Abstract Described herein are melt-processable, solvent resistant polymers comprised of repeating units of formula ##STR1## having a tensile elongation to break of at least about 50% at room temperature and mean inherent viscosity within the range from about 0.8 to about 1.65. The polymers, which are suitable for high temperature resistant wire insulation, are prepared, e.g., by the hydrogen fluoride-boron trifluoride catalyzed polymerization of a p-phenoxybenzoyl moiety-containing monomer (e.g., p-phenoxybenzoyl halide, p-phenoxybenzoic acid, or C 1 -C 3 alkyl p-phenoxybenzoates) in the presence of a capping agent whose reactivity to acetylation is greater than about 150 relative to benzene reactivity of 1. Wet workup and spray drying techniques are described, the latter preferably including dilution of hydrogen fluoride with liquid SO 2 , either before or after polymerization.
An electrical conductor bearing an insulative coating of a thermally cross-linked crystalline melt-processing polymer consisting essentially of repeating units of formula ##STR13## having a mean inherent viscosity within the range from about 0.8 to about 1.65 and elongation of at least about 50%.
Claim 2
Dependent Claim
43 words
An electrical conductor bearing an insulative coating of a thermally cross-linked crystalline melt-processing polymer consisting essentially of repeating units of formula ##STR13## having a mean inherent viscosity within the range from about 0.8 to about 1.65 and elongation of at least about 50%.
Claim 3
Dependent Claim
28 words
An electrical conductor bearing an insulative coating of a polymer according to claim 1 whose polymeric chains consist essentially of chains of inherent viscosity greater than about 0.6.