US3975503A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for producing alkali carbonate
Assignee: Kali Chemie AG
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Filing: 1974-12-13
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Granted: 1976-08-17
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Expires: 1994-12-13
Abstract
Abstract A method for producing alkali carbonate crystals, including adding to an alkali carbonate and alkali hydroxide solution stream a 10 to 75 weight-% alkali hydroxide solution, charging the resulting mixture into a CO 2 -containing gas whose temperature is from 150° to 700°C, collecting mixture remaining as liquid from the gas at the end of a residence time of mixture in gas of 0.1 to 10 seconds, separating alkali carbonate crystals from the collected mixture, and feeding the collected mixture, following the separating, back in the alkali carbonate and alkali hydroxide solution stream for another adding of alkali hydroxide solution.
Inventors
- 👤 Ulrich Hauschild
- 👤 Reimar Musall
- 👤 Hans-Jurgen Schroder
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 03:35
CPC Classifications
C; C01; C01D; C01D7/00; C01D7/07; C01D7/35; C01D7/37
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
211 words
A method for producing alkali carbonate crystals, comprising the steps of: a. adding to an alkali carbonate and alkali hydroxide recycle stream that contains at least 8% by weight of alkali hydroxide, a 10 to 75 weight-% alkali hydroxide solution to form a resulting solution which has an alkali hydroxide content of at least 8% by weight; b. spraying the resulting solution into a CO 2 -containing gas whose temperature is from 150 to 700°C to react a portion of the alkali hyroxide in said resulting solution with the CO 2 -containing gas and form a liquid mixture containing alkali carbonate formed from reaction of alkali hydroxide with the CO 2 -containing gas, the amount of alkali hydroxide being reacted to form alkali carbonate being equal to the amount of alkali hydroxide added to the recycle stream during the step of adding; c. collecting said liquid mixture containing said formed alkali carbonate from the gas at the end of a residence time of said mixture in said gas of from 0.1 to 10 seconds; d. separating alkali carbonate crystals from the collected liquid mixture, and; e. recycling the collected liquid mixture, following the step of separating, as the said alkali carbonate and alkali hydroxide recycle stream to the step of adding.
Claim 2
Independent Claim
211 words
A method for producing alkali carbonate crystals, comprising the steps of: a. adding to an alkali carbonate and alkali hydroxide recycle stream that contains at least 8% by weight of alkali hydroxide, a 10 to 75 weight-% alkali hydroxide solution to form a resulting solution which has an alkali hydroxide content of at least 8% by weight; b. spraying the resulting solution into a CO 2 -containing gas whose temperature is from 150 to 700°C to react a portion of the alkali hyroxide in said resulting solution with the CO 2 -containing gas and form a liquid mixture containing alkali carbonate formed from reaction of alkali hydroxide with the CO 2 -containing gas, the amount of alkali hydroxide being reacted to form alkali carbonate being equal to the amount of alkali hydroxide added to the recycle stream during the step of adding; c. collecting said liquid mixture containing said formed alkali carbonate from the gas at the end of a residence time of said mixture in said gas of from 0.1 to 10 seconds; d. separating alkali carbonate crystals from the collected liquid mixture, and; e. recycling the collected liquid mixture, following the step of separating, as the said alkali carbonate and alkali hydroxide recycle stream to the step of adding.
Claim 3
Dependent Claim
29 words
A method as claimed in claim 1, wherein the alkali hydroxide solution added to the alkali carbonate and alkali hydroxide recycle stream is a 45 to 55 weight-% solution.
Claim 4
Dependent Claim
27 words
A method as claimed in claim 1, wherein the temperature of the liquid mixture after collection in step (c) is controlled to be at 75° to 115°C.
Claim 5
Dependent Claim
27 words
A method as claimed in claim 3, wherein the temperature of the liquid mixture after collection in step (c) is controlled to be at 80° to 95°C.
Claim 6
Dependent Claim
46 words
A method as claimed in claim 1, wherein the temperature of the gas in the step of charging is in the range of from 250° to 600°C and wherein the gas temperature at the step of collecting is in the range of from 80° to 120°C.
Claim 7
Dependent Claim
26 words
A method as claimed in claim 1, wherein the residence time in the step of charging is in the range of from 0.2 to 3 seconds.
Claim 8
Dependent Claim
51 words
A method as claimed in claim 1, wherein the step of separating includes the dividing of the collected mixture into two streams, the removing of alkali carbonate crystals from only one of the streams, and the combining of the two streams, following the step of removing, to form the recycle stream.
Claim 9
Dependent Claim
30 words
A method as claimed in claim 1, wherein the alkali carbonate and alkali hydroxide recycle stream contains 13 to 18 weight-% sodium carbonate and 8 to 14 weight-% sodium hydroxide.
Claim 10
Dependent Claim
30 words
A method as claimed in claim 1, wherein the alkali carbonate and alkali hydroxide recycle stream contains 35 to 52 weight-% potassium carbonate and 8 to 20 weight-% potassium hydroxide.
Claim 11
Dependent Claim
33 words
A method as claimed in claim 9, wherein the alkali carbonate and alkali hydroxide recycle stream contains 46 to 52 weight-% potassium carbonate for producing K 2 CO 3 . 11/2H 2 0.
Claim 12
Dependent Claim
34 words
A method as claimed in claim 9, wherein the alkali carbonate and alkali hydroxide recycle stream contains 35 to 46 weight-% potassium carbonate for producing K 2 CO 3 free of water of hydration.
Claim 13
Dependent Claim
20 words
A method as claimed in claim 1, further comprising drying the alkali carbonate crystals with gas containing CO 2 .
Claim 14
Dependent Claim
29 words
A method as claimed in claim 12, wherein the alkali is sodium and the step of drying is a step for dewatering the sodium carbonate crystals to heavy soda.
Claim 15
Dependent Claim
26 words
A method as defined in claim 1, wherein the alkali hydroxide solution that is added to the recycle stream contains 10 to 60 weight-% alkali hydroxide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-17 | 1980-02-16 | 1980-08-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-17 | 1984-02-16 | 1984-08-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-17 | 1988-02-16 | 1988-08-17 | $7700.00 | Window Closed / Lapsed |