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US4036771A Expired / Lapsed US ⏱️ 0.0 years remaining

Lubricating bases for multigrade oils

Assignee: IFP Energies nouvelles
•
Filing: 1975-09-05
•
Granted: 1977-07-19
•
Expires: 1995-09-05
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Abstract

Abstract There are disclosed lubricating compositions consisting of homogeneous mixtures of:

Inventors

  • 👤 Jacques Denis
  • 👤 Guy Parc

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:16
CPC Classifications
C; C10; C10M; C10M3/00; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C08G65/331; C08G65/332; C10M2203/00; C10M2203/06; C10M2205/00; C10M2205/02; C10M2207/00; C10M2207/28; C10M2207/282; C10M2207/283; C10M2207/34; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/10; C10M2209/103; C10M2209/109; C10M2209/11; C10M2209/111

Claims Analysis

Total Claims: 57
Claim 1
Independent Claim 348 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one hydrocarbyl monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 - OH, oxyalkylenated monohydric hydrocarbyl alcohols, and oxyalkylenated monohydric phenols of the formula R 2 --O(R 1 --O) n H, wherein R 2 is an aliphatic, alicyclic or aromatic monovalent hydrocarbyl radical, and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 2 moles of dimeric acid for 1 mole of dihydroxyl compound and 2 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 2
Dependent Claim 348 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one hydrocarbyl monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 - OH, oxyalkylenated monohydric hydrocarbyl alcohols, and oxyalkylenated monohydric phenols of the formula R 2 --O(R 1 --O) n H, wherein R 2 is an aliphatic, alicyclic or aromatic monovalent hydrocarbyl radical, and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 2 moles of dimeric acid for 1 mole of dihydroxyl compound and 2 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 3
Dependent Claim 37 words
A composition according to claim 1, wherein the dihydroxyl compound consists essentially of at least one polypropylene glycol having 2-30 oxypropylene groups and the monohydroxyl compound comprises at least one oxypropylenated monohydric alcohol having 1-30 oxypropylene groups.
Claim 4
Dependent Claim 26 words
A composition according to claim 1, wherein the dimeric acid results from the dimerisation of at least one unsaturated fatty acid that contains 18 carbon atoms.
Claim 5
Dependent Claim 86 words
A composition according to claim 2, wherein the dimeric acid results from the dimerization of C 18 unsaturated fatty acids, the dihydroxyl compound is a polypropylene glycol having a molecular weight of approximately 130 to 1,800 and the monohydroxyl compound is selected from the group consisting of (a) a monohydroxyl polyether of condensation of 1,2-propylene oxide on an aliphatic monohydric alcohol having 13 to 15 carbon atoms, which contains about 20 1,2-propylene oxide units per molecule, and (b) an aliphatic monohydric alcohol of 9-11 carbon atoms.
Claim 6
Dependent Claim 16 words
A composition according to claim 4, wherein said monohydroxyl compound consists essentially of said monohydroxyl polyether.
Claim 7
Dependent Claim 35 words
A composition according to claim 1, wherein the hydrocarbon oil is selected from solvent-refined or acid-refined mineral oils and hydrorefined mineral oils which have a viscosity at 37.8° C. of about 100 to 600 SSU.
Claim 8
Dependent Claim 28 words
A composition according to claim 1, wherein the hydrocarbon oil is selected from olefin polymers and mono- or polyalkylated aromatic compounds, which may be at least partially hydrogenated.
Claim 9
Dependent Claim 32 words
A composition according to claim 1, wherein said homogenous mixture essentially contains from 80 to 95% by weight of hydrocarbon oil and from 5 to 20% by weight of complex ester composition.
Claim 10
Dependent Claim 40 words
A composition according to claim 1, wherein said homogeneous mixture contains from 10 to 40% by weight of light ester, from 50 to 80% by weight of hydrocarbon oil and from 1 to 40% by weight of complex ester composition.
Claim 11
Dependent Claim 30 words
The improved lubricating composition according to claim 1, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 20 W 40 rating.
Claim 12
Dependent Claim 30 words
The improved lubricating composition according to claim 1, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 10 W 30 rating.
Claim 13
Dependent Claim 346 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H-- O -- R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one hydrocarbyl monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 --OH, oxyalkylenated monohydric hydrocarbyl alcohols, and oxyalkylenated monohydric phenols of the formula R 2 --O(R 1 -O) n H, wherein R 2 is an aliphatic, alicyclic or aromatic monovalent hydrocarbyl radical, and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 3 moles of dimeric acid for 2 moles of dihydroxyl compound and 2 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 14
