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US3994835A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of colored polyurethane foams

Assignee: Bayer AG
•
Filing: 1973-12-05
•
Granted: 1976-11-30
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Expires: 1993-12-05
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Abstract

Abstract Dispersions of dyestuffs which contain at least one free amino or hydroxyl group capable of reacting with isocyanates under the conditions of polyaddition and liquids in which the dyes are soluble to an extent less than 2 % are suitable for the production of colored polyurethane foams. The dye dispersions can be added before or during the polyaddition reaction.

Inventors

  • 👤 Karlheinz Wolf
  • 👤 Konrad Nonn
  • 👤 Reinhold Hornle
  • 👤 Hans Unterbirker
  • 👤 Jurgen Koerner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:55
CPC Classifications
C; C09; C09B; C09B69/00; C09B69/10; C09B69/106; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3819; C08G18/3836

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 90 words
In a process for producing a colored polyurethane foam wherein a polyether or a polyester is reacted with an organic polyisocyanate to produce a polyurethane foam, the improvement which comprises adding to the reactants of the polyurethane foam production before or during the reaction a dispersion of one or more dyes each of which contains at least one free amino or hydroxyl group capable of reaction with isocyanates under the conditions of polyaddition and liquids in which the dyes are soluble to an extent of less than 2% at 20°C.
Claim 2
Dependent Claim 90 words
In a process for producing a colored polyurethane foam wherein a polyether or a polyester is reacted with an organic polyisocyanate to produce a polyurethane foam, the improvement which comprises adding to the reactants of the polyurethane foam production before or during the reaction a dispersion of one or more dyes each of which contains at least one free amino or hydroxyl group capable of reaction with isocyanates under the conditions of polyaddition and liquids in which the dyes are soluble to an extent of less than 2% at 20°C.
Claim 3
Dependent Claim 50 words
The process of claim 1 wherein said dispersion is a mixture of 5%-50% by weight of dye and the remainder a liquid compatible with the foam producing reactants, capable of dissolving no more than 2% of said dye and having a vapor pressure at 20°C of less than 1 mbar.
Claim 4
Dependent Claim 32 words
The process of claim 2 wherein said liquid is a plasticizer which will remain the foam and will not react with the isocyanates or said liquid is a high molecular weight polyalcohol.
Claim 5
Dependent Claim 41 words
The process of claim 3 wherein said liquid is tri-n-butyl phosphate, diphenylcresyl phosphate, diphenyloctyl phosphate, butylbenzyl phthalate, dioctyl phthalate, condensation product of adipic acid with butane-1,3-diol, propylene-1,2-diol or dipropylene glycol having an hydroxyl number of 110 - 120, or mixtures thereof.
Claim 6
Dependent Claim 59 words
The process of claim 1 wherein said amino group is primary amino or secondary amino and is attached to an aromatic nucleus of the dye (a) by a direct bond, (b) via an alkylene bridge, or (c) via an alkylene bridge separated from said nucleus by --CO--, --CO 2 --, --SO 2 --, --CONH--, --NH--, or --SO 2 NH--.
Claim 7
Dependent Claim 43 words
The process of claim 1 wherein said hydroxyl is attached to an aromatic nucleus of the dye (a) by a direct bond, (b) via an alkylene bridge, or (c) via an alkylene bridge separated from said nucleus by an oxygen, sulfur, or nitrogen.
Claim 8
Dependent Claim 36 words
The process of claim 3 wherein said liquid plasticizer is an aryl ester of phosphoric acid, alkyl ester of phosphoric acid, halogenated alkyl ester of phosphoric acid, adipic acid ester, phthalic acid ester or glyceric ester.
Claim 9
Dependent Claim 31 words
The process of claim 6 wherein said liquid high molecular weight polyalcohol is a condensation product of adipic acid and butane-1,3-diol or propylene-1,2-glycol with a hydroxyl number of 110 - 120.

References Cited (Backward Citations)

GB823089A Cited
GB867235A Cited
US3137671A Cited
US3228780A Cited
US3278486A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-30 1980-05-31 1980-11-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-30 1984-05-31 1984-11-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-30 1988-05-31 1988-11-30 $7700.00 Window Closed / Lapsed

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