← Back to Patent Explorer
US4123395A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions containing nonionic surfactant and sulfonated aromatic compatibilizing agent

Assignee: Procter and Gamble Co
•
Filing: 1977-09-28
•
Granted: 1978-10-31
•
Expires: 1997-09-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Bleach-free detergent compositions for use in automatic dishwashers comprising an alkoxylated nonionic surface-active agent and a sulfonated aromatic compatibilizing agent. Preferred nonionic surfactants include ethoxylated nonionics and preferred compatibilizing agents can be selected from xylene-, toluene-, cumene-, benzene-, trimethylbenzene-, ethylbenzene- and ethylmethylbenzenesulfonate. The instant compositions possess enhanced anti-redepositon properties for soils composed of grease and grease-protein complexes thereby providing impeccably cleaned objects which are virtually free of spots and streaks.

Inventors

  • 👤 Edward J. Maguire, Jr.
  • 👤 Robert A. Staab

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 10:09
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/34; C11D3/3418; C11D1/00; C11D1/66; C11D1/72; C11D1/721; C11D17/00; C11D17/0004

Claims Analysis

Total Claims: 34
Claim 1
Independent Claim 547 words
A cleaning composition, particularly suitable for use in automatic dishwashers and having improved antiredeposition properties, comprising: (a) at least about 4% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; and (b) at least about 5% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3, the compositions being substantially free of a chlorine bleach component and being in a form selected from the group consisting of a solid, a paste, a gel, or a non-aqueous liquid.
Claim 2
Dependent Claim 547 words
A cleaning composition, particularly suitable for use in automatic dishwashers and having improved antiredeposition properties, comprising: (a) at least about 4% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; and (b) at least about 5% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3, the compositions being substantially free of a chlorine bleach component and being in a form selected from the group consisting of a solid, a paste, a gel, or a non-aqueous liquid.
Claim 3
Dependent Claim 29 words
A composition in accordance with claim 1 wherein the weight ratio of said alkoxylated nonionic to said compatibilizing agent is in the range from about 3:5 to about 5:4.
Claim 4
Dependent Claim 21 words
A composition in accordance with claim 2 which, in addition, contains from 0.001% to about 5% of a suds regulating agent.
Claim 5
Dependent Claim 43 words
A composition in accordance with claim 3 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzene sulfonate, toluene sulfonate, xylene sulfonate, cumene sulfonate, trimethyl benzene sulfonate, ethyl benzene sulfonate, ethylmethyl benzene sulfonate and mixtures thereof.
Claim 6
Dependent Claim 95 words
A composition in accordance with claim 3 wherein said suds regulating agent is selected from the group consisting of (a) a siloxane having the formula: ##STR2## wherein x is from about 20 to about 2,000 and R and R' are each alkyl or aryl groups; (b) a microcrystalline wax having a melting point in the range from about 35° C. to about 115° C. and a saponification value of less than 100; (c) an alkyl phosphate ester component selected from the group consisting of stearyl acid phosphate and oleyl acid phosphate; and (d) mixtures thereof.
Claim 7
Dependent Claim 122 words
A composition in accordance with claim 5 wherein said alkoxylated nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; and an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof.
Claim 8
Dependent Claim 33 words
A composition in accordance with claim 6 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzenesulfonate, toluenesulfonate, xylenesulfonate, cumenesulfonate, trimethylbenzenesulfonate, ethylbenzenesulfonate, ethylmethylbenzenesulfonate and mixtures thereof.
Claim 9
Dependent Claim 530 words
A granular cleaning composition, particularly suitable for use in automatic dishwashers, having improved antiredeposition properties comprising: (a) from about 4% to about 20% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; (b) from about 5% to about 20% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than about 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3; and which is substantially free of a chlorine bleach component.
Claim 10
Dependent Claim 530 words
A granular cleaning composition, particularly suitable for use in automatic dishwashers, having improved antiredeposition properties comprising: (a) from about 4% to about 20% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; (b) from about 5% to about 20% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than about 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3; and which is substantially free of a chlorine bleach component.
Claim 11
Dependent Claim 27 words
