Gels of nonpolar liquids with N-acyl amino acids and derivatives thereof as gelling agents

Claim 2

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than about 20 and having a solubility less than 10% by weight in water with an effective gel forming amount of at least one compound containing an N-acylamino acid component having the formula: ##EQU7## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkylacyl group; Z is selected from the group consisting of hydroxy, -NH 2 , -OR 1 , -NHR 2 , ##EQU8## and -0 -R 5 NH 3 + wherein R 1 , R 2 , R 3 , R 4 and R 5 are selected from the group consisting of C 1 to C 30 aliphatic hydrocarbon groups and aralkyl groups; X is selected from the group consisting of hydrogen and methyl; and Y is selected from the group consisting of ##EQU9## wherein R 6 is C 1 to C 4 alkyl, benzyl, phenyl, --CH 2 OH, ##EQU10## --CH 2 SH, --CH 2 CH 2 --S-CH 3 or -- (CH 2 ) p --COZ and p is a positive integer of 1 or 2 and Z is the same as above, --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above and --(CH 2 ) n --, wherein n is a positive integer of 1 to 6; with the proviso that when Z is --OR 1 , ##EQU11## where R 6 is --(CH 2 ) m NHCOR and that at least one of R, R 1 , R 2 , R 3 , R 4 and R 5 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 3

The process of claim 1, wherein said homogeneous admixing is conducted at temperatures ranging from room temperature up to the boiling point of said non-polar organic liquid.

Claim 4

The process of claim 1, wherein said compound containing an N-acylamino acid component is admixed with said non-polar organic liquid in the form of very fine powdered particles or as a solution.

Claim 5

The process of claim 1, wherein the effective gel forming amount of said compound containing an N-acylamino acid component added to said non-polar organic liquid is 0.05% to 20% by weight.

Claim 6

A process for preparing a gel, which comprises: mixing a non-polar organic liquid having a dielectric constant of less than about 20 and having a solubility less than 10% by weight in water with 0.05 - 20% by weight based on said non-polar organic liquid of a compound containing an N-acylamino acid component having the formula (I), ##EQU12## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is selected from the group consisting of hydroxy, --NH 2 , --OR 1 , --NHR 2 , ##EQU13## and --O -R 5 NH 3 + , wherein R 1 , R 2 , R 3 , R 4 and R 5 are selected from the group consisting of C 1 to C 30 aliphatic hydrocarbon radicals and aralkyl radicals; X is selected from the group consisting of hydrogen and methyl; Y is selected from the group consisting of ##EQU14## wherein R 6 is C 1 to C 4 alkyl, benzyl, phenyl, --CH 2 OH, ##EQU15## --CH 2 SH, --CH 2 CH 2 --S--CH 3 or --(CH 2) p --COZ and p is a positive integer of 1 or 2 and Z is the same as above, --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, and --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that when Z is -OR 1 , ##EQU16## wherein R 6 is --(CH 2 ) m NHCOR and that at least one of R, R 1 , R 2 , R 3 , R 4 and R 5 is a C 6 to C 30 aliphatic hydrocarbon group; heating the mixture to effect solution; cooling the resulting solution to room temperature; and thereafter; allowing said cooled solution to stand until gel formation occurs.

