Sulfur removal from high temperature fuel gas generated by gasification

Claim 2

A process for removing sulfur from hot fuel gas obtained from the gasification of coal with an unacceptably high sulfur content comprising the steps of: a. continuously passing the hot fuel gas into a midsection of a heat transfer tower; b. continuously passing the hot fuel gas from the midsection into the base of a fuel gas cooling section of the tower, the cooling section being above the midsection; c. continuously passing cool solids into the top of the fuel gas cooling section; d. continuously passing the solids and the fuel gas countercurrent to each other in the fuel gas cooling section and continuously transferring heat from the hot fuel gas to the cool solids in the fuel gas cooling section by direct countercurrent heat transfer to cool the fuel gas and heat the solids; e. continuously removing the cooled fuel gas from the top of the fuel gas cooling section to separate the gas from the solids; f. continuously removing sulfur from the removed and cooled fuel gas to form purified and cooled fuel gas; g. continuously passing the purified and cooled fuel gas into the base of a solids cooling section of the tower, the solids cooling section being below the midsection; h. continuously passing the heated solids from the base of the fuel gas cooling section into the top of the solids cooling section; i. continuously passing the solids and the fuel gas countercurrent to each other in the solids cooling section and continuously transferring heat from the heated solids to the purified and cooled fuel gas in the solids cooling section by direct countercurrent heat transfer to cool the solids and heat the purified fuel gas; j. continuously removing the heated and purified fuel gas from the solids cooling section at the top thereof to separate the heated and purified fuel gas from the solids for use of the heated and purified fuel gas as a fuel; and k. continuously passing the cooled solids from the solids cooling section to the top of the fuel gas cooling section to recycle the solids.

Claim 3

The process for removing sulfur claimed in claim 1 wherein: a. the heated solids are passed from the fuel gas cooling section into the solids cooling section through a standpipe in the midsection for close proximation of the solids and the creation thereby of a barrier for the passage of fuel gas between the fuel gas cooling section and the solids cooling section; and b. the pressures of the hot fuel gas entering the fuel gas cooling section and the pressure of the heated and purified fuel gas at the top of the solids cooling section are maintained substantially equal to cooperate with the solids in the standpipe in preventing the passage of fuel gas between the fuel gas cooling section and the solids cooling section.

Claim 4

The process claimed in claim 2 wherein the solids are passed through the fuel gas cooling section, the midsection, and the solids cooling section by gravity.

Claim 5

The process for removing sulfur claimed in claim 3 wherein the solids passed from the solids cooling section are additionally cooled.

Claim 6

The process for removing sulfur claimed in claim 4 wherein particulates are removed from the cooled fuel gas.

Claim 7

A process for removing sulfur from a hot fuel gas stream obtained from the gasification of coal with an unacceptably high sulfur content comprising the steps of: a. continuously passing the hot fuel gas stream into the midsection of a heat transfer tower; b. continuously passing the hot fuel gas stream from the midsection into the base of a fuel gas cooling section of the tower and through the fuel gas cooling section by a pressure differential; c. continuously passing cool solids into the top of the fuel gas cooling section and through the fuel gas cooling section countercurrent to the fuel gas stream therein; d. continuously transferring heat from the fuel gas stream to the solids in the fuel gas cooling section by direct countercurrent heat transfer to cool the fuel gas and heat the solids; e. continuously removing the cooled fuel gas from the top of the fuel gas cooling section by a pressure differential as a stream to separate the fuel gas stream from the solids; f. continuously removing sulfur from the removed and cooled fuel gas stream to form a purified and cooled fuel gas stream; g. continuously passing the purified and cooled fuel gas stream into the base of a solids cooling section of the tower and through the solids cooling section by a pressure differential, the solids cooling section being below the midsection; h. continuously passing the heated solids from the base of the fuel gas cooling section through a standpipe in the midsection into the top of the solids cooling section to create a gas barrier in the standpipe by the solids between the fuel gas cooling section and the solids cooling section; i. continuously transferring heat from the solids to the purified gas stream in the solids cooling section by direct countercurrent heat transfer to cool the solids and heat the purified gas stream; j. continuously removing the heated and purified fuel gas stream from the top of the solids cooling section by a pressure differential to separate the heated and purified fuel gas stream from the solids for use of the heated and purified fuel gas as a fuel; k. continuously passing the cooled solids from the solids cooling section to recycle the solids; l. creating the pressure differentials for the fuel gas streams; and m. maintaining the pressure differential between the hot fuel gas stream entering the fuel gas cooling section and the purified fuel gas stream at the top of the solids cooling section at substantially zero to cooperate with the solids passing through the standpipe to prevent bypassing the hot fuel gas stream into the solids cooling section, such maintenance being by controlling the amount of pressure differential creation.

Claim 8

A process for removing sulfur from a hot fuel gas stream obtained from the gasification of coal with an unacceptably high sulfur content comprising the steps of: a. continuously passing the hot fuel gas stream into the midsection of a heat transfer tower; b. continuously passing the hot fuel gas stream from the midsection into the base of a fuel gas cooling section of the tower and through the fuel gas cooling section by a pressure differential; c. continuously passing cool solids into the top of the fuel gas cooling section and through the fuel gas cooling section countercurrent to the fuel gas stream therein; d. continuously transferring heat from the fuel gas stream to the solids in the fuel gas cooling section by direct countercurrent heat transfer to cool the fuel gas and heat the solids; e. continuously removing the cooled fuel gas from the top of the fuel gas cooling section by a pressure differential as a stream to separate the fuel gas stream from the solids; f. continuously removing sulfur from the removed and cooled fuel gas stream to form a purified and cooled fuel gas stream; g. continuously passing the purified and cooled fuel gas stream into the base of a solids cooling section of the tower and through the solids cooling section by a pressure differential, the solids cooling section being below the midsection; h. continuously passing the heated solids from the base of the fuel gas cooling section through a standpipe in the midsection into the top of the solids cooling section to create a gas barrier in the standpipe by the solids between the fuel gas cooling section and the solids cooling section; i. continuously transferring heat from the solids to the purified gas stream in the solids cooling section by direct countercurrent heat transfer to cool the solids and heat the purified gas stream; j. continuously removing the heated and purified fuel gas stream from the top of the solids cooling section by a pressure differential to separate the heated and purified fuel gas stream from the solids for use of the heated and purified fuel gas as a fuel; k. continuously passing the cooled solids from the solids cooling section to recycle the solids; l. creating the pressure differentials for the fuel gas streams; and m. maintaining the pressure differential between the hot fuel gas stream entering the fuel gas cooling section and the purified fuel gas stream at the top of the solids cooling section at substantially zero to cooperate with the solids passing through the standpipe to prevent bypassing the hot fuel gas stream into the solids cooling section, such maintenance being by controlling the amount of pressure differential creation.

Claim 9

The sulfur removal process claimed in claim 6 wherein the solids are passed through the fuel gas cooling section, the midsection, and the solids cooling section by gravity and the solids are passed between the solids cooling section and the fuel gas cooling section by elevation.

Claim 10

The sulfur removal process claimed in claim 7 wherein the solids are additionally cooled during their elevation.

Claim 11

The process claimed in claim 8 wherein particulates are removed from the cooled fuel gas prior to the sulfur removal step.