A composition in accordance with claim 8 wherein said alkoxylated nonionic surface-active agent and said compatibilizing agent collectively represent from about 9% to about 40% by weight.
Claim 12
Dependent Claim 29 words
A composition in accordance with claim 9 wherein the weight ratio of said alkoxylated nonionic to said compatibilizing agent is in the range from about 3:5 to about 5:4.
Claim 13
Dependent Claim 23 words
A composition in accordance with claim 10 which, in addition, contains from 0.001% to about 5% by weight of a suds regulating agent.
Claim 14
Dependent Claim 27 words
A composition in accordance with claim 11 wherein said alkoxylated nonionic surface-active agent and said compatibilizing agent collectively represent from about 10% to about 30% by weight.
Claim 15
Dependent Claim 26 words
A composition in accordance with claim 12 wherein said suds regulating agent is present in an amount of from about 0.05% to about 3% by weight.
Claim 16
Dependent Claim 43 words
A composition in accordance with claim 13 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzene sulfonate, toluene sulfonate, xylene sulfonate, cumene sulfonate, trimethyl benzene sulfonate, ethyl benzene sulfonate, ethylmethyl benzene sulfonate and mixtures thereof.
Claim 17
Dependent Claim 95 words
A composition in accordance with claim 13 wherein said suds regulating agent is selected from the group consisting of (a) a siloxane having the formula: ##STR3## wherein x is from about 20 to about 2,000 and R and R' are each alkyl or aryl groups; (b) a microcrystalline wax having a melting point in the range from about 35° C. to about 115° C. and a saponification value of less than 100; (c) an alkyl phosphate ester component selected from the group consisting of stearyl acid phosphate and oleyl acid phosphate; and (d) mixtures thereof.
Claim 18
Dependent Claim 122 words
A composition in accordance with claim 15 wherein said alkoxylated nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; and an alkoxylate having the formula: Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof.
Claim 19
Dependent Claim 33 words
A composition in accordance with claim 16 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzenesulfonate, toluenesulfonate, xylenesulfonate, cumenesulfonate, trimethylbenzenesulfonate, ethylbenzenesulfonate, ethylmethylbenzenesulfonate and mixtures thereof.
Claim 20
Dependent Claim 32 words
A composition in accordance with claim 17 wherein R and R' of said siloxane suds regulating agent are selected from the group consisting of methyl, ethyl, propyl, butyl, phenyl and mixtures thereof.
Claim 21
Dependent Claim 55 words
A composition in accordance with claim 17 wherein said microcrystalline wax suds regulating agent has a melting point from about 65° C. to about 100° C. and is selected from the group consisting of microcrystalline and oxidized microcrystalline petrolatum waxes, Fischer-Tropsch and oxidized Fischer-Tropsch waxes, ozokerite, ceresin, montan wax, beeswax, candelilla, carnauba and mixtures thereof.
Claim 22
Dependent Claim 22 words
A composition in accordance with claim 17 wherein the weight ratio of said nonionic alkoxylate to said compatibilizing agent is about 1:1.
Claim 23
Dependent Claim 532 words
A pasty or gelled cleaning composition, particularly suitable for use in automatic dishwashers and having improved antiredeposition properties, comprising: (a) from about 6% to about 55% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; (b) from about 7.5% to about 65% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3; and which is substantially free of a chlorine bleach component.
Claim 24
Dependent Claim 532 words
A pasty or gelled cleaning composition, particularly suitable for use in automatic dishwashers and having improved antiredeposition properties, comprising: (a) from about 6% to about 55% by weight of an alkoxylated low-foaming nonionic surface-active agent, wherein said nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 20 moles of ethylene oxide; a polyetherester having the formula (ClC.sub.6 H.sub.4).sub.2 CHCO.sub.2 (CH.sub.2 CH.sub.2 O).sub.x R wherein x is an integer from 4 to 20 and R is a lower alkyl group containing not more than 4 carbon atoms; a surfactant having the formula Y(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein Y is the residue of an organic compound having from about 1 to 6 carbon atoms and one reactive hydrogen atom, n has an average of at least about 6.4, as determined by hydroxyl number, and m has a value such that the oxyethylene portion constitutes about 10 to 90 weight percent of the molecule; a surfactant having the formula P[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxypropylene portion is at least about 58 and m has a value such that the oxyethylene content of the molecule is from about 10 to 90 weight percent; a surfactant having the formula P[(C.sub.2 H.sub.4 O).sub.n (C.sub.3 H.sub.6 O).sub.m H].sub.x wherein P is the