Claim 7

A process for preparing a gel, which comprises: mixing a non-polar organic liquid having a dielectric constant of less than about 20 and having a solubility less than 10% by weight in water with 0.05 - 20% by weight based on said non-polar organic liquid of a compound containing an N-acylamino acid component having the formula (I), ##EQU12## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is selected from the group consisting of hydroxy, --NH 2 , --OR 1 , --NHR 2 , ##EQU13## and --O -R 5 NH 3 + , wherein R 1 , R 2 , R 3 , R 4 and R 5 are selected from the group consisting of C 1 to C 30 aliphatic hydrocarbon radicals and aralkyl radicals; X is selected from the group consisting of hydrogen and methyl; Y is selected from the group consisting of ##EQU14## wherein R 6 is C 1 to C 4 alkyl, benzyl, phenyl, --CH 2 OH, ##EQU15## --CH 2 SH, --CH 2 CH 2 --S--CH 3 or --(CH 2) p --COZ and p is a positive integer of 1 or 2 and Z is the same as above, --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, and --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that when Z is -OR 1 , ##EQU16## wherein R 6 is --(CH 2 ) m NHCOR and that at least one of R, R 1 , R 2 , R 3 , R 4 and R 5 is a C 6 to C 30 aliphatic hydrocarbon group; heating the mixture to effect solution; cooling the resulting solution to room temperature; and thereafter; allowing said cooled solution to stand until gel formation occurs.

Claim 8

The process of claim 5, wherein said non-polar organic liquid is a liquid hydrocarbon.

Claim 9

The process of claim 6, wherein said liquid hydrocarbon is selected from the group consisting of gasoline, naphthas, kerosine, gas oil, heavy oil, crude oil, spindle oil, turbine oil, liquid paraffin, benzene, oxlene, toluene, hexane, heptane, octane and cyclohexane.

Claim 10

The process of claim 5, wherein said non-polar organic liquid is a fatty oil.

Claim 11

The process of claim 8, wherein said fatty oil is selected from the group consisting of corn oil, soybean oil, olive oil, rape seed oil and cotton seed oil.

Claim 12

The process of claim 5, wherein said non-polar organic liquid is an ester.

Claim 13

The process of claim 10, wherein said ester is selected from the group consisting of butyl acetate, diethyl phthalate, dioctyl phthalate, dioctyl sebacate and tricresyl phosphate.

Claim 14

The process of claim 5, wherein said non-polar organic liquid is a ketone selected from the group consisting of methyl isobutyl ketone and diisobutyl ketone.

Claim 15

The process of claim 5, wherein said non-polar organic liquid is a normally liquid polyoxyalkylene monoalkyl ether.

Claim 16

The process of claim 13, wherein said polyoxyalkylene monoalkyl ether is polyoxyethylene monolauryl ether containing 4 to 6 oxyethylene units or polyoxypropylene monoalkyl ethers wherein the alkyl group has 4 to 12 carbon atoms and the number of oxypropylene units is 10 to 50.

Claim 17

The process of claim 5, wherein said non-polar organic liquid is a normally liquid polyoxyalkylene glycol fatty acid ester.

Claim 18

The process of claim 15, wherein said polyoxyalkylene glycol fatty acid ester is polyoxyethylene lauric or oleic acid ester containing 4 to 6 oxyethylene units.

Claim 19

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than about 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of at least one compound containing an N-acylamino acid component having the formula ##EQU17## wherein RCO is a C 5 to C 30 aliphatic acyl, and Y is selected from the group consisting of ##EQU18## wherein R 6 is a C 1 to C 4 alkyl and --(CH 2 ).sub. m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above; and allowing the mixture to stand until gel formation occurs.

Claim 20

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than about 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of at least one compound containing an N-acylamino acid component having the formula ##EQU17## wherein RCO is a C 5 to C 30 aliphatic acyl, and Y is selected from the group consisting of ##EQU18## wherein R 6 is a C 1 to C 4 alkyl and --(CH 2 ).sub. m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above; and allowing the mixture to stand until gel formation occurs.

Claim 21

The process of claim 17, wherein said compound containing an N-acylamino acid component is selected from the group consisting of N-lauroylalanine, N.sup.α, N.sup.δ-dicaproyl ornithine, N.sup.α,N.sup.δ-dicapryloyl orinthine, N.sup.α,N.sup.δ-dilauroylornithine, N.sup.α,N.sup.ε-dicocoylornithine, N.sup.α,N.sup.ε-dicaproyllysine and N.sup.α,N.sup.ε-dicapryloyllysine.

