US4126668A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of hydrogen rich gas by combined steam reforming and intermediate oxidation-reduction
Assignee: Individual
•
Filing: 1975-05-23
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Granted: 1978-11-21
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Expires: 1995-05-23
Abstract
Abstract A hydrogen rich gas such as pure hydrogen, ammonia synthesis gas, or methanol synthesis gas is generated by reacting steam with a nongaseous intermediate, whereby some of the steam is reduced to hydrogen and some of the intermediate is oxidized. Carbon dioxide may be added to or substituted for the steam, whereby carbon monoxide is produced in addition to or in lieu of H 2 . The oxidized intermediate is reduced by a reducing gas. The reducing gas is generated by partially reforming a light hydrocarbon such as natural gas or naphtha with steam and/or CO 2 , and then partially oxidizing the partially reformed gas with air. The low BTU exhaust gas resulting after reduction of intermediate oxide is used as fuel for the primary reformer. When ammonia synthesis gas is produced by this process, the purge and flash gases from the ammonia synthesis loop are added to the reducing gas.
Inventors
- 👤 Donald C. Erickson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 21:50
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/02; C01B3/06; C01B3/32; C01B3/34; C01B3/38; C01B3/384; C01B2203/00; C01B2203/02; C01B2203/0205; C01B2203/0227; C01B2203/0238; C01B2203/04; C01B2203/0415; C01B2203/0465; C01B2203/0475; C01B2203/0495; C01B2203/06; C01B2203/061; C01B2203/068; C01B2203/08; C01B2203/0805; C01B2203/0811; C01B2203/0822; C01B2203/0827; C01B2203/0872; C01B2203/0883; C01B2203/0888; C01B2203/0894; C01B2203/12; C01B2203/1205; C01B2203/1211; C01B2203/1235; C01B2203/1241; C01B2203/1247; C01B2203/14; C01B2203/142; C01B2203/146; C01B2203/148; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/36; Y02P; Y02P20/00; Y02P20/10; Y02P20/129
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
123 words
A process for generating hydrogen which comprises a. generating the hydrogen by intermediate oxidation-reduction, wherein at least one intermediate selected from the group consisting of iron, wustite, tin, and WO 2 is reacted with steam to produce the hydrogen and an oxide of the intermediate, and the intermediate oxide is reacted with a reducing gas to regenerate the intermediate, whereby an exhaust reducing gas is available; b. oxidizing at least part of said exhaust reducing gas, whereby heat is released; c. supplying said heat to an endothermic reforming reaction between steam and a light hydrocarbon, whereby a reformed reducing gas mixture is obtained; d. using said reformed gas mixture as a source of at least part of said reducing gas in step a.
Claim 2
Dependent Claim
123 words
A process for generating hydrogen which comprises a. generating the hydrogen by intermediate oxidation-reduction, wherein at least one intermediate selected from the group consisting of iron, wustite, tin, and WO 2 is reacted with steam to produce the hydrogen and an oxide of the intermediate, and the intermediate oxide is reacted with a reducing gas to regenerate the intermediate, whereby an exhaust reducing gas is available; b. oxidizing at least part of said exhaust reducing gas, whereby heat is released; c. supplying said heat to an endothermic reforming reaction between steam and a light hydrocarbon, whereby a reformed reducing gas mixture is obtained; d. using said reformed gas mixture as a source of at least part of said reducing gas in step a.
Claim 3
Dependent Claim
30 words
The process according to claim 1, wherein said heat is supplied to said steam hydrocarbon reforming reaction by indirect heat exchange through the catalyst containing tubes of a steam reformer.
Claim 4
Dependent Claim
26 words
The process according to claim 1 wherein CO 2 is supplied in addition to steam and hydrocarbon as a reactant in the endothermic steam-hydrocarbon reforming reaction.
Claim 5
Dependent Claim
28 words
The process according to claim 1 wherein the reformed gas mixture is partially oxidized by a free oxygen containing gas prior to being used as the reducing gas.
Claim 6
Dependent Claim
39 words
The process according to claim 1 wherein said reformed gas mixture plus a free oxygen containing gas are contacted directly with the intermediate oxide, whereby partial oxidation of the reformed gas mixture and reduction of intermediate oxide occur concurrently.
Claim 7
Dependent Claim
16 words
The process according to claim 4 wherein carbonaceous fuel is added to said reformed gas mixture.
Claim 8
Dependent Claim
60 words
The process according to claim 1 wherein at least part of the steam supply to be reacted with at least one intermediate is generated at a pressure of approximately 120 bars using waste heat from the process, and is then expanded through a turbo-expander to the approximate pressure of the intermediate, whereby mechanical energy is recovered from the waste heat.
Claim 9
Dependent Claim
24 words
The process according to claim 1 wherein at least one of the metal or metallic compounds is iron, wustite, WO 2 , or tin.
Claim 10
Dependent Claim
22 words
The process according to claim 1 wherein at least one of the metal or metallic compounds is tungsten dioxide, tungsten, or molybdenum.
Claim 11
Dependent Claim
44 words
The process according to claim 1 wherein at least one of the intermediates consists essentially of liquid tin at a temperature in the approximate range of 900° K. to 1250° K. and a pressure in the approximate range of 5 bars to 180 bars.
Claim 12
Dependent Claim
127 words
In a process for producing hydrogen in which steam is reacted with at least one metal or metallic compound so as to produce hydrogen and oxidize the metal or metallic compound, and the oxidized metal or metallic compound is subsequently reduced by a reducing gas, so as to regenerate the metal or metallic compound and make available an exhaust reducing gas, the improvement which comprises: generating said reducing gas by: a. partially reforming a light hydrocarbon with steam, thereby yielding a partially reformed gas; b. partially oxidizing said partially reformed gas with air or oxygen; thereby generating said reducing gas c. combusting at least part of said exhaust reducing gas with air so as to supply the heat requirement of the endothermic reforming reaction of step (a).
Claim 13
Dependent Claim
127 words
In a process for producing hydrogen in which steam is reacted with at least one metal or metallic compound so as to produce hydrogen and oxidize the metal or metallic compound, and the oxidized metal or metallic compound is subsequently reduced by a reducing gas, so as to regenerate the metal or metallic compound and make available an exhaust reducing gas, the improvement which comprises: generating said reducing gas by: a. partially reforming a light hydrocarbon with steam, thereby yielding a partially reformed gas; b. partially oxidizing said partially reformed gas with air or oxygen; thereby generating said reducing gas c. combusting at least part of said exhaust reducing gas with air so as to supply the heat requirement of the endothermic reforming reaction of step (a).
Claim 14
Dependent Claim
23 words
The process of claim 11 in which supplemental fuel is added to the partially reformed gas which is partially oxidized in step (b).
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-20 | 1982-05-22 | 1982-11-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-20 | 1986-05-22 | 1986-11-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-20 | 1990-05-22 | 1990-11-21 | $7700.00 | Window Closed / Lapsed |