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US4012434A Expired / Lapsed US ⏱️ 0.0 years remaining

Nematic compounds and mixtures

Assignee: Merck Patent GmbH
•
Filing: 1975-10-24
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Granted: 1977-03-15
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Expires: 1995-10-24
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Abstract

Abstract Compounds of the general formula ##STR1## wherein n is 0, 1 or 2, R 1 is straight-chain alkyl or alkoxy of 1-7 carbon atoms or straight-chain alkanoyloxy of 2-7 carbon atoms, and R 2 is straight-chain alkyl or alkoxy of 1-7 carbon atoms with the proviso that when n is 0, R 1 and R 2 together contain at least 4 carbon atoms, which form nematic phases, can be produced by reacting a phenol of the general formula ##STR2## WHEREIN R 2 has the values given above, and p is 0, 1 or 2 or a corresponding phenolate, with an aromatic carboxylic acid of the general formula ##STR3## WHEREIN R 1 has the values given above, and q is 0, 1 or 2, and the sum p + q is n, or with a reactive derivative of this acid.

Inventors

  • 👤 Ralf Steinstrasser

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:04
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/10; C09K19/20; C09K19/2007

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 37 words
A compound of the formula ##STR13##wherein R 1 is straight-chain alkyl or straight-chain alkoxy of 1-7 carbon atoms or straight-chain alkanoyloxy of 2-7 carbon atoms, R 2 is straight-chain alkyl or straight-chain alkoxy of 1-7 carbon atoms.
Claim 2
Dependent Claim 37 words
A compound of the formula ##STR13##wherein R 1 is straight-chain alkyl or straight-chain alkoxy of 1-7 carbon atoms or straight-chain alkanoyloxy of 2-7 carbon atoms, R 2 is straight-chain alkyl or straight-chain alkoxy of 1-7 carbon atoms.
Claim 3
Dependent Claim 18 words
A compound according to claim 1, wherein R 1 and R 2 are alkyl of 2-7 carbon atoms.
Claim 4
Dependent Claim 20 words
A compound according to claim 1, wherein R 1 is alkoxy and R 2 is alkyl of 2-7 carbon atoms.
Claim 5
Dependent Claim 20 words
A compound according to claim 1, wherein R 1 is alkyl of 2-7 carbon atoms and R 2 is alkoxy.
Claim 6
Dependent Claim 20 words
A compound according to claim 1, wherein R 1 is alkanoyloxy and R 2 is alkyl of 2-7 carbon atoms.
Claim 7
Dependent Claim 37 words
A compound of claim 4 selected from the group consisting of 4'-methoxyphenyl ester of 4-(4-ethylbenzoyloxy)-benzoic acid, 4'-butoxyphenyl ester of 4-(4-ethylbenzoyloxy)-benzoic acid, 4'-methoxyphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid, 4'-butoxyphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid and 4'-hexoxyphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid.
Claim 8
Dependent Claim 52 words
A compound of claim 2 selected from the group consisting of 4'-methylphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid, 4'-butylphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid, 4'-hexylphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid, 4'-ethylphenyl ester of 4-(4-hexylbenzoyloxy)-benzoic acid, 4'-butylphenyl ester of 4-(4-hexylbenzoyloxy)-benzoic acid, 4'-hexylphenyl ester of 4-(4-hexylbenzoyloxy)-benzoic acid, 4'-ethylphenyl ester of 4-(4-ethylbenzoyloxy)-benzoic acid and 4'-butylphenyl ester of 4-(4-ethylbenzoyloxy)-benzoic acid.
Claim 9
Dependent Claim 47 words
A compound of claim 3 selected from the group consisting of 4'-ethylphenyl ester of 4-anisoyloxybenzoic acid, 4'-propylphenyl ester of 4-anisoyloxybenzoic acid, 4'-heptylphenyl ester of 4-anisoyloxybenzoic acid, 4'-ethylphenyl ester of 4-(4-ethoxybenzoyloxy)-benzoic acid, 4'-butylphenyl ester of 4-(4-butoxybenzoyloxy)-benzoic acid, 4'-methylphenyl ester of 4-(4-hexoxybenzoyloxy)-benzoic acid and 4'-butylphenyl ester of 4-(4-hexoxybenzoyloxy)-benzoic acid.
Claim 10
Dependent Claim 37 words
A compound of claim 1 selected from the group consisting of 4'-ethoxyphenyl ester of 4-anisoyloxybenzoic acid, 4'-butoxyphenyl ester of 4-(4-ethoxybenzoyloxy)-benzoic acid, 4'-hexoxyphenyl ester of 4-(4-butoxybenzoyloxy)-benzoic acid, 4'-methoxyphenyl ester of 4-(4-hexoxybenzoyloxy)-benzoic acid and 4'-hexoxyphenyl ester of 4-(4-hexoxybenzoyloxy)-benzoic acid.
Claim 11
Dependent Claim 10 words
The compound of claim 1, 4'-butylphenyl ester of 4-anisoyloxybenzoic acid.
Claim 12
Dependent Claim 10 words
The compound of claim 1, 4'-butylphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid.
Claim 13
Dependent Claim 10 words
The compound of claim 1, 4'-hexoxyphenyl ester of 4-(4-butylbenzoyloxy)-benzoic acid.

References Cited (Backward Citations)

US1974689A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-14 1980-09-13 1981-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-14 1984-09-13 1985-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-14 1988-09-13 1989-03-15 $7700.00 Window Closed / Lapsed

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