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US4039523A Expired / Lapsed US ⏱️ 0.0 years remaining

3-Sulfoalkyl-6-hydroxy-pyrid-(2)-one-containing azo dyestuffs

Assignee: Novartis AG
•
Filing: 1974-12-24
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Granted: 1977-08-02
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Expires: 1994-12-24
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Abstract

Abstract An azo dyestuff of the formula ##STR1## in which D is benzene or naphthalene, optionally substituted by sulfonic acid, carboxy, hydroxy, halogen, nitro, amino, lower alkylamino, lower alkyl, lower alkoxy, lower alkylsulfonyl, trifluoromethyl, cyano, cyclohexyloxycarbonyl, sulfonic acid-N-lower alkylamide, sulfonic acid N-lower alkoxy-loweralkylamide, lower acylamino, phenylazo, sulfophenylazo, sulfonaphthylazo, β-sulfatoethylsulfonyl, β-sulfatoethylsulfonamido, aminosulfonyloxy and a fibre-reactive radical bound via an amino group; or is thiazole, quinoline, benzthiazole, 6-methylbenzthiazole, 1,3,5-thiadiazole or benzisothiazole; R is hydrogen, lower alkyl, lower halogenalkyl, lower hydroxyalkyl, lower acylamino-lower alkyl, phenyl-lower alkyl, phenyl, halogenphenyl, lower alkoxyphenyl, lower acylaminophenyl, lower acylamino-lower alkyl and amino-lower alkyl, in which the amino group is optionally substituted by a fibre-reactive radical; R' is hydrogen, lower alkyl, phenyl-lower alkyl, phenyl, halogenphenyl and lower alkoxy-phenyl; and V is hydrogen, lower alkyl and phenyl, optionally substituted by halogen, nitro, cyano, amino, lower acylamino and a fibre-reactive radical bound via an amino group; and the heavy metal complex compound thereof, is suitable for dyeing and printing widely different types of materials, such as natural and synthetic polyamide and cellulose materials of fibrous structure. These dyestuffs show an excellent building-up capacity and valuable yellow pure and brilliant shades. The dyeings and prints exhibit a good stability to acids and alkalis, a good fastness to light and a good fastness to wet processing.

Inventors

  • 👤 Gert Hegar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 05:32
CPC Classifications
C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/60; C07D213/62; C07D213/69; C07D213/78; C07D213/79; C07D213/80; C07D213/81; C07D213/82; C09; C09B; C09B45/00; C09B45/02; C09B45/025; C09B62/00; C09B62/002; C09B62/006; C09B62/0067; C09B62/008; C09B62/0088

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 208 words
An azo dyestuff of the formula ##STR21## in which D is benzene or naphthalene, unsubstituted or substituted by sulfonic acid, carboxy, hydroxy, chloro, bromo, NH 2 --, lower alkylamino, lower alkyl, lower alkoxy, lower alkylsulfonyl, trifluoromethyl, cyano, cyclohexyloxycarbonyl, sulfonic acid-N-lower alkylamide, sulfonic acid-N-lower alkoxyloweralkylamide, acetylamino, phenylazo, sulfophenylazo, sulfonaphthylazo, β-sulfatoethylsulfonyl, aminosulfonyloxy or a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides and bound via an amino group; or is thiazole, quinoline, benzthiazole, 6-methylbenzthiazole, 1,3,5-thiadiazole or benzisothiazole; R is hydrogen, lower alkyl, lower chloroalkyl, lower hydroxyalkyl, acetylamino-lower alkyl, phenyl-lower alkyl, phenyl, chlorophenyl, lower alkoxyphenyl, acetaminophenyl or amino-lower alkyl, in which the amino group is unsubstituted or substituted by a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides; R' is hydrogen, lower alkyl, phenyl-lower alkyl, phenyl, chlorophenyl or lower alkoxy-phenyl; and V is hydrogen, lower alkyl or phenyl, unsubstituted or substituted by chloro, nitro, cyano, NH 2 -- or a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides and bound via an amino group; and the heavy metal complex compound thereof selected from the group consisting of iron, manganese, nickel, copper, cobalt and chromium.
Claim 2
Dependent Claim 208 words
An azo dyestuff of the formula ##STR21## in which D is benzene or naphthalene, unsubstituted or substituted by sulfonic acid, carboxy, hydroxy, chloro, bromo, NH 2 --, lower alkylamino, lower alkyl, lower alkoxy, lower alkylsulfonyl, trifluoromethyl, cyano, cyclohexyloxycarbonyl, sulfonic acid-N-lower alkylamide, sulfonic acid-N-lower alkoxyloweralkylamide, acetylamino, phenylazo, sulfophenylazo, sulfonaphthylazo, β-sulfatoethylsulfonyl, aminosulfonyloxy or a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides and bound via an amino group; or is thiazole, quinoline, benzthiazole, 6-methylbenzthiazole, 1,3,5-thiadiazole or benzisothiazole; R is hydrogen, lower alkyl, lower chloroalkyl, lower hydroxyalkyl, acetylamino-lower alkyl, phenyl-lower alkyl, phenyl, chlorophenyl, lower alkoxyphenyl, acetaminophenyl or amino-lower alkyl, in which the amino group is unsubstituted or substituted by a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides; R' is hydrogen, lower alkyl, phenyl-lower alkyl, phenyl, chlorophenyl or lower alkoxy-phenyl; and V is hydrogen, lower alkyl or phenyl, unsubstituted or substituted by chloro, nitro, cyano, NH 2 -- or a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides and bound via an amino group; and the heavy metal complex compound thereof selected from the group consisting of iron, manganese, nickel, copper, cobalt and chromium.
Claim 3
Dependent Claim 118 words
An azo dyestuff as claimed in claim 1 of the formula ##STR22## in which D' is sulfobenzene, R and R' each is hydrogen or alkyl with 1 to 4 carbon atoms, one Y is chloro or bromo and the other Y is chloro, bromo, amino, phenylamino, sulfophenylamino, sulfonaphthylamino, carboxyphenylamino, alkoxy with 1 to 4 carbon atoms, alkoxyalkoxy with 1 to 8 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, ureido, morpholino, or a residue of the formula ##STR23## in which D' is phenylene or sulfophenylene or a residue of the formula ##STR24## in which D', R and R' are as defined above; D" is phenylene, sulfophenylene, sulfostilbene, sulfodiphenyl or sulfodiphenylurea.
Claim 4
Dependent Claim 55 words
An azo dyestuff as claimed in claim 1 of the formula ##STR25## in which D, R and R' are as defined in claim 1, V' is phenylene, R 1 is hydrogen or lower alkyl and Z is a fibre-reactive radical capable of reacting with the hydroxyl groups of cellulose or the amino groups of polyamides.
Claim 5
Dependent Claim 74 words
An azo dyestuff as claimed in claim 1 of the formula ##STR26## in which D is sulfobenzene, R and R' each is lower alkyl and one Y is chloro or bromo and the other Y is chloro, bromo, amino, phenylamino, sulfophenylamino, sulfonaphthylamino, carboxyphenylamino, alkoxy with 1 to 4 carbon atoms, alkoxyalkoxy with 1 to 8 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, ureido and morpholino.
Claim 6
Dependent Claim 12 words
The azo dyestuff as claimed in claim 2 of the formula ##STR27##
Claim 7
Dependent Claim 12 words
The azo dyestuff as claimed in claim 2 of the formula ##STR28##

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-01 1981-01-31 1981-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-01 1985-01-31 1985-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-01 1989-01-31 1989-08-02 $7700.00 Window Closed / Lapsed

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