Claim 22

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing N-acylamino acid component having the formula ##EQU19## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkylacyl group; R 1 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl; and ##EQU20## wherein R 6 is --(CH 2 ) m NHCOR, m is a positive integer of 3 or 4 and RCO is the same as above, with the proviso that at least one of R and R 1 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 23

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing N-acylamino acid component having the formula ##EQU19## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkylacyl group; R 1 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl; and ##EQU20## wherein R 6 is --(CH 2 ) m NHCOR, m is a positive integer of 3 or 4 and RCO is the same as above, with the proviso that at least one of R and R 1 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 24

The process of claim 19, wherein said compound containing an N-acylamino acid component is an N.sup.α,N.sup.δ-dicapryloylornithine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.δ-dilauroylornithine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.δ-dicocoylornithine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.δ-distearoylornithine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.δ-ditallowylornithinealkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.ε-dicapryloyllysine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.ε-dilauroyllysine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.ε-dicocoyllysine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms; N.sup.α,N.sup.ε-distearoyllysine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms or N.sup.α,N.sup.ε-ditallowyllysine alkyl ester, wherein said alkyl group has 6 to 18 carbon atoms.

Claim 25

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing an N-acylamino acid component having the formula ##EQU21## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is --NH 2 , --NHR 2 or ##EQU22## wherein R 2 , R 3 and R 4 are selected from the group consisting of C 1 to C 30 aliphatic hydrocarbon groups and aralkyl groups; and ##EQU23## wherein R 6 is C 1 to C 4 alkyl, benzyl, --CH 2 CH 2 --S--CH 3 , or --(CH 2 ) p -COZ wherein p is a positive integer of 1 or 2 and Z is the same as above; --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above and --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that at least one of R, R 2 , R 3 , and R 4 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 26

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing an N-acylamino acid component having the formula ##EQU21## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is --NH 2 , --NHR 2 or ##EQU22## wherein R 2 , R 3 and R 4 are selected from the group consisting of C 1 to C 30 aliphatic hydrocarbon groups and aralkyl groups; and ##EQU23## wherein R 6 is C 1 to C 4 alkyl, benzyl, --CH 2 CH 2 --S--CH 3 , or --(CH 2 ) p -COZ wherein p is a positive integer of 1 or 2 and Z is the same as above; --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above and --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that at least one of R, R 2 , R 3 , and R 4 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 27

The process of claim 21, wherein said compound containing an N-acylamino acid component is N-acetyl glutamic acid-α,γ-dialkyl amide, wherein said alkyl group has 12 to 18 carbon atoms; N-capryloylglutamic acid-α,γ-diamide, N-caprylyl glutamic acid-α,γ-dialkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N-lauroylglutamic acid-α,γ-diamide, N-lauroylglutamic acid-α,γ-dialkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N-cocoylglutamic acid-α,γ-diamide, N-cocoylglutamic acid-α,γ-dialkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N-stearoylglutamic acid-α,γ-diamide, N-stearoylglutamic acid-α,γ-dialkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N-tallowylglutamic acid-α,γ-diamide, N-(tallowyl)glutamic acid-α,γ-dialkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N.sup.α,N.sup.ε-diacetyllysine alkylamide, wherein said alkyl group has 12 to 18 carbon atoms; N.sup.α,N.sup.ε-dicapryloyllysine amide, N.sup.α,N.sup.ε-dicapryloyllysine alkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N.sup.α,N.sup.ε-dilauroyllysine amide, N.sup.α,N.sup.ε-dilauroyllysine alkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N.sup.α,N.sup.ε-dicocoyllysine amide, N.sup.α,N.sup.ε-dicocoyllysine alkylamide, wherein said alkyl group has 1 to 18 carbon atoms; N.sup.α,N.sup.ε-distearoyllysine amide, N.sup.α,N.sup.ε-distearoyllysine alkylamide, wherein said alkyl group has 1 to 18 carbon atoms; or N.sup.α,N.sup.ε-di(tallowyl)lysine amide, N.sup.α,N.sup.ε-di(tallowyl)lysine alkylamide, wherein said alkyl group has 1 to 18 carbon atoms.

