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US4042539A Expired / Lapsed US ⏱️ 0.0 years remaining

Primer-surfacer composition of an acrylic polymer, a polyester resin and an organic dispersant

Assignee: EIDP Inc
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Filing: 1975-10-30
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Granted: 1977-08-16
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Expires: 1995-10-30
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Abstract

Abstract The primer-surfacer composition contains a binder of An acrylic polymer of methyl methacrylate, an alkyl acrylate or an alkyl methacrylate and an ethylenically unsaturated carboxylic acid that is reacted with an alkylene imine such as ethylene imine, or propylene imine, A polyester resin, and An organic dispersant; And the primer-surfacer contains suitable pigments such as talc, barytes, titanium dioxide and zinc oxide pigments; The composition is primarily used over unprimed, primed or previously finished metal substrates to provide a surface to which an acrylic lacquer, an acrylic enamel, an alkyd enamel or a polyurethane enamel coating can be applied and provides a finish for automobiles and trucks which has excellent intercoat adhesion, excellent chip resistance, corrosion resistance and resistance to deterioration from exposure to water and high humidity.

Inventors

  • 👤 Herbert H. Fanning

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:59
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/10; C09D133/12

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 289 words
A primer-surfacer composition comprising 10-60% by weight of a binder and 40-90% by weight of a solvent for the binder; wherein the binder consists essentially of A. 75.0-95.0% by weight, based on the weight of the binder, of an acrylic polymer in solution consisting essentially of 1. 70-90% by weight of methyl methacrylate, 2. 9-19% by weight of an alkyl methacrylate having 2-8 carbon atoms in the alkyl group or an alkyl acrylate having 2-12 carbon atoms in the alkyl group, and 3. 1-11% by weight of either acrylic acid or methacrylic acid that is reacted with 1-8% by weight of an alkylene imine; b. 4.9-24.9% by weight, based on the weight of the binder, of a polyester resin in solution which is the esterification product of 25 to 48 mole percent of a saturated aliphatic dicarboxylic acid selected from the group consisting of adipic acid, succinic acid, malonic acid, glutaric acid, sebacic acid, and azelaic acid; 40 to 50 mole percent of a glycol selected from the group consisting of ethylene glycol and neopentyl glycol; and 2to 35 mole percent of an aromatic carboxylic acid constituent selected from the group consisting of benzoic acid, paratertiary butyl benzoic acid, phthalic acid, phthalic anhydride or mixtures thereof; wherein the polyester has a hydroxyl number of not greater than 15 and an acid number of not greater than 10; C. 0.1-5.0% by weight, based on the weight of the binder, of an organic pigment dispersant consisting essentially of a material represented by the structure ##STR6## where B is a methyl methacrylate/2-ethylhexyl acrylate copolymeric segment having a number average molecular weight of about 3,000 to 10,000 and containing pigment in a pigment to binder weight ratio of about 100:100 to about 600:100.
Claim 2
Dependent Claim 289 words
A primer-surfacer composition comprising 10-60% by weight of a binder and 40-90% by weight of a solvent for the binder; wherein the binder consists essentially of A. 75.0-95.0% by weight, based on the weight of the binder, of an acrylic polymer in solution consisting essentially of 1. 70-90% by weight of methyl methacrylate, 2. 9-19% by weight of an alkyl methacrylate having 2-8 carbon atoms in the alkyl group or an alkyl acrylate having 2-12 carbon atoms in the alkyl group, and 3. 