Melt preparation of 6TA/6IA polymers with phosphorus compound to reduce ammonia formation

Claim 1

In a process for preparing a random copolyamide by melt polymerization of a mixture consisting essentially of (i) hexamethylenediammonium terephthalate and (ii) hexamethylenediammonium isophthalate in a mole ratio of 30:70 to 80:20, respectively, and (iii) from 0 to 15 mole %, based on the moles of (i) and (ii), of a lactam or salt of a diamine of the formula NH 2 -- R' -- NH 2 and a diacid of the formula HOOC -- R" -- COOH, where R' is a C 2 to C 10 alkylene and R" is a C 3 to C 10 alkylene, the improvement comprising adding to said mixture prior to melt polymerization thereof from 20 to 20,000 parts per million, based on the weight of said copolymer, of at least one phosphorus compound whereby the amount of ammonia formed during melt polymerization is reduced, said phosphorus compound or compounds being of the formula ##STR6## where Q is a hydrogen atom or a radical selected from the group consisting of R, OR, OM and OH wherein R is a hydrocarbon radical and M is an alkali metal atom, with the proviso that each said phosphorus compound has no more than one OH radical and in formula (I) at least one of the Q's is hydrogen.