Dependent Claim 346 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H-- O -- R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one hydrocarbyl monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 --OH, oxyalkylenated monohydric hydrocarbyl alcohols, and oxyalkylenated monohydric phenols of the formula R 2 --O(R 1 -O) n H, wherein R 2 is an aliphatic, alicyclic or aromatic monovalent hydrocarbyl radical, and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 3 moles of dimeric acid for 2 moles of dihydroxyl compound and 2 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 15
Dependent Claim 41 words
A composition according to claim 12, wherein the dihydroxyl compound consists essentially of at least one diol of the general formula HO--R 1 '--OH and the monohydroxyl compound consists essentially of at least one oxypropylenated monohydric alcohol having 1-30 oxypropylene groups.
Claim 16
Dependent Claim 60 words
A composition according to claim 13, wherein the dimeric acid results from the dimerization of C 18 unsaturated fatty acids, the dihydroxyl compound is neopentyl glycol and the monohydroxyl compound is a monohydroxy polyether of condensation of 1,2-propylene oxide on an aliphatic monohydric alcohol having from 13 to 15 carbon atoms, which contains about 20 propylene oxide units per molecule.
Claim 17
Dependent Claim 37 words
A composition according to claim 12, wherein the dihydroxyl compound consists essentially of at least one polypropylene glycol having 2-30 oxypropylene groups and the monohydroxyl compound comprises at least one oxypropylenated monohydric alcohol having 1-30 oxypropylene groups.
Claim 18
Dependent Claim 26 words
A composition according to claim 12, wherein the dimeric acid results from the dimerization of at least one unsaturated fatty acid that contains 18 carbon atoms.
Claim 19
Dependent Claim 35 words
A composition according to claim 12, wherein the hydrocarbon oil is selected from solvent-refined or acid-refined mineral oils and hydrorefined mineral oils, which have a viscosity at 37.8° C. of about 100 to 600 SSU.
Claim 20
Dependent Claim 28 words
A composition according to claim 12, wherein the hydrocarbon oil is selected from olefin polymers and mono- or polyalkylated aromatic compounds, which may be at least partially hydrogenated.
Claim 21
Dependent Claim 32 words
A composition according to claim 12, wherein said homogeneous mixtures essentially contains from 80 to 95% by weight of hydrocarbon oil and from 5 to 20% by weight of complex ester composition.
Claim 22
Dependent Claim 40 words
A composition according to claim 12, wherein said homogenous mixture contains from 10 to 40% by weight of light ester, from 50 to 80% by weight of hydrocarbon oil and from 1 to 40% by weight of complex ester composition.
Claim 23
Dependent Claim 30 words
The improved lubricating composition according to claim 12, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 20 W 40 rating.
Claim 24
Dependent Claim 30 words
The improved lubricating composition according to claim 12, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 10 W 30 rating.
Claim 25
Dependent Claim 283 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, and at least one monocarboxylic acid having the general formula R' 2 COOH, in which R' 2 is a monovalent hydrocarbon radical with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O--R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, the reagents being employed in proportions which substantially correspond to 1 mole of dimeric acid and 2 moles of monocarboxylic acid for 2 moles of dihydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 26
Dependent Claim 283 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a dimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, and at least one monocarboxylic acid having the general formula R' 2 COOH, in which R' 2 is a monovalent hydrocarbon radical with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O--R 1 ) n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, the reagents being employed in proportions which substantially correspond to 1 mole of dimeric acid and 2 moles of monocarboxylic acid for 2 moles of dihydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylenated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 27
Dependent Claim 22 words
A composition according to claim 23, wherein the dihydroxyl compound consists essentially of at least one polypropylene glycol having 2-30 oxypropylene groups.
Claim 28
Dependent Claim 44 words
A composition according to claim 24, wherein the dimeric acid results from the dimerization of C 18 unsaturated fatty acids, the dihydroxyl compound is a polypropylene glycol having a molecular weight of from about 130 to 1,800, and the monocarboxylic acid is lauric acid.
Claim 29
Dependent Claim 26 words
A composition according to claim 23, wherein the dimeric acid results from the dimerization of at least one unsaturated fatty acid that contains 18 carbon atoms.