1-11% by weight of either acrylic acid or methacrylic acid that is reacted with 1-8% by weight of an alkylene imine; b. 4.9-24.9% by weight, based on the weight of the binder, of a polyester resin in solution which is the esterification product of 25 to 48 mole percent of a saturated aliphatic dicarboxylic acid selected from the group consisting of adipic acid, succinic acid, malonic acid, glutaric acid, sebacic acid, and azelaic acid; 40 to 50 mole percent of a glycol selected from the group consisting of ethylene glycol and neopentyl glycol; and 2to 35 mole percent of an aromatic carboxylic acid constituent selected from the group consisting of benzoic acid, paratertiary butyl benzoic acid, phthalic acid, phthalic anhydride or mixtures thereof; wherein the polyester has a hydroxyl number of not greater than 15 and an acid number of not greater than 10; C. 0.1-5.0% by weight, based on the weight of the binder, of an organic pigment dispersant consisting essentially of a material represented by the structure ##STR6## where B is a methyl methacrylate/2-ethylhexyl acrylate copolymeric segment having a number average molecular weight of about 3,000 to 10,000 and containing pigment in a pigment to binder weight ratio of about 100:100 to about 600:100.
Claim 3
Dependent Claim 47 words
The primer-surfacer composition of claim 1 in which the acrylic polymer consists essentially of 1. 78-82% by weight of methyl methacrylate, 2. 9-17% by weight of ethyl acrylate, and 3. 5-9% by weight of methacrylic acid reacted with 4-6% by weight of ethylene imine or propylene imine.
Claim 4
Dependent Claim 25 words
The primer-surfacer composition of claim 2 in which the polyester resin is the esterification product of adipic acid, ethylene glycol, benzoic acid and phthalic anhydride.
Claim 5
Dependent Claim 21 words
The primer-surfacer composition of claim 1 in which the pigments comprise a blend of talc, barytes, zinc oxide and titanium dioxide.
Claim 6
Dependent Claim 60 words
The primer surfacer composition of claim 1 comprising about 15-25% by weight of a binder and correspondingly 75-85% by weight of a solvent for the binder; wherein the binder consists essentially of A. 80.0-90.0% by weight of an acrylic polymer in solution consisting essentially of 1. 78-82% by weight, based on the weight of the acrylic polymer, of methyl methacrylate,
Claim 7
Dependent Claim 158 words
9-17% by weight, based on the weight of the acrylic polymer, of ethyl acrylate, and 3. 5-9% by weight, based on the weight of the acrylic polymer, of methacrylic acid reacted with about 4-6% by weight of ethylene imine or propylene imine, B. 7.8-19.8% by weight of a polyester resin in solution that is the esterification product of 25 to 48 mole per cent of adipic acid, 40 to 50 mole per cent of ethylene glycol, and 2 to 35 mole per cent of a mixture of phthalic anhydride and benzoic acid, C. 0.2-2.2% by weight of an organic dispersant consisting essentially of a material represented by the structure ##STR7## where B is a MMA/2-EHA copolymeric segment having a number averge molecular weight of about 3,000 to 10,000; and containing pigment in a pigment to binder ratio to about 100:100 to 300:100 wherein the pigment consists essentially of a blend of talc, barytes, zinc oxide and titanium dioxide.
Claim 8
Dependent Claim 158 words
9-17% by weight, based on the weight of the acrylic polymer, of ethyl acrylate, and 3. 5-9% by weight, based on the weight of the acrylic polymer, of methacrylic acid reacted with about 4-6% by weight of ethylene imine or propylene imine, B. 7.8-19.8% by weight of a polyester resin in solution that is the esterification product of 25 to 48 mole per cent of adipic acid, 40 to 50 mole per cent of ethylene glycol, and 2 to 35 mole per cent of a mixture of phthalic anhydride and benzoic acid, C. 0.2-2.2% by weight of an organic dispersant consisting essentially of a material represented by the structure ##STR7## where B is a MMA/2-EHA copolymeric segment having a number averge molecular weight of about 3,000 to 10,000; and containing pigment in a pigment to binder ratio to about 100:100 to 300:100 wherein the pigment consists essentially of a blend of talc, barytes, zinc oxide and titanium dioxide.
Claim 9
Dependent Claim 285 words
