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US4104332A Expired / Lapsed US ⏱️ 0.0 years remaining

Coupling of alkali metal-terminated polymers

Assignee: Phillips Petroleum Co
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Filing: 1977-03-14
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Granted: 1978-08-01
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Expires: 1997-03-14
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Abstract

Abstract Alkali metal-terminated polymers of one or more alkadienes and of one or more vinyl-substituted aromatic monomers are effectively coupled by a di-, tri-, or tetra carboxylic acid halide of substituted or unsubstituted benzene.

Inventors

  • 👤 Robert P. Zelinski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:17
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; C08G81/021; C08C; C08C19/00; C08C19/30; C08C19/42; C08C19/44

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 216 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different, are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3 or 4, wherein the radicals Y' which can be the same or different, are selected from the group of radicals consisting of --Y and ##STR5## wherein --Y is a radical selected from the group of radicals represented by the formulae ##STR6## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z, which can be the same or different, are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 carbon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).
Claim 2
Dependent Claim 216 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different, are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3 or 4, wherein the radicals Y' which can be the same or different, are selected from the group of radicals consisting of --Y and ##STR5## wherein --Y is a radical selected from the group of radicals represented by the formulae ##STR6## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z, which can be the same or different, are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 carbon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).
Claim 3
Dependent Claim 17 words
A polymer in accordance with claim 1 wherein R" is an alkyl radical with 1-6 carbon atoms.
Claim 4
Dependent Claim 66 words
A polymer in accordance with claim 1 wherein the polymer chain Z is selected from the group consisting of homopolymers and copolymers of butadiene and isoprene and of copolymers of butadiene and/or isoprene with styrene and/or a methylstyrene and wherein R is hydrogen, n is 3, and the three substituents Y and Y' are attached in 1, 3 and 5 position to the benzene ring A.
Claim 5
Dependent Claim 43 words
A polymer in accordance with claim 1 wherein the radicals Z have the structure A'--B'--, wherein A' is a polystyrene block and B' is a rubbery block obtained by polymerizing or copolymerizing an alkadiene selected from the group consisting of butadiene and isoprene.
Claim 6
Dependent Claim 206 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3, or 4, wherein the radicals Y' which can be the same or different are selected from the group of radicals consisting of --Y and ##STR7## wherein --Y is the radical ##STR8## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z which can be the same or different are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 cabon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).
Claim 7
Dependent Claim 206 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3, or 4, wherein the radicals Y' which can be the same or different are selected from the group of radicals consisting of --Y and ##STR7## wherein --Y is the radical ##STR8## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z which can be the same or different are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 cabon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).
Claim 8
Dependent Claim 17 words
A polymer in accordance with claim 5 wherein R" is an alkyl radical with 1-6 carbon atoms.
Claim 9
Dependent Claim 64 words
A polymer in accordance with claim 5 wherein the polymer chain Z is selected from the group of homopolymers and copolymers of butadiene and isoprene and of copolymers of butadiene and/or isoprene with styrene and/or a methylstyrene and wherein R is hydrogen, n is 3, and the three substituents Y and Y' are attached in 1,3, and 5 position to the benzene ring A.
Claim 10
Dependent Claim 43 words
A polymer in accordance with claim 5 wherein the radicals Z have the structures A'--B'--, wherein A' is a polystyrene block and B' is a rubbery block obtained by polymerizing or copolymerizing an alkadiene selected from the group consisting of butadiene and isoprene.
Claim 11
Dependent Claim 206 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3, or 4, wherein the radicals Y' which can be the same or different are selected from the group of radicals consisting of --Y and ##STR9## wherein --Y is the radical ##STR10## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z which can be the same or different are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 carbon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).
Claim 12
Dependent Claim 206 words
A polymer having the structure A(Y').sub.n-1 YR.sub.6-n (I) wherein A represents a benzene ring, wherein the radicals R which can be the same or different are selected from the group consisting of hydrogen and hydrocarbyl radicals with 1-6 carbon atoms per radical, the total number of carbon atoms in all R radicals being between 0 and about 10, wherein n is 2, 3, or 4, wherein the radicals Y' which can be the same or different are selected from the group of radicals consisting of --Y and ##STR9## wherein --Y is the radical ##STR10## wherein R" is hydrogen or a hydrocarbyl radical having 1-10 carbon atoms and the radicals Z which can be the same or different are selected from the group consisting of polymer chains of one or more alkadienes having 4-12 carbon atoms and copolymer chains of one or more alkadienes having 4-12 carbon atoms and one or more monovinylarenes of 8-18 carbon atoms, having the vinyl radical attached to an arene ring carbon atom, said polymer chains being unhydrogenated or having at least a portion of the olefinic unsaturation thereof removed by hydrogenation, with the further provision that at least 160 polymer chains Z are present in 100 molecules of the formula (I).

References Cited (Backward Citations)

US3135716A Cited
US3177190A Cited
US3281383A Cited
US3506639A Cited
US3810877A Cited
US4039633A Cited
US4049753A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-31 1982-01-30 1982-08-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-31 1986-01-30 1986-08-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-31 1990-01-30 1990-08-01 $7700.00 Window Closed / Lapsed

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