Abstract A heat flow type differential calorimeter uses a planar thermoelectric disc as its major heat flow path for transferring heat to the sample and reference capsules. To improve the reproducibility of the calorimeter, two small discs of a thermoelectric material capable of forming a thermocouple with the thermoelectric disc are attached thereto in face-to-face relationship. Next a thermocouple pair made of the same material as the small disc and a third material, capable of forming a thermocouple with the disc, is attached to the center of each of the small discs. This converts the usual point contact temperature sensor to a large surface area temperature sensor and hence improves the reproducibility of the thermal analyzer.
A cell for use in the differential thermal analysis of sample materials comprising: a thermally conductive disc at least a portion of which is fabricated of a first metal, said metal portion of said conductive disc having two face area regions each adapted to receive one of said sample materials and a reference material, said conductive disc having an outer portion fabricated of a ceramic and an inner portion fabricated of said first metal; a pair of second discs each disc having a face, being fabricated of a second metal capable of forming a thermocouple with said first metal, and affixed to at least a portion of a different one of said face area regions of said conductive disc in face-to-face relationship to form respective sandwich-like thermocouple regions for said sample and reference materials; a first lead of said second metal affixed to one of said second discs; a second lead of said second metal affixed to the other of said second discs; and means for sensing the temperature of said sample material.
Claim 2
Dependent Claim
173 words
A cell for use in the differential thermal analysis of sample materials comprising: a thermally conductive disc at least a portion of which is fabricated of a first metal, said metal portion of said conductive disc having two face area regions each adapted to receive one of said sample materials and a reference material, said conductive disc having an outer portion fabricated of a ceramic and an inner portion fabricated of said first metal; a pair of second discs each disc having a face, being fabricated of a second metal capable of forming a thermocouple with said first metal, and affixed to at least a portion of a different one of said face area regions of said conductive disc in face-to-face relationship to form respective sandwich-like thermocouple regions for said sample and reference materials; a first lead of said second metal affixed to one of said second discs; a second lead of said second metal affixed to the other of said second discs; and means for sensing the temperature of said sample material.