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US4065381A Expired / Lapsed US ⏱️ 0.0 years remaining

Maintaining effective molar ratio of HF to metal pentafluoride in a hydrocarbon conversion process

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1976-12-29
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Granted: 1977-12-27
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Expires: 1996-12-29
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Abstract

Abstract A hydrocarbon phase separated from a hydrocarbon conversion process is solvent extracted with anhydrous liquid HF to separate metal pentafluoride which is carried over into the hydrocarbon phase. The extract of HF and metal fluoride is then combined with the catalyst phase (HF and metal pentafluoride) and stripped with hydrogen to reduce the molar ratio of HF to metal pentafluoride to the level that HF + metal pentafluoride catalyst is utilized in the hydrocarbon conversion process. The metal pentafluoride is TaF5 and/or NbF5 and the hydrocarbon conversion may involve isomerization, alkylation with olefins and reactions of a paraffin with another paraffin.

Inventors

  • 👤 Geoffrey R. Say
  • 👤 William C. Baird, Jr.
  • 👤 Paul W. Kamienski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:37
CPC Classifications
C; C07; C07C; C07C7/00; C07C7/10; B; B01; B01J; B01J27/00; B01J27/06; B01J27/08; B01J27/12; C07C5/00; C07C5/22; C07C5/2206; C07C5/2226; C07C5/2246; C07C5/2253; C07C2527/00; C07C2527/06; C07C2527/08; C07C2527/12; C07C2527/1206; C07C2527/135

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 257 words
In a hydrocarbon conversion process which comprises 1. converting a hydrocarbon feedstock with a substantially liquid phase acid catalyst comprising (a) a metal pentafluoride selected from the group consisting of tantalum pentafluoride, niobium pentafluoride and mixtures thereof, and (b) hydrogen fluoride, such that the reaction effluent from said process is separated in a settling zone into a hydrocarbon phase containing minor amounts of metal pentafluoride and a catalyst phase; 2. removing at least a portion of the metal pentafluoride from the hydrocarbon phase by contact with a solvent comprising substantially anhydrous liquid hydrogen fluoride, thereby forming a hydrocarbon phase depleted in metal pentafluoride and an extract phase containing hydrogen fluoride and the metal pentafluoride thus removed, the molar ratio of hydrogen fluoride to metal pentafluoride in said extract phase being greater than that desired in said hydrocarbon conversion process, the improvement which comprises maintaining the molar ratio of hydrogen fluoride to metal pentafluoride in the extract phase at the level desired in said hydrocarbon conversion process while inhibiting the deactivation of the catalyst phase by: 3. combining at least a portion of said extract phase with said catalyst phase in said settling zone to form a catalyst mixture and stripping said mixture with a gas containing molecular hydrogen for a time sufficient to reduce the molar ratio of hydrogen fluoride to metal pentafluoride in said catalyst mixture to the level desired in said hydrocarbon converting step (1); and 4. passing at least a portion of said stripped catalyst mixture from step (3) to said converting step (1).
Claim 2
Dependent Claim 257 words
In a hydrocarbon conversion process which comprises 1. converting a hydrocarbon feedstock with a substantially liquid phase acid catalyst comprising (a) a metal pentafluoride selected from the group consisting of tantalum pentafluoride, niobium pentafluoride and mixtures thereof, and (b) hydrogen fluoride, such that the reaction effluent from said process is separated in a settling zone into a hydrocarbon phase containing minor amounts of metal pentafluoride and a catalyst phase; 2. removing at least a portion of the metal pentafluoride from the hydrocarbon phase by contact with a solvent comprising substantially anhydrous liquid hydrogen fluoride, thereby forming a hydrocarbon phase depleted in metal pentafluoride and an extract phase containing hydrogen fluoride and the metal pentafluoride thus removed, the molar ratio of hydrogen fluoride to metal pentafluoride in said extract phase being greater than that desired in said hydrocarbon conversion process, the improvement which comprises maintaining the molar ratio of hydrogen fluoride to metal pentafluoride in the extract phase at the level desired in said hydrocarbon conversion process while inhibiting the deactivation of the catalyst phase by: 3. combining at least a portion of said extract phase with said catalyst phase in said settling zone to form a catalyst mixture and stripping said mixture with a gas containing molecular hydrogen for a time sufficient to reduce the molar ratio of hydrogen fluoride to metal pentafluoride in said catalyst mixture to the level desired in said hydrocarbon converting step (1); and 4. passing at least a portion of said stripped catalyst mixture from step (3) to said converting step (1).
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein the metal pentafluoride is tantalum pentafluoride.
Claim 4
Dependent Claim 65 words
The process of claim 1 wherein the metal pentafluoride removal step (2) is effected at a temperature in the range of from about 0° to about 200° F., at a pressure in the range of from about 20 to about 250 psig, and at a volume ratio of said liquid hydrogen fluoride to the hydrocarbon phase in the range of from about 1:200 to 1:1.
Claim 5
Dependent Claim 27 words
The process of claim 1 wherein the molar ratio of hydrogen fluoride to metal pentafluoride in said hydrocarbon converting step (1) ranges from about 1 to 40.
Claim 6
Dependent Claim 18 words
The process of claim 1 wherein said hydrocarbon converting step (1) is effected in the presence of hydrogen.
Claim 7
Dependent Claim 45 words
The process of claim 5 wherein said hydrocarbon converting step (1) is isomerization and said hydrocarbon feedstock is selected from the group consisting of an acyclic hydrocarbon having at least 4 carbon atoms, an alicyclic hydrocarbon having at least 6 carbon atoms and mixtures thereof.
Claim 8
Dependent Claim 49 words
The process of claim 5 wherein in said hydrocarbon converting step (1) said hydrocarbon feedstock is selected from the group consisting of an acyclic hydrocarbon an alicyclic hydrocarbon having at least 5 carbon atoms, an aromatic, hydrocarbon, an alkylaromatic hydrocarbon having at least 6 carbon atoms and mixtures thereof.
Claim 9
Dependent Claim 47 words
The process of claim 1 wherein in said hydrocarbon converting step (1) said hydrocarbon feedstock is selected from the group consisting of an acyclic hydrocarbon an alicyclic hydrocarbon having at least 5 carbon atoms, hydrocarbon, an alkylaromatic hydrocarbon having at least 6 carbon atoms and mixtures thereof.
Claim 10
Dependent Claim 52 words
The process of claim 1 wherein in said hydrocarbon converting step (1) said hydrocarbon feedstock is selected from the group consisting of i-C 4 -C 6 aliphatic hydrocarbons, C 5 -C 15 cycloaliphatic hydrocarbons and mixtures thereof and said hydrocarbon feedstock is reacted with a paraffin having more than 6 carbon atoms.

References Cited (Backward Citations)

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US3852184A Cited
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US3728411A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-26 1981-06-27 1981-12-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-26 1985-06-27 1985-12-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-26 1989-06-27 1989-12-27 $7700.00 Window Closed / Lapsed

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