residue of an organic compound having from about 8 to 18 carbon atoms and containing x reactive hydrogen atoms in which x has a value of 1 or 2, n has a value such that the molecular weight of the polyoxyethylene portion is at least about 44 and m has a value such that the oxypropylene content of the molecule is from about 10 to 90 weight percent; an alkoxylate having the formula Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to about 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof; a condensation product of benzyl chloride and an ethoxylated alkyl phenol wherein the alkyl group has from about 6 to about 12 carbon atoms and wherein from about 12 to about 20 ethylene oxide molecules have been condensed per mole of alkyl phenol; and mixtures of the foregoing surfactants; (b) from about 7.5% to about 65% by weight of a sulfonated aromatic compatibilizing agent having a critical micelle concentration greater than 1% by weight at 25° C., wherein the weight ratio of said alkoxylated nonionic surface-active agent to said sulfonated compatibilizing agent is in the range from about 2:5 to about 5:3; and which is substantially free of a chlorine bleach component.
Claim 25
Dependent Claim 27 words
A composition in accordance with claim 21 wherein said alkoxylated nonionic surface-active agent and said compatibilizing agent collectively represent from about 20% to about 90% by weight.
Claim 26
Dependent Claim 29 words
A composition in accordance with claim 22 wherein the weight ratio of said alkoxylated nonionic to said compatibilizing agent is in the range from about 3:5 to about 5:4.
Claim 27
Dependent Claim 23 words
A composition in accordance with claim 23 which, in addition, contains from 0.001% to about 5% by weight of a suds regulating agent.
Claim 28
Dependent Claim 26 words
A composition in accordance with claim 24 wherein said suds regulating agent is present in an amount of from about 0.05% to about 3% by weight.
Claim 29
Dependent Claim 43 words
A composition in accordance with claim 25 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzene sulfonate, toluene sulfonate, xylene sulfonate, cumene sulfonate, trimethyl benzene sulfonate, ethyl benzene sulfonate, ethylmethyl benzene sulfonate and mixtures thereof.
Claim 30
Dependent Claim 95 words
A composition in accordance with claim 25 wherein said suds regulating agent is selected from the group consisting of (a) a siloxane having the formula: ##STR4## wherein x is from about 20 to about 2,000 and R and R' are each alkyl or aryl groups; (b) a microcrystalline wax having a melting point in the range from about 35° C. to about 115° C. and a saponification value of less than 100; (c) an alkyl phosphate ester component selected from the group consisting of stearyl acid phosphate and oleyl acid phosphate; and (d) mixtures thereof.
Claim 31
Dependent Claim 122 words
A composition in accordance with claim 27 wherein said alkoxylated nonionic surface-active agent is selected from the group consisting of a condensation product of one mole tallow alcohol with from about 6 to about 15 moles of ethylene oxide; and an alkoxylate having the formula: Y[(C.sub.3 H.sub.6 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x wherein x has a value of at least about 2, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about 900 and m has a value such that the oxyethylene content of the molecule is from about 10% to 90% by weight, and wherein Y is selected from the group consisting of propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylene diamine and mixtures thereof.
Claim 32
Dependent Claim 33 words
A composition in accordance with claim 28 wherein said compatibilizing agent is selected from the group consisting of an alkali metal salt of benzenesulfonate, toluenesulfonate, xylenesulfonate, cumenesulfonate, trimethylbenzenesulfonate, ethylbenzenesulfonate, ethylmethylbenzenesulfonate and mixtures thereof.
Claim 33
Dependent Claim 32 words
A composition in accordance with claim 29 wherein R and R' of said siloxane suds regulating agent are selected from the group consisting of methyl, ethyl, propyl, butyl, phenyl and mixtures thereof.
Claim 34
Dependent Claim 55 words
A composition in accordance with claim 27 wherein said microcrystalline wax suds regulating agent has a melting point from about 65° C. to about 100° C. and is selected from the group consisting of microcrystalline and oxidized microcrystalline petrolatum waxes, Fischer-Tropsch and oxidized Fischer-Tropsch waxes, ozokerite, ceresin, montan wax, beeswax, candelilla, carnauba and mixtures thereof.

References Cited (Backward Citations)

US2340035A Cited
US3250727A Cited
US3314891A Cited
US3679589A Cited
US4001132A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-30 1982-05-01 1982-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-30 1986-05-01 1986-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-30 1990-05-01 1990-10-31 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag