Vinyl halide stabilizer compositions of antimony organic sulfur-containing compounds and ortho-dihydric phenols

Claim 2

A resin heat stabilizer composition which consists essentially of, an antimony organic sulfur-containing compound having the formula R.sub.n SbX.sub.3.sub.-n where R of the formula is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, cycloalkyl, cycloalkenyl, mixed aryl-alkyl, and substituted groups thereof, where X of the formula is selected from the group consisting of sulfur, SR and SRCOOR', where R of the group SR is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where R of the group SRCOOR' is selected from alkylene, arylene, aralkylene, and substituted groups thereof, wherein R' of the group SRCOOR' is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where n is an integer of 0 to 2, and a phenol selected from the group consisting of o-dihydric phenols and o-dihydric alkyl phenols, and mixtures thereof, said antimony compound and phenol components in relative amounts which together provide a synergistic heat stabilizing effectiveness upon said resin.

Claim 3

The composition of claim 1 wherein said phenol is selected from the group consisting of catechol, t-butyl catechol and 2,3-dihydroxynaphthalene.

Claim 4

The composition of claim 1 which is liquid and shelf-stable at ambient temperatures.

Claim 5

The composition of claim 3 wherein said antimony compound is selected from the group consisting of antimony tris (isoctylthioglycolate), antimony tris (isooctylmercaptopropionate), dodecylmercaptoantimony bis (isooctylthioglycolate), antimony tris (glycoldimercaptoacetate), and mixtures thereof.

Claim 6

The composition of claim 3 wherein said phenol is selected from the group consisting of catechol, t-butyl catechol, and 2,3-dihydroxynaphthalene.

Claim 7

The composition of claim 1 which includes a metal carboxylate selected from the group consisting of an alkali or alkaline earth metal salt of a carboxylic or thiocarboxylic acid.

Claim 8

The composition of claim 6 wherein said acid is a fatty acid.

Claim 9

A vinyl halide resin composition which comprises a vinyl chloride resin and, as a heat stabilizer, an effective amount of a composition consisting essentially of, an antimony organic sulfur-containing compound having the formula R.sub.n SbX.sub.3.sub.-n where R of the formula is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, cycloalkyl, cycloalkenyl, mixed aryl-alkyl, and substituted groups thereof, wherein X of the formula is selected from the group consisting of sulfur, SR and SRCOOR', where R of the group SR is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where R of the group SRCOOR' is selected from alkylene, arylene, aralkylene, and substituted groups thereof, wherein R' of the group SRCOOR' is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where n is an integer of 0 to 2, and a phenol selected from the group consisting of o-dihydric phenols and o-dihydric alkyl phenols, and mixtures thereof, said antimony compound and phenol components in relative amounts which together provide a synergistic heat stabilizing effectiveness upon said resin.

Claim 10

A vinyl halide resin composition which comprises a vinyl chloride resin and, as a heat stabilizer, an effective amount of a composition consisting essentially of, an antimony organic sulfur-containing compound having the formula R.sub.n SbX.sub.3.sub.-n where R of the formula is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, cycloalkyl, cycloalkenyl, mixed aryl-alkyl, and substituted groups thereof, wherein X of the formula is selected from the group consisting of sulfur, SR and SRCOOR', where R of the group SR is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where R of the group SRCOOR' is selected from alkylene, arylene, aralkylene, and substituted groups thereof, wherein R' of the group SRCOOR' is selected from alkyl, aryl, mixed aryl-alkyl, and substituted groups thereof, where n is an integer of 0 to 2, and a phenol selected from the group consisting of o-dihydric phenols and o-dihydric alkyl phenols, and mixtures thereof, said antimony compound and phenol components in relative amounts which together provide a synergistic heat stabilizing effectiveness upon said resin.

Claim 11

The composition of claim 8 wherein said phenol is selected from the group consisting of catechol, t-butyl catechol and 2,3-dihydroxynaphthalene.

Claim 12

The composition of claim 8 wherein said vinyl halide resin comprises polyvinyl chloride.

Claim 13

The composition of claim 8 wherein the stabilizer composition is liquid and shelf-stable at ambient temperatures.

Claim 14

The composition of claim 11 wherein said antimony compound is selected from the group consisting of antimony tris (isooctylthioglycolate), antimony tris (isooctylmercaptopropionate), dodecylmercaptoantimony bis (isooctylthioglycolate), antimony tris (glycoldimercaptoacetate), and mixture thereof.

Claim 15

The composition of claim 11 wherein said phenol is selected from the group consisting of catechol, t-butyl catechol, and 2,3-dihydroxynaphthalene.

Claim 16

The composition of claim 8 wherein the relative amount of said antimony compound is from about 0.05 to about 3 parts by weight per 100 parts resin and the relative amount of phenol present is from about 1 to about 10 percent by weight of said antimony compound.

Claim 17

A vinyl halide resin composition which comprises a vinyl chloride resin and, as a heat stabilizer, an effective amount of a composition consisting essentially of, an antimony organic sulfur-containing compound selected from the group consisting of antimony tris (isooctylthioglycolate), antimony tris (laurylmercaptide), antimony tris (isooctylmercaptopropionate), dodecylmercaptoantimony bis (isooctylthioglycolate), antimony tris (glycoldimercaptoacetate), antimony tris (dodecylthioglycolate), and mixtures thereof, and a phenol selected from the group consisting of catechol, t-butyl catechol and 2,3-dihydroxynaphthalene, and mixtures thereof, said antimony compound and phenol components in relative amounts which together provide a synergistic heat stabilizing effectiveness upon said resin.

Claim 18

A vinyl halide resin composition which comprises a vinyl chloride resin and, as a heat stabilizer, an effective amount of a composition consisting essentially of, an antimony organic sulfur-containing compound selected from the group consisting of antimony tris (isooctylthioglycolate), antimony tris (laurylmercaptide), antimony tris (isooctylmercaptopropionate), dodecylmercaptoantimony bis (isooctylthioglycolate), antimony tris (glycoldimercaptoacetate), antimony tris (dodecylthioglycolate), and mixtures thereof, and a phenol selected from the group consisting of catechol, t-butyl catechol and 2,3-dihydroxynaphthalene, and mixtures thereof, said antimony compound and phenol components in relative amounts which together provide a synergistic heat stabilizing effectiveness upon said resin.

Claim 19

The composition of claim 15 wherein said effective tamount is on the order of about 0.05 to about 5 parts by weight per 100 parts resin.

Claim 20

The composition of claim 16 wherein the relative amount of said antimony compound is from about 0.05 to about 3 parts by weight per 100 parts resin and the relative amount of phenol present is from about 1 to about 10 percent by weight of said antimony compound.

Claim 21

A heat stabilizer composition for imparting a vinyl halide resin with enhanced resistance to early discoloration, said composition being a liquid and shelf-stable at ambient temperature and comprising an antimony mercaptoacid ester and a phenol selected from the group consisting of o-dihydroxy phenols and o-dihydroxyl alkyl phenols.

Claim 22

A heat stabilizer composition for imparting a vinyl halide resin with enhanced resistance to early discoloration, said composition being a liquid and shelf-stable at ambient temperature and comprising an antimony mercaptoacid ester and a phenol selected from the group consisting of o-dihydroxy phenols and o-dihydroxyl alkyl phenols.

Claim 23

The composition of claim 18 which is in combination with a metal salt of a fatty acid.

Claim 24

The composition of claim 19 wherein said salt is calcium stearate.