A primer-surfacer composition comprising 10-60% by weight of a binder and 40-90% by weight of a solvent for the binder; wherein the binder consists essentially of A. 60.0-95.0% by weight, based on the weight of the binder, of an acrylic polymer in solution consisting essentially of 1. 70-90% by weight of methyl methacrylate, 2. 9-19% by weight of an alkyl methacrylate having 2-8 carbon atoms in the alkyl group or an alkyl acrylate having 2-12 carbon atoms in the alkyl group, and 3. 1-11% by weight of either acrylic acid or methacrylic acid that is reacted with 1-8% by weight of an alkylene imine; B. 4.9-39.9% by weight, based on the weight of the binder, of a polyester resin in solution which is the esterification product of 25to 48 mole percent of a saturated aliphatic dicarboxylic acid selected from the group consisting of adipic acid, succinic acid, malonic acid, glutaric acid, sebacic acid, and azelaic acid; 40 to 50 mole percent of a glycol selected from the group consisting of ethylene glycol and neopentyl glycol; and 2 to 35 mole percent of an aromatic carboxylic acid constituent selected from the group consisting of benzoic acid, paratertiary butyl benzoic acid, phthalic acid, phthalic anhydride or mixtures thereof; wherein the polyester has a hydroxyl number of not greater than 15 and an acid number of not greater than 10; C. 0.1-8.0% by weight, based on the weight of the binder, of an organic pigment dispersant selected from the group of ##STR8## where B is a methyl methacrylate/2-ethylhexyl acrylate copolymeric segment having a number average molecular weight of about 3,000 to 10,000 and containing pigment in a pigment to binder weight ratio of about 100:100 to about 600:100.
Claim 10
Dependent Claim 285 words
A primer-surfacer composition comprising 10-60% by weight of a binder and 40-90% by weight of a solvent for the binder; wherein the binder consists essentially of A. 60.0-95.0% by weight, based on the weight of the binder, of an acrylic polymer in solution consisting essentially of 1. 70-90% by weight of methyl methacrylate, 2. 9-19% by weight of an alkyl methacrylate having 2-8 carbon atoms in the alkyl group or an alkyl acrylate having 2-12 carbon atoms in the alkyl group, and 3. 1-11% by weight of either acrylic acid or methacrylic acid that is reacted with 1-8% by weight of an alkylene imine; B. 4.9-39.9% by weight, based on the weight of the binder, of a polyester resin in solution which is the esterification product of 25to 48 mole percent of a saturated aliphatic dicarboxylic acid selected from the group consisting of adipic acid, succinic acid, malonic acid, glutaric acid, sebacic acid, and azelaic acid; 40 to 50 mole percent of a glycol selected from the group consisting of ethylene glycol and neopentyl glycol; and 2 to 35 mole percent of an aromatic carboxylic acid constituent selected from the group consisting of benzoic acid, paratertiary butyl benzoic acid, phthalic acid, phthalic anhydride or mixtures thereof; wherein the polyester has a hydroxyl number of not greater than 15 and an acid number of not greater than 10; C. 0.1-8.0% by weight, based on the weight of the binder, of an organic pigment dispersant selected from the group of ##STR8## where B is a methyl methacrylate/2-ethylhexyl acrylate copolymeric segment having a number average molecular weight of about 3,000 to 10,000 and containing pigment in a pigment to binder weight ratio of about 100:100 to about 600:100.
Claim 11
Dependent Claim 47 words
The primer-surfacer composition of Claim 6 in which the acrylic polymer consists essentially of 1. 78-82% by weight of methyl methacrylate, 2. 9-17% by weight of ethyl acrylate, and 3. 5-9% by weight of methacrylic acid reacted with 4-6% by weight of ethylene imine or propylene imine.
Claim 12
Dependent Claim 25 words
The primer-surfacer composition of claim 7 in which the polyester resin is the esterification product of adipic acid, ethylene glycol, benzoic acid and phthalic anhydride.
Claim 13
Dependent Claim 21 words
The primer-surfacer composition of claim 8 in which the pigments comprise a blend of talc, barytes, zinc oxide and titanium dioxide.
Claim 14
Dependent Claim 24 words
The primer surfacer composition of claim 8 in which the pigments comprise a blend of talc, barytes, zinc oxide, iron oxide and carbon black.
Claim 15
Dependent Claim 59 words
The primer surfacer composition of claim 6 containing in addition to the binder constituent up to 20% by weight of cellulose acetate butyrate, based on the weight of the binder; wherein the cellulose acetate buryrate has a butyryl content of about 30-60% by weight and a viscosity of about 2-25 seconds measured at 25° C. determined according to ASTM-D-1343-56.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-15 1981-02-14 1981-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-15 1985-02-14 1985-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-15 1989-02-14 1989-08-16 $7700.00 Window Closed / Lapsed

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