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US4082588A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal protecting lead/plastic laminate

Assignee: Department of National Defence
•
Filing: 1977-01-19
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Granted: 1978-04-04
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Expires: 1997-01-19
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Abstract

Abstract A method of protecting surfaces against deterioration by environmental factors is described. In a particular aspect of this invention a metal surface subject to electrochemical corrosion has applied to it a metal-plastic laminate comprising (a) a foil of corrosion-resistant metal, in particular lead; (b) a plastic film ranging up to about 20 mils in thickness, bonded to one surface of the metal foil, either by "extrusion coating" or by means of a suitable adhesive; and (c) a coating of pressure-sensitive adhesive on the opposite surface of the metal foil. (In some cases the outer plastic film can be omitted.) The laminate is bonded to the metal substrate by means of the pressure-sensitive adhesive. This method, when used in conjunction with a coating of anti-fouling paint, is effective for protecting the hull of a marine vessel both against corrosion and fouling by marine organisms such as barnacles; and the invention is also effective in protecting wooden vessels against marine borers. The method is relatively inexpensive and easy to carry out, and requires only a minimum of surface preparation of the substrate.

Inventors

  • 👤 William Arthur Anderton
  • 👤 Richard Benjamin Hollis Sewell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:39
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; B29; B29C; B29C63/00; B32B27/00; B32B27/30; B32B27/304; B32B37/00; B32B37/12; B63; B63B; B63B59/00; B63B59/04; E; E04; E04B; E04B1/00; E04B1/62; E04B1/64; E04B1/642; B32B2307/00; B32B2307/70; B32B2307/714; B32B2309/00; B32B2309/08; B32B2309/10; B32B2309/105; B32B2311/00; B32B2311/14; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 104 words
A method for protection against electrochemical corrosion of a metal substrate which is subject to said corrosion, said method comprising applying to said substrate a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said lead foil; whereby said laminate is bonded to the surface of said substrate by means of said pressure-sensitive adhesive.
Claim 2
Independent Claim 104 words
A method for protection against electrochemical corrosion of a metal substrate which is subject to said corrosion, said method comprising applying to said substrate a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said lead foil; whereby said laminate is bonded to the surface of said substrate by means of said pressure-sensitive adhesive.
Claim 3
Dependent Claim 14 words
A method as in claim 1 wherein the metal substrate is iron or steel.
Claim 4
Independent Claim 123 words
A method which comprises applying to the hull of a marine vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 20 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said foil, the laminate being bonded to said hull by means of said pressure-sensitive adhesive; and (d) applied to the outer surface of said plastic film, a protective coating layer having anti-fouling properties; whereby the hull of said vessel is protected both against electrochemical corrosion and against fouling by marine organisms.
Claim 5
Independent Claim 123 words
A method which comprises applying to the hull of a marine vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 20 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said foil, the laminate being bonded to said hull by means of said pressure-sensitive adhesive; and (d) applied to the outer surface of said plastic film, a protective coating layer having anti-fouling properties; whereby the hull of said vessel is protected both against electrochemical corrosion and against fouling by marine organisms.
Claim 6
Dependent Claim 18 words
A method as in claim 1 wherein the laminate is applied by rolling it onto said metal substrate.
Claim 7
Independent Claim 97 words
A method of protecting a steel marine vessel against electrochemical corrosion, which comprises applying to the hull of said vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said lead foil; whereby said laminate is bonded to said hull by means of said pressure-sensitive adhesive.
Claim 8
Independent Claim 97 words
A method of protecting a steel marine vessel against electrochemical corrosion, which comprises applying to the hull of said vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; and (c) a coating of pressure-sensitive adhesive on the opposite surface of said lead foil; whereby said laminate is bonded to said hull by means of said pressure-sensitive adhesive.
Claim 9
Independent Claim 117 words
