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US3964256A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of non-toxic gas by combustion of solid propellant

Assignee: Societe Nationale des Poudres et Explosifs
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Filing: 1973-10-10
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Granted: 1976-06-22
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Expires: 1993-10-10
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Abstract

Abstract A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, comprises:

Inventors

  • 👤 Bernard E. Plantif
  • 👤 Bernard J. Doin
  • 👤 Jean S. Beaumont

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:18
CPC Classifications
C; C06; C06D; C06D5/00; C06D5/06

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 210 words
A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, which comprises the steps of: a. effecting combustion of a pyrotechnic charge consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent said inorganic oxidant being selected from the group consisting of alkali metal and alkaline earth metal perchlorates and a low content of a carbonaceous, oxygen-containing, binder not exceeding 17 percent, said binder being selected from the group consisting of cellulose triacetate and silicone resins, the remaining ingredients being free of nitrogenous compounds; in a combustion chamber to produce a substantial volume of combustion gases at an elevated temperature, b. passing the hot combustion gases through a first cooling phase in which the hot combustion gases are diluted with oxygen obtained by the thermal decomposition of an oxygen-containing inorganic compound which has a low thermal stability and liberates, in gaseous form, only oxygen, whereby the combustion gases are cooled to a temperature of from 225° to 700°C, and c. passing the gaseous mixture from step (b) to a second cooling phase in which the gas mixture from the first cooling phase is cooled by contact with cooling means to the temperature of utilization.
Claim 2
Dependent Claim 210 words
A process for the rapid production of a substantial volume of non-toxic gas at a moderate temperature, which comprises the steps of: a. effecting combustion of a pyrotechnic charge consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent said inorganic oxidant being selected from the group consisting of alkali metal and alkaline earth metal perchlorates and a low content of a carbonaceous, oxygen-containing, binder not exceeding 17 percent, said binder being selected from the group consisting of cellulose triacetate and silicone resins, the remaining ingredients being free of nitrogenous compounds; in a combustion chamber to produce a substantial volume of combustion gases at an elevated temperature, b. passing the hot combustion gases through a first cooling phase in which the hot combustion gases are diluted with oxygen obtained by the thermal decomposition of an oxygen-containing inorganic compound which has a low thermal stability and liberates, in gaseous form, only oxygen, whereby the combustion gases are cooled to a temperature of from 225° to 700°C, and c. passing the gaseous mixture from step (b) to a second cooling phase in which the gas mixture from the first cooling phase is cooled by contact with cooling means to the temperature of utilization.
Claim 3
Dependent Claim 30 words
A process according to claim 1, wherein said propellant comprises cellulose triacetate as a binder and also comprises a plasticiser selected from the group consisting of triacetin and tricresyl phosphate.
Claim 4
Dependent Claim 44 words
A process according to claim 2, wherein said propellant also comprises, as a modifying agent, at least one of carbon black in an amount of up to 0.5 percent by weight and aluminum powder in an amount of up to 5 percent by weight.
Claim 5
Dependent Claim 54 words
A process according to claim 1, wherein said propellant has the following composition, in parts by weight: potassium perchlorate in excess of 80 to 92 cellulose triacetate 8.5 to 17 plasticiser selected from the group consisting of triacetin and tricresyl phosphate 1 to 3 acetylene black 0.15 to 0.5 aluminium powder 0.5 to 2.
Claim 6
Dependent Claim 42 words
A process according to claim 1, wherein said propellant has the following composition in parts by weight: potassium perchlorate 88 cellulose triacetate 10 plasticiser selected from the group consisting of triac- etin and tricresyl phosphate 2.5 acetylene black 0.2 aluminium powder 1.
Claim 7
Dependent Claim 56 words
A process according to claim 1 wherein said propellant has the following composition, in parts by weight: potassium perchlorate in excess of 80 to 92 silicone resin having a carbon content of less than 33% 8.5 to 14 catalyst for said silicone resin 0.8 to 1.5 acetylene black 0.15 to 0.5 aluminium powder 0.5 to 2.
Claim 8
Dependent Claim 62 words
A process according to claim 1, wherein said oxygen-containing inorganic compound used in step (b) has a decomposition temperature of from 225° to 700°C, said compound being in the form of granules or pellets containing a non-oxidisable binder, in an amount between 1 and 7 percent, said binder being selected from the group consisting of aluminum stearate, potassium bromide, plaster and cement.
Claim 9
Dependent Claim 29 words
A process according to claim 1, wherein said cooling means used in step (c) consists of a compound which decomposes at a temperature below 200°C to produce a gas.
Claim 10
Dependent Claim 33 words
A process according to claim 8, wherein said compound is selected from the group consisting of alkali metal and alkaline earth metal oxalates, carbonates and bicarbonates, and is in the form of pellets.
Claim 11
Dependent Claim 18 words
A process according to claim 1, wherein said cooling means used in step (c) comprises a heat exchanger.
Claim 12
Independent Claim 147 words
An apparatus adapted to inflate a safety device in a moving vehicle, comprising a combustion chamber, a solid pyrotechnic composition located in said combustion chamber, said composition consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent, and a low content of a carbonaceous, oxygen-containing binder not exceeding 17 percent, the remaining ingredient being free of nitrogenous compounds, said composition producing hot gaseous products on ignition, ignition means in said combustion chamber, means for discharging the gaseous products from the combustion chamber into a first cooling chamber, an oxygen-containing inorganic compound of low thermal stability in said first cooling chamber capable of liberating only oxygen from under the action of heat from said gaseous products, a second cooling chamber arranged to receive said gaseous products from the first cooling chamber and cooling means in said second cooling chamber.
Claim 13
Independent Claim 147 words
An apparatus adapted to inflate a safety device in a moving vehicle, comprising a combustion chamber, a solid pyrotechnic composition located in said combustion chamber, said composition consisting of a composite solid propellant having a high content of inorganic non-nitrogenous oxidant in excess of 80 percent, and a low content of a carbonaceous, oxygen-containing binder not exceeding 17 percent, the remaining ingredient being free of nitrogenous compounds, said composition producing hot gaseous products on ignition, ignition means in said combustion chamber, means for discharging the gaseous products from the combustion chamber into a first cooling chamber, an oxygen-containing inorganic compound of low thermal stability in said first cooling chamber capable of liberating only oxygen from under the action of heat from said gaseous products, a second cooling chamber arranged to receive said gaseous products from the first cooling chamber and cooling means in said second cooling chamber.

References Cited (Backward Citations)

US2946671A Cited
US2566560A Cited
US3222230A Cited
US3171764A Cited
US3214308A Cited
US3197349A Cited
US3453156A Cited
US3738878A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-22 1979-12-22 1980-06-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-22 1983-12-22 1984-06-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-22 1987-12-22 1988-06-22 $7700.00 Window Closed / Lapsed

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