Claim 28

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing an N-acylamino acid component having the formula ##EQU24## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; R 5 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl; and Y ##EQU25## wherein R 6 is selected from the group consisting of C 1 to C 4 alkyl, benzyl or --(CH 2 ) m NHCOR, and m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 5 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 29

A process for preparing a gel, which comprises: homogeneously admixing a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water with 0.05% to 20% by weight of a compound containing an N-acylamino acid component having the formula ##EQU24## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; R 5 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl; and Y ##EQU25## wherein R 6 is selected from the group consisting of C 1 to C 4 alkyl, benzyl or --(CH 2 ) m NHCOR, and m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 5 is a C 5 to C 30 aliphatic hydrocarbon group; and allowing the mixture to stand until gel formation occurs.

Claim 30

The process of claim 23, wherein said compound containing an N-acylamino acid component is an N.sup.α,N.sup.δ-dicapryloyllysine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms; an N.sup.α,N.sup.ε-dilauroyllysine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.ε-dicocoyllysine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.ε-distearoyllysine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.ε-ditallowyllysine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.ε-dicapryloylornithine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms; an N.sup.α,N.sup.δ-dilauroylornithine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.δ-dicocoylornithine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.δdistearoylornithine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N.sup.α,N.sup.δ-ditallowylornithine alkylamine salt, wherein said alkylamine has 4 to 18 carbon atoms; an N-lauroylphenylalanine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms; an N-cocoylphenylalanine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms; an N-stearoylphenylalanine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms, or an N-tallowylphenylalanine alkylamine salt, wherein said alkylamine has 8 to 18 carbon atoms.

Claim 31

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one compound containing an N-acylamino acid component having the formula ##EQU26## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is hydroxy, --NH 2 , --OR 1 , --NHR 2 , ##EQU27## or --O -R 5 NH 3 + , wherein R 1 , R 2 , R 3 , R 4 and R 5 is a C 2 to C 30 aliphatic hydrocarbon group and aralkyl groups; X is hydrogen or methyl; and ##EQU28## wherein R 6 is C 1 to C 4 alkyl, benzyl, phenyl, --CH 2 OH, ##EQU29## --CH 2 SH, --CH 2 CH 2 --S--CH 3 or --(CH 2 ) p COZ; and p is a positive integer of 1 or 2, and Z is the same as above; --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, or --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that when Z is --OR 1 , ##EQU30## wherein R 6 is --(CH 2 ) m NHCOR and that at least one of R, R 1 , R 2 , R 3 , R 4 and R 5 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 32

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one compound containing an N-acylamino acid component having the formula ##EQU26## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is hydroxy, --NH 2 , --OR 1 , --NHR 2 , ##EQU27## or --O -R 5 NH 3 + , wherein R 1 , R 2 , R 3 , R 4 and R 5 is a C 2 to C 30 aliphatic hydrocarbon group and aralkyl groups; X is hydrogen or methyl; and ##EQU28## wherein R 6 is C 1 to C 4 alkyl, benzyl, phenyl, --CH 2 OH, ##EQU29## --CH 2 SH, --CH 2 CH 2 --S--CH 3 or --(CH 2 ) p COZ; and p is a positive integer of 1 or 2, and Z is the same as above; --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, or --(CH 2 ) n --, wherein n is a positive integer of 1 to 6, with the proviso that when Z is --OR 1 , ##EQU30## wherein R 6 is --(CH 2 ) m NHCOR and that at least one of R, R 1 , R 2 , R 3 , R 4 and R 5 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 33

