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US4021405A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer substrates coated with stabilized polymeric coating composition

Assignee: Wyeth Holdings LLC
•
Filing: 1975-03-20
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Granted: 1977-05-03
•
Expires: 1995-03-20
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Abstract

Abstract Articles of manufacture comprising polymeric substrates coated with a composition of matter consisting of an acid catalyzed reaction product of (A) a urethane prepolymer having terminal hydroxy groups produced from (1) a polyol of 200 - 3,000 molecular weight, (2) an organic diisocyanate and (3) a polyhydric alcohol; and (B) a polyalkylether of a polymethylol melamine containing various ultraviolet light absorbers, are disclosed.

Inventors

  • 👤 Robert Jerome Tucker
  • 👤 Ruth Greenwood

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 00:19
CPC Classifications
C; C09; C09D; C09D175/00; C09D175/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31573; Y10T428/31576; Y10T428/3158; Y10T428/31587; Y10T428/31609; Y10T428/31612; Y10T428/31616; Y10T428/31855; Y10T428/31859; Y10T428/31862; Y10T428/31935; Y10T428/31938; Y10T428/31942

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 172 words
An article of manufacture comprising a polymeric substrate having a mar-resistant coating thereon, said coating consisting essentially of the acid catalyzed reaction product of a mixture of (1), (2) and (3), the amount of (1) and (2) ranging from about 5:1 to about 1:1, respectively, in which (1) is a saturated urethane prepolymer having terminal hydroxy groups which is the reaction product of materials consisting essentially of a mixture of (a) and (b), at a molar ratio of 1:2, respectively, in which (a) is an isocyanate-terminated urethane which is the reaction product of a mixture consisting essentially of (I) and (II), at a molar ratio of 1:2, respectively, in which (I) is a saturated diol having a molecular weight of from about 200 to about 3000 and (II) is a saturated organic diisocyanate and (b) is a monomeric, sterically bulky, polyhydric alcohol containing 2- 6 hydroxyl groups and being free of oxyalkylene units (2) is a polyalkylether of a polymethylol melamine and (3) is an ultraviolet light absorber comprising 2-[(2-hydroxy-5-t-octylphenyl)]benzotriazole or 2,2'-dihydroxy-4-methoxybenzophenone.
Claim 2
Dependent Claim 172 words
An article of manufacture comprising a polymeric substrate having a mar-resistant coating thereon, said coating consisting essentially of the acid catalyzed reaction product of a mixture of (1), (2) and (3), the amount of (1) and (2) ranging from about 5:1 to about 1:1, respectively, in which (1) is a saturated urethane prepolymer having terminal hydroxy groups which is the reaction product of materials consisting essentially of a mixture of (a) and (b), at a molar ratio of 1:2, respectively, in which (a) is an isocyanate-terminated urethane which is the reaction product of a mixture consisting essentially of (I) and (II), at a molar ratio of 1:2, respectively, in which (I) is a saturated diol having a molecular weight of from about 200 to about 3000 and (II) is a saturated organic diisocyanate and (b) is a monomeric, sterically bulky, polyhydric alcohol containing 2- 6 hydroxyl groups and being free of oxyalkylene units (2) is a polyalkylether of a polymethylol melamine and (3) is an ultraviolet light absorber comprising 2-[(2-hydroxy-5-t-octylphenyl)]benzotriazole or 2,2'-dihydroxy-4-methoxybenzophenone.
Claim 3
Dependent Claim 15 words
An article of manufacture according to claim 1 wherein said (I) is a polytetramethyleneether glycol.
Claim 4
Dependent Claim 15 words
An article of manufacture according to claim 1 wherein said (II) is methylene bis(cyclohexane isocyanate).
Claim 5
Dependent Claim 14 words
An article of manufacture according to claim 1 wherein said (b) is 1,4-cyclohexane dimethanol.
Claim 6
Dependent Claim 14 words
An article of manufacture according to claim 1 wherein said (2) is hexakismethoxymethyl melamine.
Claim 7
Dependent Claim 12 words
An article according to claim 1 wherein said substrate is a lens.
Claim 8
Dependent Claim 15 words
An article of manufacture according to claim 1 wherein said polymeric substrate comprises a polycarbonate.
Claim 9
Dependent Claim 14 words
An article of manufacture according to claim 1 wherein said polymeric substrate comprises polyethylene.
Claim 10
Dependent Claim 15 words
An article of manufacture according to claim 1 wherein said polymeric substrate comprises polymethyl methacrylate.
Claim 11
Dependent Claim 14 words
An article of manufacture according to claim 1 wherein said polymeric substrate comprises polypropylene.
Claim 12
Dependent Claim 15 words
An article of manufacture according to claim 1 wherein said polymeric substrate comprises polyvinyl chloride.

References Cited (Backward Citations)

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US3626023A Cited
US3912790A Cited
US3804810A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-02 1980-11-01 1981-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-02 1984-11-01 1985-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-02 1988-11-01 1989-05-03 $7700.00 Window Closed / Lapsed

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