Aqueous insoluble polymers containing a plurality of diazomethylene groups

Claim 2

An aqueous insoluble polymer possessing a plurality of diazomethylene groups wherein each diazomethylene group either forms part of the polymer backbone chain or forms part of a side chain attached to the polymer backbone chain in which case one of the valencies of each diazomethylene group is linked to the polymer backbone chain and the other valency is bonded to an organic substituting group selected from the group consisting of (i) alkyl containing 1-20 carbon atoms, (ii) cycloalkyl containing 5-7 carbon atoms, (iii) aryl, (iv) aralkyl containing 1-6 carbon atoms in the alkyl portion, (v) 5- or 6-membered heterocyclic rings containing one or more hetero atoms selected from O, N and S, (vi) alkyl of 1-6 carbon atoms substituted by a heterocyclic ring as defined in (v), (vii) alkenyl of up to 6 carbon atoms, (viii) cycloalkenyl of 5-7 (ix) alkenyl of up to 6 carbon atoms substituted by aryl or a heterocyclic ring as defined in (v) or any of groups (i)-(ix) substituted by one or more halogen atoms, cyano, nitro, sulphone, oxo, esterified carboxy, C 1-6 alkyl, or C 1-6 alkoxy groups.

Claim 3

A polymer as claimed in claim 1 wherein the diazomethylene groups are linked to the polymer backbone through an alkylene or arylene group.

Claim 4

A polymer as claimed in claim 1 in which the backbone chain contains units derived from styrene.

Claim 5

A polymer as claimed in claim 1 wherein one of the valencies of each diazomethylene group is linked to the polymer backbone chain through a phenyl group and the other valency is linked to a phenyl group which may be substituted by one or more alkyl or alkoxy groups.

Claim 6

A polymer possessing a plurality of diazomethylene groups wherein each diazomethylene group either forms part of the polymer backbone chain or forms part of a side chain attached to the polymer backbone chain in which case one of the valencies of each diazomethylene group is linked to the polymer backbone chain and the other valency is bonded to an organic substituting group selected from the group consisting of (i) alkyl containing 1-20 carbon atoms, (ii) cycloalkyl containing 5-7 carbon atoms, (iii) aryl, (iv) aralkyl containing 1-6 carbon atoms in the alkyl portion, (v) 5- or 6-membered heterocyclic rings containing one or more hetero atoms selected from O, N and S, (vi) alkyl of 1-6 carbon atoms substituted by a heterocyclic ring as defined in (v), (vii) vinyl or allyl, (viii) cycloalkenyl of 5-7 carbon atoms and (ix) alkenyl of up to 6 carbon atoms substituted by aryl or a heterocyclic ring as defined in (v) or any of groups (i)-(ix) substituted by one or more halogen atoms, cyano, nitro, sulphone, oxo, esterified carboxy, C 1-6 alkyl, or C 1-6 alkoxy groups; said polymer backbone chain containing units derived from styrene and being crosslinked by the presence of from 0.1 to 7% by weight of divinyl benzene.

Claim 7

A polymer possessing a plurality of diazomethylene groups wherein each diazomethylene group either forms part of the polymer backbone chain or forms part of a side chain attached to the polymer backbone chain in which case one of the valencies of each diazomethylene group is linked to the polymer backbone chain and the other valency is bonded to an organic substituting group selected from the group consisting of (i) alkyl containing 1-20 carbon atoms, (ii) cycloalkyl containing 5-7 carbon atoms, (iii) aryl, (iv) aralkyl containing 1-6 carbon atoms in the alkyl portion, (v) 5- or 6-membered heterocyclic rings containing one or more hetero atoms selected from O, N and S, (vi) alkyl of 1-6 carbon atoms substituted by a heterocyclic ring as defined in (v), (vii) vinyl or allyl, (viii) cycloalkenyl of 5-7 carbon atoms and (ix) alkenyl of up to 6 carbon atoms substituted by aryl or a heterocyclic ring as defined in (v) or any of groups (i)-(ix) substituted by one or more halogen atoms, cyano, nitro, sulphone, oxo, esterified carboxy, C 1-6 alkyl, or C 1-6 alkoxy groups; said polymer backbone chain containing units derived from styrene and being crosslinked by the presence of from 0.1 to 7% by weight of divinyl benzene.