The gel of claim 25, wherein said non-polar organic liquid is selected from the group consisting of gasoline, naphthas, kerosine, gas oil, heavy oil, crude oil, spindle oil, turbine oil, liquid paraffin, benzene, xylene, toluene, hexane, heptane, octane, cyclohexane, corn oil, soybean oil, olive oil, rapeseed oil, cotton seed oil, butyl acetate, diethyl phthalate, dioctyl phthalate, dioctyl sebacate, tricresyl phosphate, methyl isobutyl ketone, diisobutyl ketone, liquid polyoxyethylene, monolauryl ether, liquid polyoxyethylene monostearyl ether, liquid polyoxypropylene monobutyl ether, liquid polyoxypropylene monolauryl ether, liquid polyoxypropylene monostearyl ether, liquid polyoxyethylene glycol lauric acid ester, liquid polyoxypropylene glycol oleic acid ester and mixtures thereof.

Claim 34

A gel, consisting essentially of a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water, and 0.05% - 20% by weight of at least one compound having the formula ##EQU31## wherein RCO is C 5 to C 30 aliphatic acyl, and ##EQU32## wherein R 6 is C 1 to C 4 alkyl or --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above.

Claim 35

A gel, consisting essentially of a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water, and 0.05% - 20% by weight of at least one compound having the formula ##EQU31## wherein RCO is C 5 to C 30 aliphatic acyl, and ##EQU32## wherein R 6 is C 1 to C 4 alkyl or --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above.

Claim 36

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one cmpound having the formula ##EQU33## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; R 1 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl group, and ##EQU34## wherein R 6 is --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and RCO is the same as above, with the proviso that at least one of R and R 1 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 37

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one cmpound having the formula ##EQU33## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; R 1 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl group, and ##EQU34## wherein R 6 is --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and RCO is the same as above, with the proviso that at least one of R and R 1 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 38

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one compound having the formula ##EQU35## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is --NH 2 or --NHR 2 , wherein R 2 is a C 1 to C 30 aliphatic hydrocarbon group or aralkyl group; and ##EQU36## wherein R 6 is C 1 to C 4 alkyl, benzyl, --CH 2 CH 2 --S--CH 3 or --(CH 2 ) p --COZ, wherein p is a positive integer of 1 or 2 and Z is the same as above, or --(CH 2 ) m COR, wherein m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 2 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 39

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water and 0.05% to 20% by weight of at least one compound having the formula ##EQU35## wherein RCO is a C 2 to C 30 aliphatic acyl group or an aralkyl acyl group; Z is --NH 2 or --NHR 2 , wherein R 2 is a C 1 to C 30 aliphatic hydrocarbon group or aralkyl group; and ##EQU36## wherein R 6 is C 1 to C 4 alkyl, benzyl, --CH 2 CH 2 --S--CH 3 or --(CH 2 ) p --COZ, wherein p is a positive integer of 1 or 2 and Z is the same as above, or --(CH 2 ) m COR, wherein m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 2 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 40

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water, and 0.05% to 20% by weight of at least one compound having the formula ##EQU37## wherein RCO is C 2 to C 30 aliphatic acyl; R 5 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl group; and Y is C 1 to C 4 alkyl, benzyl or --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 5 is a C 5 to C 30 aliphatic hydrocarbon group.

Claim 41

A gel, consisting essentially of: a homogeneous mixture of a non-polar organic liquid having a dielectric constant of less than 20 and having a solubility less than 10% by weight in water, and 0.05% to 20% by weight of at least one compound having the formula ##EQU37## wherein RCO is C 2 to C 30 aliphatic acyl; R 5 is a C 1 to C 30 aliphatic hydrocarbon group or an aralkyl group; and Y is C 1 to C 4 alkyl, benzyl or --(CH 2 ) m NHCOR, wherein m is a positive integer of 3 or 4 and COR is the same as above, with the proviso that at least one of R and R 5 is a C 5 to C 30 aliphatic hydrocarbon group.