Claim 30
Dependent Claim 35 words
A composition according to claim 23, wherein the hydrocarbon oil is selected from solvent-refined or acid-refined mineral oils and hydrorefined mineral oils, which have a viscosity at 37.8° C. of about 100 to 600 SSU.
Claim 31
Dependent Claim 28 words
A composition according to claim 23, wherein the hydrocarbon oil is selected from olefin polymers and mono- or polyalkylated aromatic compounds, which may be at least partially hydrogenated.
Claim 32
Dependent Claim 32 words
A composition according to claim 23, wherein said homogenous mixtures essentially contains from 80 to 95% by weight of hydrocarbon oil and from 5 to 20% by weight of complex ester composition.
Claim 33
Dependent Claim 40 words
A composition according to claim 23, wherein said homogenous mixture contains from 10 to 40% by weight of light ester, from 50 to 80% by weight of hydrocarbon oil and from 1 to 40% by weight of complex ester composition.
Claim 34
Dependent Claim 30 words
The improved lubricating composition according to claim 23, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 20 W 40 rating.
Claim 35
Dependent Claim 30 words
The improved lubricating composition according to claim 23, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 10 W 30 rating.
Claim 36
Dependent Claim 365 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a trimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ).sub. n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 -- OH, in which R 2 is an aliphatic, alicyclic or aromatic hydrocarbyl monovalent radical, and oxyalkylenated hydrocarbyl monohydric alcohols or monohydric phenols having the general formula R 2 -- O -- R 1 -- O ).sub. n H, in which R.sub. 1 and R 2 are as defined above and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 2 moles of trimeric acid for 1 mole of dihydroxyl compound and 4 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 37
Dependent Claim 365 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a trimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ).sub. n OH, in which R 1 is a 1,2-alkylene radical and n is a number of from 2 to 50, and diols having the general formula HO -- R 1 ' -- OH, in which R 1 ' is a divalent hydrocarbon radical, and with at least one monohydroxyl compound selected from monohydric hydrocarbyl alcohols, monohydric phenols of the formula R 2 -- OH, in which R 2 is an aliphatic, alicyclic or aromatic hydrocarbyl monovalent radical, and oxyalkylenated hydrocarbyl monohydric alcohols or monohydric phenols having the general formula R 2 -- O -- R 1 -- O ).sub. n H, in which R.sub. 1 and R 2 are as defined above and n' is a number of from 1 to 50, the reagents being employed in proportions which substantially correspond to 2 moles of trimeric acid for 1 mole of dihydroxyl compound and 4 moles of monohydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 38
Dependent Claim 37 words
A composition according to claim 33, wherein the dihydroxyl compound consists essentially of at least one polypropylene glycol having 2-30 oxypropylene groups and the monohydroxyl compound comprises at least one oxypropylenated monohydric alcohol having 1-30 oxypropylene groups.
Claim 39
Dependent Claim 26 words
A composition according to claim 33, wherein the trimeric acid results from the trimerization of at least one unsaturated fatty acid which contains 18 carbon atoms.
Claim 40
Dependent Claim 71 words
A composition according to claim 34, wherein the trimeric acid results from the trimerization of C 18 unsaturated fatty acids, the dihydroxyl compound is a polypropylene glycol having a molecular weight of from about 130 to 1,800, and the monohydroxyl compound is a monohydroxy polyether of condensation of 1,2-propylene oxide on an aliphatic monohydric alcohol having from 13 to 15 carbon atoms, which contains about 20 1,2-propylene oxide units per molecule.
Claim 41
Dependent Claim 35 words
A composition according to claim 33, wherein the hydrocarbon oil is selected from solvent-refined or acid-refined mineral oils and hydrorefined mineral oils, which have a viscosity at 37.8° C of about 100 to 600 SSU.
Claim 42
Dependent Claim 28 words
A composition according to claim 33, wherein the hydrocarbon oil is selected from olefin polymers and mono- or polyalkylated aromatic compounds, which may be at least partially hydrogenated.
Claim 43
Dependent Claim 32 words
A composition according to claim 33, wherein said homogenous mixtures essentially contains from 80 to 95% by weight of hydrocarbon oil and from 5 to 20% by weight of complex ester composition.
Claim 44
Dependent Claim 40 words
A composition according to claim 33, wherein said homogenous mixture contains from 10 to 40% by weight of light ester, from 50 to 80% by weight of hydrocarbon oil and from 1 to 40% by weight of complex ester composition.
Claim 45
Dependent Claim 30 words
