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US4039640A Expired / Lapsed US ⏱️ 0.0 years remaining

Moldable compositions comprising polyvinyl nitrate

Assignee: Societe Nationale des Poudres et Explosifs
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Filing: 1976-08-05
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Granted: 1977-08-02
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Expires: 1996-08-05
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Abstract

Abstract A mouldable thermoplastic composition comprises (i) polyvinyl nitrate, (ii) nitrocellulose and/or polyvinyl acetate and (iii) 2-nitro-diphenylamine and may be used to form combustible articles such as cartridge cases. Preferably, the composition comprises from 30 to 90% by weight of polyvinyl nitrate based on the total weight of components (i) and (ii). The composition may comprise up to about 30% by weight, based on the weight of components (i) and (ii), of at least one additive selected from cellulose acetate, dinitrotoluene, phthalates, non-volatile esters, heterocyclic ketones, ureas and ABS copolymers.

Inventors

  • 👤 Louis J. Leneveu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 07:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/32; C06; C06B; C06B21/00; C06B21/0033; C06B21/005; C06B21/0091; C06B45/00; C06B45/04; C06B45/06; C06B45/10; C06B45/105; C08L; C08L1/00; C08L1/08; C08L1/16; C08L1/18; C08L39/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 67 words
A method of making a combustible article, which comprises mixing (i) polyvinyl nitrate, (ii) at least one material selected from the group consisting of nitrocellulose and polyvinyl acetate, and (iii) 2-nitrodiphenylamine, in an organic solvent, forming fibers, stretching the fibers, forming granules, heating the granules to a temperature between their softening temperature and their decomposition temperature, and moulding the granules so formed to produce the combustible article.
Claim 2
Independent Claim 67 words
A method of making a combustible article, which comprises mixing (i) polyvinyl nitrate, (ii) at least one material selected from the group consisting of nitrocellulose and polyvinyl acetate, and (iii) 2-nitrodiphenylamine, in an organic solvent, forming fibers, stretching the fibers, forming granules, heating the granules to a temperature between their softening temperature and their decomposition temperature, and moulding the granules so formed to produce the combustible article.
Claim 3
Dependent Claim 25 words
A method according to claim 1, which comprises mixing the granules of the mouldable thermoplastic composition with a porous powder comprising nitrocellulose prior to moulding.
Claim 4
Dependent Claim 44 words
The method according to claim 1 which additionally comprises dehydrating polyvinyl nitrate with isopropyl alcohol and the granules are prepared by grinding said dehydrated polyvinyl nitrate, mixing with said component (ii), in a solvent, adding 2-nitro-diphenylamine, stretching the resulting fibers and cutting into granules.
Claim 5
Dependent Claim 20 words
The method according to claim 1 wherein the molding step is compression moulding at a pressure of about 10 bars.
Claim 6
Dependent Claim 13 words
The method according to claim 1 wherein the molding step is injection moulding.
Claim 7
Dependent Claim 17 words
The method according to claim 1 wherein said polyvinyl nitrate constitutes 30-90% of weight of said granules.
Claim 8
Dependent Claim 21 words
The method according to claim 2 wherein said porous powder comprising nitrocellulose constitutes up to 60% by weight of the mixture.

References Cited (Backward Citations)

US3078200A Cited
US3422170A Cited
US3428502A Cited
US3447983A Cited
US3563977A Cited
US3669924A Cited
US3673286A Cited
US3779820A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-01 1981-01-31 1981-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-01 1985-01-31 1985-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-01 1989-01-31 1989-08-02 $7700.00 Window Closed / Lapsed

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