US4022830A
Expired / Lapsed
US
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Process for preparing polychlorobenzamide derivatives
Assignee: Texaco Development Corp
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Filing: 1975-08-15
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Granted: 1977-05-10
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Expires: 1995-08-15
Abstract
Abstract A novel process for preparing polychlorobenzamide derivatives, useful as biocidal agents, flame retardants in plastic resins, and the like, from corresponding polychlorobenzonitrile compound in near quantitative yields is disclosed. A polychlorobenzonitrile compound is admixed and reacted with excess sulfuric acid at an elevated temperature e.g. 100° to 160° C for a time period sufficient to hydrolyze the polychlorobenzonitrile derivative to the corresponding polychlorobenzamide derivative. The reaction product is then recovered to provide the corresponding polychlorobenzamide derivative in an excellent yield above about 90%.
Inventors
- 👤 Lewis W. Watts, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 14:59
CPC Classifications
C; C07; C07C; C07C231/00; C07C231/06; C07C233/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
92 words
A process for preparing a polychlorobenzamide derivative with essentially no further hydrolysis to the acid in commercially economical yields from the corresponding polychlorobenzonitrile compound having the formula: ##STR3## wherein X is selected from a group consisting of a chloro radical and Y is a hydroxy radical comprising the step of: initially admixing and reacting said polychlorobenzonitrile compound with a molar excess of sulfuric acid of a concentration sufficient to hydrolyze said polychlorobenzonitrile compound at elevated temperatures of from about 100° to 170° C to form a reaction mixture containing said polychlorobenzamide derivative.
Claim 2
Dependent Claim
92 words
A process for preparing a polychlorobenzamide derivative with essentially no further hydrolysis to the acid in commercially economical yields from the corresponding polychlorobenzonitrile compound having the formula: ##STR3## wherein X is selected from a group consisting of a chloro radical and Y is a hydroxy radical comprising the step of: initially admixing and reacting said polychlorobenzonitrile compound with a molar excess of sulfuric acid of a concentration sufficient to hydrolyze said polychlorobenzonitrile compound at elevated temperatures of from about 100° to 170° C to form a reaction mixture containing said polychlorobenzamide derivative.
Claim 3
Dependent Claim
39 words
The process of claim 1 comprising the further step of: isolating said formed polychlorobenzamide derivative by diluting and cooling the reaction mixture with water such that said polyhalobenzamide derivative precipitates as a solid and separating said solid by filtration.
Claim 4
Dependent Claim
40 words
The process of claim 1 wherein said polychlorobenzonitrile is 4-hydroxytetrachlorobenzonitrile; wherein said concentrated sulfuric acid has a concentration in excess of 94% H 2 SO 4 by total weight and wherein said elevated temperature is about 135° to 145° C.
Claim 5
Dependent Claim
19 words
The process of claim 1 wherein said concentration of sulfuric acid is greater than about 70% by total weight.
Claim 6
Dependent Claim
53 words
A process for preparing hydrotetrachlorobenzamide derivative with essentially no further hydrolysis to the acid in commercially economical yields from the corresponding hydroxychlorobenzonitrile compound comprising the step of admixing and reacting said hydrotetrachlorobenzonitrile compound with a molar excess of sulfuric acid at a concentration of about 75% and at elevated temperatures of 150°-170° C.
Claim 7
Dependent Claim
53 words
A process for preparing hydrotetrachlorobenzamide derivative with essentially no further hydrolysis to the acid in commercially economical yields from the corresponding hydroxychlorobenzonitrile compound comprising the step of admixing and reacting said hydrotetrachlorobenzonitrile compound with a molar excess of sulfuric acid at a concentration of about 75% and at elevated temperatures of 150°-170° C.
References Cited (Backward Citations)
US3444196A
Cited
US3401191A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-09 | 1980-11-08 | 1981-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-09 | 1984-11-08 | 1985-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-09 | 1988-11-08 | 1989-05-10 | $7700.00 | Window Closed / Lapsed |