The improved lubricating composition according to claim 33, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 20 W 40 rating.
Claim 46
Dependent Claim 30 words
The improved lubricating composition according to claim 33, wherein said viscosity index improver is added in an amount sufficient to yeild a final composition of SAE 10 W 30 rating.
Claim 47
Dependent Claim 287 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a trimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, and at least one monocarboxylic acid having the general formula R 2 ' COOH, in which R 2 ' is a monovalent hydrocarbon radical, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ) OH, in which R 1 is a 1,2, alkylene radical and n is a number of from 2 to 50, the reagents being employed in proportions which substantially correspond to 1 mole of trimeric acid and 3 moles of monocarboxylic acid for 3 moles of dihydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 48
Dependent Claim 287 words
In a lubricating composition usable as multigrade oil for motor-car engines, and comprising a major proportion of base oil of lubricating viscosity and, in amounts sufficient to effect each additives' attendant function, an additive selected from the group consisting of viscosity index improvers, antioxidants, detergents and mixtures thereof, the improvement which comprises utilizing as the base oil a homogeneous mixture comprising: a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity, b. from 1 to 50% by weight of at least one complex ester composition produced by the esterification of a trimeric acid derived from at least one unsaturated fatty acid which contains from 14 to 22 carbon atoms, and at least one monocarboxylic acid having the general formula R 2 ' COOH, in which R 2 ' is a monovalent hydrocarbon radical, with at least one dihydroxyl compound selected from polyalkylene glycols having the general formula H -- O -- R 1 ) OH, in which R 1 is a 1,2, alkylene radical and n is a number of from 2 to 50, the reagents being employed in proportions which substantially correspond to 1 mole of trimeric acid and 3 moles of monocarboxylic acid for 3 moles of dihydroxyl compound, and c. from 0 to 40% by weight of at least one light ester selected from esters of monohydric hydrocarbyl alcohols and hydrocarbyl dicarboxylic acids, esters of polyols and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl monocarboxylic acids, esters of polyoxyalkylinated hydrocarbyl monohydric alcohols of a low degree of condensation and hydrocarbyl dicarboxylic acids, and esters of polyoxalkylene glycols of low molecular weight and hydrocarbyl monocarboxylic acids.
Claim 49
Dependent Claim 24 words
A composition according to claim 43, characterized in that the dihydroxyl compound consists essentially of at least one polypropylene glycol having 2-30 oxypropylene groups.
Claim 50
Dependent Claim 43 words
A composition to claim 44, wherein the trimeric acid results from the trimerization of C 18 unsaturated fatty acids, the dihydroxyl compound is a polypropylene glycol having a molecular weight of from about 130 to 1,800, and the monocarboxylic acid is lauric acid.
Claim 51
Dependent Claim 26 words
A composition according to claim 43 wherein the trimeric acid results from the trimerization of at least one unsaturated fatty acid which contains 18 carbon atoms.
Claim 52
Dependent Claim 35 words
A composition according to claim 43, wherein the hydrocarbon oil is selected from solvent-refined or acid-refined mineral oils and hydrorefined mineral oils, which have a viscosity at 37.8° C of about 100 to 600 SSU.
Claim 53
Dependent Claim 28 words
A composition according to claim 43, wherein the hydrocarbon oil is selected from olefin polymers and mono- or polyalkylated aromatic compounds, which may be at least partially hydrogenated.
Claim 54
Dependent Claim 32 words
A composition according to claim 43, wherein said homogenous mixtures essentially contains from 80 to 95% by weight of hydrocarbon oil and from 5 to 20% by weight of complex ester composition.
Claim 55
Dependent Claim 40 words
A composition according to claim 43, wherein said homogenous mixture contains from 10 to 40% by weight of light ester, from 50 to 80% by weight of hydrocarbon oil and from 1 to 40% by weight of complex ester composition.
Claim 56
Dependent Claim 30 words
The improved lubricating composition according to claim 43, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 20 W 40 rating.
Claim 57
Dependent Claim 30 words
The improved lubricating composition according to claim 43, wherein said viscosity index improver is added in an amount sufficient to yield a final composition of SAE 10 W 30 rating.

References Cited (Backward Citations)

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-18 1981-01-17 1981-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-18 1985-01-17 1985-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-18 1989-01-17 1989-07-19 $7700.00 Window Closed / Lapsed

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