A method of protecting a wooden marine vessel against marine borers and fouling organisms which comprises applying to the hull of said vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; (c) a coating of pressure-sensitive adhesive on the opposite surface of said metal foil; and (d) a protective coating layer having anti-fouling properties applied to the outer surface of said plastic film; whereby said laminate is bonded to said hull by means of said pressure-sensitive adhesive.
Claim 10
Independent Claim 117 words
A method of protecting a wooden marine vessel against marine borers and fouling organisms which comprises applying to the hull of said vessel a metal-plastic laminate comprising (a) a foil of corrosion-resistant lead, said foil having a thickness from about 1 to about 25 mils; (b) a plastic film of thickness ranging from 0 to about 20 mils, one surface of which is bonded to one surface of said metal foil; (c) a coating of pressure-sensitive adhesive on the opposite surface of said metal foil; and (d) a protective coating layer having anti-fouling properties applied to the outer surface of said plastic film; whereby said laminate is bonded to said hull by means of said pressure-sensitive adhesive.
Claim 11
Dependent Claim 25 words
A method as set forth in claim 1 wherein the plastic film is bonded to said one surface of the lead foil by extrusion lamination.
Claim 12
Dependent Claim 25 words
A method as set forth in claim 6 wherein the plastic film is bonded to said one surface of the lead foil by extrusion lamination.
Claim 13
Dependent Claim 25 words
A method as set forth in claim 3 wherein the plastic film is bonded to said one surface of the metal foil by extrusion lamination.
Claim 14
Dependent Claim 21 words
A method as in claim 1 wherein the plastic film is adhesively secured to said one surface of the metal foil.
Claim 15
Dependent Claim 21 words
A method as in claim 6 wherein the plastic film is adhesively secured to said one surface of the lead foil.
Claim 16
Dependent Claim 21 words
A method as in claim 3 wherein the plastic film is adhesively secured to said one surface of the lead foil.
Claim 17
Dependent Claim 17 words
A method as in claim 5 wherein the laminate is applied by rolling it onto said hull.
Claim 18
Dependent Claim 17 words
A method as in claim 6 wherein the laminate is applied by rolling it onto said hull.
Claim 19
Dependent Claim 23 words
A method as in claim 5 wherein the plastic film is bonded to said one surface of the lead foil by extrusion lamination.
Claim 20
Dependent Claim 18 words
A method as set forth in claim 1 wherein the lead foil has a thickness of 5-6 mils.
Claim 21
Dependent Claim 18 words
A method as set forth in claim 6 wherein the lead foil has a thickness of 5-6 mils.
Claim 22
Dependent Claim 16 words
A method as defined in claim 1 wherein the plastic film is omitted from the laminate.
Claim 23
Dependent Claim 16 words
A method as defined in claim 6 wherein the plastic film is omitted from the laminate.
Claim 24
Dependent Claim 13 words
A method as defined in claim 1 wherein the plastic film is saran.
Claim 25
Dependent Claim 13 words
A method as defined in claim 6 wherein the plastic film is saran.
Claim 26
Dependent Claim 15 words
A method as defined in claim 1 wherein the pressure-sensitive adhesive is a polyvinyl ether.
Claim 27
Dependent Claim 15 words
A method as defined in claim 6 wherein the pressure-sensitive adhesive is a polyvinyl ether.
Claim 28
Dependent Claim 25 words
A method as defined in claim 1 wherein saran film is secured to one surface of said lead foil by means of polyvinyl butyral adhesive.
Claim 29
Dependent Claim 25 words
A method as defined in claim 6 wherein saran film is secured to one surface of a lead foil by means of polyvinyl butyral adhesive.
Claim 30
Dependent Claim 25 words
A method as defined in claim 5 wherein saran film is secured to one surface of said lead foil by means of polyvinyl butyral adhesive.
Claim 31
Dependent Claim 17 words
A method as in claim 6 wherein the laminate is applied by rolling it onto said surface.
Claim 32
Dependent Claim 31 words
A method as set forth in claim 1 wherein the substrate to be protected is a generally cylindrical metal body, and the lead-plastic laminate is applied thereto in a spiral pattern.
Claim 33
Dependent Claim 31 words
A method as set forth in claim 6 wherein the substrate to be protected is a generally cylindrical metal body, and the metal-plastic laminate is applied thereto in a spiral pattern.
Claim 34
Dependent Claim 21 words
A method as in claim 5 wherein the plastic film is adhesively secured to said one surface of the lead foil.
Claim 35
Dependent Claim 16 words
A method as defined in claim 5 wherein the plastic film is omitted from the laminate.
Claim 36
Dependent Claim 13 words
A method as defined in claim 5 wherein the plastic film is saran.

References Cited (Backward Citations)

US3323965A Cited
US3582452A Cited
US3600268A Cited
US3607614A Cited
US3719551A Cited
US3740958A Cited
US3761334A Cited
US3912519A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-04-03 1981-10-03 1982-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-04-03 1985-10-03 1986-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-04-03 1989-10-03 1990-04-04 $7700.00 Window Closed / Lapsed

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