Process for preparation for copper-iron-aluminum catalysts and catalysts prepared by the process

Claim 2

A process for preparing copper-iron-aluminum catalysts, which comprises dissolving a cupric salt, a ferrous salt and an aluminum salt in water in proportions such that the solution contains 1.4 to 2.5 iron atoms and 0.4 to 1.2 aluminum atoms per one atom of copper, adding an alkali to the solution at a temperature higher than 60° C. and lower than the boiling point of the solution until the pH of the solution is in the range of from 9.5 to 11.8 to form a precipitate, separating the precipitate and then water-washing, drying, calcining and pulverizing the separated precipitate.

Claim 3

A process for the preparation of copper-iron-aluminum catalysts according to claim 1 wherein the copper salt is cupric sulfate, the iron salt is ferrous sulfate and the aluminum salt is aluminum sulfate.

Claim 4

A process according to claim 1, which consists essentially of dissolving in water (a) a cupric salt selected from the group consisting of cupric sulfate, cupric chloride and cupric nitrate, (b) a ferrous salt selected from the group consisting of ferrous sulfate, ferrous chloride and ferrous nitrate, and (c) an aluminum salt selected from the group consisting of aluminum sulfate, aluminum chloride and aluminum nitrate, to form an aqueous reaction mixture containing from 1.4 to 2.5 atoms of iron and 0.4 to 1.2 atoms of aluminum, per one atom of copper, gradually adding an aqueous solution of an alkali metal hydroxide to said reaction mixture and mixing same therein, at a temperature of from 60° C. to the boiling temperature of the reaction mixture, to change the pH of said reaction mixture to from 9.5 to 11.8, then maintaining said reaction mixture at said temperature for from 10 minutes to 20 hours while agitating said reaction mixture containing a black precipitate suspended therein, then separating said precipitate from the remainder of the reaction mixture, washing the precipitate with water to remove water-soluble ions, then drying the precipitate calcining the dried product at 450° to 850° C. for a period of time at the calcination temperature of from 0 to 2 hours to obtain a catalyst product.

Claim 5

A catalyst prepared by the process of claim 1.

Claim 6

A catalyst prepared by the process of claim 3.