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US4145503A Expired / Lapsed US ⏱️ 0.0 years remaining

Autoxidizable compositions

Assignee: Rohm and Haas Co
•
Filing: 1977-03-28
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Granted: 1979-03-20
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Expires: 1997-03-28
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Abstract

Abstract The invention is concerned with novel autoxidizable compositions comprising an unsaturated acid ester of a glycol monodicyclopentenyl ether, a condensation or vinyl addition polymer, a siccative and a volatile stabilizer, which compositions are uniquely adapted to be formulated with high solids and practical viscosity ranges for coating and/or impregnating purposes.

Inventors

  • 👤 William D. Emmons
  • 👤 Kayson Nyi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 06:47
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/26; C08F20/30; C08F299/00; C08F299/02; C08F299/06; Y; Y10; Y10S; Y10S525/00; Y10S525/92; Y10S525/921; Y10S525/922

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 106 words
A soluble linear addition polymer obtained (1) by anionic polymerization or (2) by solution polymerization or aqueous emulsion polymerization using a free radical initiator, adapted to be cured by autoxidation with a siccative, of a compound having the general formula: ##STR3## wherein R' is H or CH 3 and R" is selected from the groups consisting of (a) Alkylene groups having 2 to 6 carbon atoms and (b) Oxaalkylene groups having 4 to 12 carbon atoms and having one or more oxygen atoms joining distinct segments of the alkylene chain each of at least 2 carbon atoms length extending between oxygen atoms of the alkylene group.
Claim 2
Dependent Claim 106 words
A soluble linear addition polymer obtained (1) by anionic polymerization or (2) by solution polymerization or aqueous emulsion polymerization using a free radical initiator, adapted to be cured by autoxidation with a siccative, of a compound having the general formula: ##STR3## wherein R' is H or CH 3 and R" is selected from the groups consisting of (a) Alkylene groups having 2 to 6 carbon atoms and (b) Oxaalkylene groups having 4 to 12 carbon atoms and having one or more oxygen atoms joining distinct segments of the alkylene chain each of at least 2 carbon atoms length extending between oxygen atoms of the alkylene group.
Claim 3
Dependent Claim 10 words
A polymer according to claim 1 wherein R" is ethylene.
Claim 4
Dependent Claim 16 words
A polymer according to claim 1 wherein R" is ethylene and R' is CH 3 .
Claim 5
Dependent Claim 14 words
A polymer according to claim 1 wherein R" is ethylene and R' is H.
Claim 6
Dependent Claim 57 words
A soluble linear addition copolymer obtained by solution polymerization or aqueous emulsion polymerization using a free radical initiator, adapted to be cured by autoxidation with a siccative, of a compound having the general formula I as defined in claim 1 with at least one other ethylenically unsaturated monomer having a group of the formula H 2 C═C<.
Claim 7
Dependent Claim 27 words
A copolymer according to claim 5 in which the relative proportions between formula I monomer and other monomeric material is from about 1:99 (weight ratio) to 99:1.
Claim 8
Dependent Claim 28 words
Cured articles, such as films obtained by the autoxidation with a siccative of a linear polymer as defined in claim 1 disposed in the shape of the article.
Claim 9
Dependent Claim 31 words
A coating and/or impregnating composition adapted to be cured by autoxidation comprising a compound of formula I as defined in claim 1 and a small but effective amount of a siccative.
Claim 10
Dependent Claim 15 words
An autoxidizable composition according to claim 8 comprising a siccative and a volatile oxime stabilizer.

References Cited (Backward Citations)

US2454743A Cited
US3243416A Cited
US3940353A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-19 1982-09-18 1983-03-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-19 1986-09-18 1987-03-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-19 1990-09-18 1991-03-20 $7700.00 Window Closed / Lapsed

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