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US4082876A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for producing foamed body having chemical embossed patterns and resultant product

Assignee: Lonseal Corp
•
Filing: 1976-02-18
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Granted: 1978-04-04
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Expires: 1996-02-18
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Abstract

Abstract Methods for producing bodies having chemically embossed patterns comprise: (1) adding sulphur and synthetic rubber material capable of forming sulphur bridges to a vinyl chloride resin preparation containing a foaming agent, forming the mixture into a sheet, printing embossed patterns on the sheet using an ink containing a vulcanization accelerator, drying the printed sheet and then heating the sheet to decompose the foaming agent thereby foaming the sheet; and (2) adding synthetic rubber material containing terminal groups capable of reacting with isocyanates to a vinyl chloride resin preparation containing a foaming agent, forming the mixture into a sheet, printing embossed patterns on the sheet using an ink containing isocyanates, drying the printed sheet and then heating the sheet to decompose the foaming agent thereby foaming the sheet.

Inventors

  • 👤 Nobuo Miura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 11:42
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/06; C08J9/10; C08J9/0061; D; D06; D06N; D06N3/00; D06N3/04; D06N3/06; D06N3/065; D06N3/10; D06N7/00; D06N7/0005; D06N7/0007; D06N7/001; D06N7/0013; C08J2327/00; C08J2327/02; C08J2327/04; C08J2327/06; C08J2409/00; Y; Y10; Y10S; Y10S264/00; Y10S264/18; Y10S264/82; Y10T; Y10T428/00; Y10T428/24; Y10T428/24479; Y10T428/24496; Y10T428/24504

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 148 words
A method for producing a foamed body having chemically embossed patterns which comprises: forming a composition containing a plasticized polyvinyl chloride resin, a synthetic rubber material capable of forming sulphur bridges, a blowing agent selected from the group consisting of dinitrosopentamethylene tetramine and azobisdicarbonimide, sulphur as the vulcanization agent and a curing asistant into a sheet; printing an ink containing a vulcanization accelerator selected from the group consisting of 2-mercaptobenzothiazole, the zinc salt of 2-mercaptobenzothiazole, the sodium salt of 2-mercaptobenzothiazole, tetramethylthiuram monosulfide, tetramethylthiuram disulfide, piperidine pentamethylene dithiocarbamate, zinc diethyl dithiocarbamate and zinc-dibutylxanthate onto said sheet in a desired configuration; drying and curing the printed sheet by heating said printed sheet to a temperature of 90°-100° C for at least 20 hours; and heating said dried sheet to a temperature of 180°-210° C to cause foaming of said sheet thereby generating a sheet having said chemically embossed patterns therein.
Claim 2
Independent Claim 148 words
A method for producing a foamed body having chemically embossed patterns which comprises: forming a composition containing a plasticized polyvinyl chloride resin, a synthetic rubber material capable of forming sulphur bridges, a blowing agent selected from the group consisting of dinitrosopentamethylene tetramine and azobisdicarbonimide, sulphur as the vulcanization agent and a curing asistant into a sheet; printing an ink containing a vulcanization accelerator selected from the group consisting of 2-mercaptobenzothiazole, the zinc salt of 2-mercaptobenzothiazole, the sodium salt of 2-mercaptobenzothiazole, tetramethylthiuram monosulfide, tetramethylthiuram disulfide, piperidine pentamethylene dithiocarbamate, zinc diethyl dithiocarbamate and zinc-dibutylxanthate onto said sheet in a desired configuration; drying and curing the printed sheet by heating said printed sheet to a temperature of 90°-100° C for at least 20 hours; and heating said dried sheet to a temperature of 180°-210° C to cause foaming of said sheet thereby generating a sheet having said chemically embossed patterns therein.
Claim 3
Dependent Claim 27 words
The method of claim 1 wherein said vinyl chloride resin preparation further contains at least one additive selected from the group consisting of stabilizers, lubricants and pigments.
Claim 4
Dependent Claim 11 words
An embossed foamed body prepared by the method of claim 1.
Claim 5
Independent Claim 111 words
A method for producing a foamed body having chemically embossed patterns which comprises: forming a composition containing a plasticized vinyl chloride resin, a synthetic rubber material containing terminal groups capable of reacting with isocyanate functional groups, and a blowing agent selected from the group consisting of dinitroso pentamethylene tetramine and azobisdicarbonimide into a sheet; printing said sheet with an ink containing an isocyanate capable of reacting with said synthetic rubber into a desired configuration; drying said printed sheet at a temperature of 90°-100° C; and heating said dried sheet to a temperature of 180°-210° C to cause foaming of said sheet thereby generating a sheet having said chemically embossed patterns therein.
Claim 6
Independent Claim 111 words
A method for producing a foamed body having chemically embossed patterns which comprises: forming a composition containing a plasticized vinyl chloride resin, a synthetic rubber material containing terminal groups capable of reacting with isocyanate functional groups, and a blowing agent selected from the group consisting of dinitroso pentamethylene tetramine and azobisdicarbonimide into a sheet; printing said sheet with an ink containing an isocyanate capable of reacting with said synthetic rubber into a desired configuration; drying said printed sheet at a temperature of 90°-100° C; and heating said dried sheet to a temperature of 180°-210° C to cause foaming of said sheet thereby generating a sheet having said chemically embossed patterns therein.
Claim 7
Dependent Claim 27 words
The method of claim 4 wherein said vinyl chloride resin preparation further contains at least one additive selected from the group consisting of, stabilizers, lubricants and pigments.
Claim 8
Dependent Claim 11 words
An embossed foamed body prepared by the method of claim 4.

References Cited (Backward Citations)

US3365353A Cited
US3538204A Cited
US3453171A Cited
US3519527A Cited
US3823214A Cited
US3800013A Cited
US3804933A Cited
US3857915A Cited
US3819438A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-04-03 1981-10-03 1982-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-04-03 1985-10-03 1986-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-04-03 1989-10-03 1990-04-04 $7700.00 Window Closed / Lapsed

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