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US3992333A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly absorbent copolymers and foamed articles having rewettability made therefrom

Assignee: Rohm and Haas Co
•
Filing: 1972-06-27
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Granted: 1976-11-16
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Expires: 1992-06-27
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Abstract

Abstract The present invention is concerned with new and improved binders for the production of foamed or cellular articles which have a high degree of absorbency, and retain their bonded character as well as absorbency through numerous wash-dry cycles. The cellular articles are bonded by a novel self-cross-linking binder comprising a copolymer of (a) N-methylol-amine or -amide units, (b) sulfonic acid units which contain no basic nitrogen atoms or group, and (c) certain acrylic units of neutral but mildly hydrophilic character which contain no basic nitrogen atoms or group.

Inventors

  • 👤 William D. Emmons
  • 👤 Vincent J. Moser
  • 👤 John G. Brodnyan
  • 👤 Norman Shachat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 20:23
CPC Classifications
C; C08; C08J; C08J9/00; C08F; C08F246/00; D; D04; D04H; D04H1/00; D04H1/40; D04H1/58; D04H1/587; D04H1/64; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/285; D06M15/29; D06M15/356; D06M15/3566; C08J2357/00; C08J2357/04; Y; Y10; Y10S; Y10S521/00; Y10S521/905

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 125 words
As an article of manufacture an absorbent and readily wettable spone-like mass comprising a copolymer of a. 0.2 to 10% by weight of at least one α,β- monoethylenically unsaturated monomer containing an amino group in which the nitrogen atom is attached to a carbon atom of a 1,3,5-triazine ring, a carboxylamide group, or a ureido group, the nitrogen atom of such amino, carboxylamido, or ureido group being substituted by a methylol or methoxymethyl group, b. 0.2 to 15% by weight of at least one α,β-monoethylenically unsaturated monomer, in acid or salt form, having a sulfur-containing acid group and containing no basic nitrogen atom, and c. the balance to make 100% by weight, of at least one other α,β-monoethylenically monomer which contains no basic nitrogen atom.
Claim 2
Dependent Claim 125 words
As an article of manufacture an absorbent and readily wettable spone-like mass comprising a copolymer of a. 0.2 to 10% by weight of at least one α,β- monoethylenically unsaturated monomer containing an amino group in which the nitrogen atom is attached to a carbon atom of a 1,3,5-triazine ring, a carboxylamide group, or a ureido group, the nitrogen atom of such amino, carboxylamido, or ureido group being substituted by a methylol or methoxymethyl group, b. 0.2 to 15% by weight of at least one α,β-monoethylenically unsaturated monomer, in acid or salt form, having a sulfur-containing acid group and containing no basic nitrogen atom, and c. the balance to make 100% by weight, of at least one other α,β-monoethylenically monomer which contains no basic nitrogen atom.
Claim 3
Dependent Claim 44 words
As an article of manufacture, an absorbent and readily wettable sponge-like mass comprising a copolymer according to claim 1 wherein the copolymer comprises from about 0.5-10% by weight of monomeric material (a) and from about 0.5 to 8% by weight of monomeric material (b).
Claim 4
Dependent Claim 46 words
As an article of manufacture, an absorbent and readily wettable sponge-like mass comprising a copolymer according to claim 2 wherein the copolymer comprises from about 0.5 to 4% by weight of monomeric material (a) and from about 0.5 to 8% by weight of monomeric material (b).
Claim 5
Dependent Claim 12 words
An article according to claim 3 wherein the mass contains intercommunicating cells.

References Cited (Backward Citations)

US2256483A Cited
US2387730A Cited
US3711449A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-16 1980-05-17 1980-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-16 1984-05-17 1984-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-16 1988-05-17 1988-11-16 $7700.00 Window Closed / Lapsed

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