding 17 percent, said binder being selected from the group consisting of cellulose triacetate and silicone resins, the remaining ingredients being free of nitrogenous compounds; in a combustion chamber to produce a substantial volume of combustion gases at an elevated temperature, b. passing the hot combustion gases through a first cooling phase in which the hot combustion gases are diluted with oxygen obtained by the thermal decomposition of an oxygen-containing inorganic compound which has a low thermal stability and liberates, in gaseous form, only oxygen, whereby the combustion gases are cooled to a temperature of from 225° to 700°C, and c. passing the gaseous mixture from step (b) to a second cooling phase in which the gas mixture from the first cooling phase is cooled by contact with cooling means to the temperature of utilization.
Claim 3
Dependent Claim
30 words
A process according to claim 1, wherein said propellant comprises cellulose triacetate as a binder and also comprises a plasticiser selected from the group consisting of triacetin and tricresyl phosphate.
Claim 4
Dependent Claim
44 words
A process according to claim 2, wherein said propellant also comprises, as a modifying agent, at least one of carbon black in an amount of up to 0.5 percent by weight and aluminum powder in an amount of up to 5 percent by weight.
Claim 5
Dependent Claim
54 words
A process according to claim 1, wherein said propellant has the following composition, in parts by weight: potassium perchlorate
in excess of
80 to 92
cellulose triacetate 8.5 to 17
plasticiser selected from the
group consisting of triacetin
and tricresyl phosphate 1 to 3
acetylene black 0.15 to 0.5
aluminium powder 0.5 to 2.
Claim 6
Dependent Claim
42 words
A process according to claim 1, wherein said propellant has the following composition in parts by weight: potassium perchlorate 88
cellulose triacetate 10
plasticiser selected from the
group consisting of triac-
etin and tricresyl phosphate
2.5
acetylene black 0.2
aluminium powder 1.
Claim 7
Dependent Claim
56 words
A process according to claim 1 wherein said propellant has the following composition, in parts by weight: potassium perchlorate
in excess of
80 to 92
silicone resin having a carbon
content of less than 33% 8.5 to 14
catalyst for said silicone resin
0.8 to 1.5
acetylene black 0.15 to 0.5
aluminium powder 0.5 to 2.
Claim 8
Dependent Claim
62 words
A process according to claim 1, wherein said oxygen-containing inorganic compound used in step (b) has a decomposition temperature of from 225° to 700°C, said compound being in the form of granules or pellets containing a non-oxidisable binder, in an amount between 1 and 7 percent, said binder being selected from the group consisting of aluminum stearate, potassium bromide, plaster and cement.
Claim 9
Dependent Claim
29 words
A process according to claim 1, wherein said cooling means used in step (c) consists of a compound which decomposes at a temperature below 200°C to produce a gas.
Claim 10
Dependent Claim
33 words
A process according to claim 8, wherein said compound is selected from the group consisting of alkali metal and alkaline earth metal oxalates, carbonates and bicarbonates, and is in the form of pellets.
Claim 11
Dependent Claim
18 words
A process according to claim 1, wherein said cooling means used in step (c) comprises a heat exchanger.
Claim 12
Independent Claim
147 words
An apparatus adapted to inflate a safety device in a moving vehicle, comprising a combustion chamber, a solid pyrotechnic composition located in said combustion chamber, said composition consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent, and a low content of a carbonaceous, oxygen-containing binder not exceeding 17 percent, the remaining ingredient being free of nitrogenous compounds, said composition producing hot gaseous products on ignition, ignition means in said combustion chamber, means for discharging the gaseous products from the combustion chamber into a first cooling chamber, an oxygen-containing inorganic compound of low thermal stability in said first cooling chamber capable of liberating only oxygen from under the action of heat from said gaseous products, a second cooling chamber arranged to receive said gaseous products from the first cooling chamber and cooling means in said second cooling chamber.
Claim 13
Independent Claim
147 words
An apparatus adapted to inflate a safety device in a moving vehicle, comprising a combustion chamber, a solid pyrotechnic composition located in said combustion chamber, said composition consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent, and a low content of a carbonaceous, oxygen-containing binder not exceeding 17 percent, the remaining ingredient being free of nitrogenous compounds, said composition producing hot gaseous products on ignition, ignition means in said combustion chamber, means for discharging the gaseous products from the combustion chamber into a first cooling chamber, an oxygen-containing inorganic compound of low thermal stability in said first cooling chamber capable of liberating only oxygen from under the action of heat from said gaseous products, a second cooling chamber arranged to receive said gaseous products from the first cooling chamber and cooling means in said second cooling chamber.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-22 | 1979-12-22 | 1980-06-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-22 | 1983-12-22 | 1984-06-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-22 | 1987-12-22 | 1988-06-22 | $7700.00 | Window Closed / Lapsed |