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US4026477A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the separation of components of scrap storage batteries

Assignee: A Tonolli and Co SpA
•
Filing: 1972-06-09
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Granted: 1977-05-31
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Expires: 1992-06-09
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Abstract

Abstract A process for separation of the components of scrap lead storage batteries including crushing, and then heating the pieces while tumbling, dry screening the paste from the residual materials which are fed to a sink-float apparatus whose fluidized pulp comprises a liquid suspension of battery paste. The pH and density of the pulp are regulated in the pH range of 7-10 by addition of sulphuric acid. After sink-float separation the drained and washed materials are recovered and the pulp and wash liquid are recycled back into the system.

Inventors

  • 👤 Gustavo Tremolada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:03
CPC Classifications
B; B03; B03B; B03B9/00; B03B9/06; B03B9/061; C; C22; C22B; C22B7/00; H; H01; H01M; H01M10/00; H01M10/54; B03B2009/066; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y02W; Y02W30/00; Y02W30/50; Y02W30/52; Y02W30/84

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 206 words
A process for the separation of scrap lead storage batteries and parts thereof in three parts, namely metallic components, paste and inactive material, essentially comprising: emptying from the batteries their sulphuric acid content; then crushing the batteries into pieces of sizes between 2 and 15 cm, apart from the paste which is detached; heating the pieces and paste at 35°-50° C., while tumbling them, until the paste reaches a humidity content of 2-7%, thereby neutralizing the residual acidity of the paste; then separating and recovering the dry paste from the materials from the preceding step by dry screening said materials using a screen having openings of size in the range of 2 to 30 mm; then feeding the residual material, substantially free of paste, into a separating zone containing an aqueous suspension of the paste, and having a density from 10 to 100% greater than that of the battery containers, and a pH regulated between 7 and 10, the pH and viscosity of the suspension being regulated by addition of sulphuric acid; removing as sink the metallic components and as float the inactive material; draining and washing the sink and float respectively, and recirculating the suspension of paste at the proper density to the separating zone.
Claim 2
Dependent Claim 206 words
A process for the separation of scrap lead storage batteries and parts thereof in three parts, namely metallic components, paste and inactive material, essentially comprising: emptying from the batteries their sulphuric acid content; then crushing the batteries into pieces of sizes between 2 and 15 cm, apart from the paste which is detached; heating the pieces and paste at 35°-50° C., while tumbling them, until the paste reaches a humidity content of 2-7%, thereby neutralizing the residual acidity of the paste; then separating and recovering the dry paste from the materials from the preceding step by dry screening said materials using a screen having openings of size in the range of 2 to 30 mm; then feeding the residual material, substantially free of paste, into a separating zone containing an aqueous suspension of the paste, and having a density from 10 to 100% greater than that of the battery containers, and a pH regulated between 7 and 10, the pH and viscosity of the suspension being regulated by addition of sulphuric acid; removing as sink the metallic components and as float the inactive material; draining and washing the sink and float respectively, and recirculating the suspension of paste at the proper density to the separating zone.
Claim 3
Dependent Claim 14 words
A process according to claim 1, wherein crushing and heating are carried out contemporaneously.
Claim 4
Dependent Claim 32 words
A process according to claim 1, wherein water from the washing steps is recirculated through a thickener for recovering paste therefrom, the overflow from said thickener being recirculated as reuseable wash water.
Claim 5
Dependent Claim 25 words
A process according to claim 1, wherein the heating is performed by direct heating with hot gases in counter-current flow with respect to the material.
Claim 6
Dependent Claim 27 words
A process according to claim 1, wherein the density of the fluidized pulp, when the cases are in ebonite, is between 1.7 and 2 kg/dm 3 .

References Cited (Backward Citations)

US961121A Cited
US1895504A Cited
US2356648A Cited
US2690261A Cited
US2693878A Cited
US2966350A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-30 1980-11-29 1981-05-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-30 1984-11-29 1985-05-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-30 1988-11-29 1989-05-31 $7700.00 Window Closed / Lapsed

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